Search results for "Ultrafiltration"
showing 10 items of 68 documents
Characterization of Chlorolignins in Bleached Kraft Pulp Mill Effluents Using Elemental Analysis and Fingerprinting by CuO Oxidation And Hplc
1994
Abstract Elemental analyses and chemical degradation techniques were applied to characterize lignin compounds in different stages of the chlorine bleaching process and in total mill effluent. Ultrafiltration was used for separation of chlorolignins into three nominal molecular weight fractions. Alkaline CuO oxidation products were analyzed by HPLC with diode array detection. Major compounds were identified by reference to authentic compounds. For comparison, native lignins (MWL), kraft lignins, and humic substances were studied as well. The oxygen, carbon and organic chlorine contents were closely similar in the various mill samples and their fractions. In all mill samples, vanillin and 6-c…
Sub-critical filtration conditions of commercial hollow-fibre membranes in a submerged anaerobic MBR (HF-SAnMBR) system: The effect of gas sparging i…
2012
A submerged anaerobic MBR demonstration plant with two commercial hollow-fibre ultrafiltration systems (PURON®, Koch Membrane Systems, PUR-PSH31) was operated using municipal wastewater at high levels of mixed liquor total solids (MLTS) (above 22gL -1). A modified flux-step method was applied to assess the critical flux (J C) at different gas sparging intensities. The results showed a linear dependency between J C and the specific gas demand per unit of membrane area (SGD m). J C ranged from 12 to 19LMH at SGD m values of between 0.17 and 0.5Nm 3h -1m -2, which are quite low in comparison to aerobic MBR. Long-term trials showed that the membranes operated steadily at fluxes close to the est…
Experimental study of the anaerobic urban wastewater treatment in a submerged hollow-fibre membrane bioreactor at pilot scale
2011
The aim of this study was to assess the effect of several operational variables on both biological and separation process performance in a submerged anaerobic membrane bioreactor pilot plant that treats urban wastewater. The pilot plant is equipped with two industrial hollow-fibre ultrafiltration membrane modules (PURON¿ Koch Membrane Systems, 30m 2 of filtration surface each). It was operated under mesophilic conditions (at 33°C), 70days of SRT, and variable HRT ranging from 20 to 6h. The effects of the influent COD/SO 4-S ratio (ranging from 2 to 12) and the MLTS concentration (ranging from 6 to 22gL -1) were also analysed. The main performance results were about 87% of COD removal, efflu…
Evaluation of enantioselective binding of basic drugs to plasma by ACE.
2007
The present paper deals with the evaluation of the stereoselective binding of antihistamines (brompheniramine, chlorpheniramine, hydroxyzine, orphenadrine and phenindamine), phenothiazines (promethazine and trimeprazine) and a local anesthetic (bupivacaine) to human plasma proteins. Since all of them are drugs highly bound to proteins, a methodology to determine the bound fraction of each drug enantiomer was proposed. This methodology includes the incubation of samples containing plasma and racemic drug, ultrafiltration of the mixture and the chiral separation of enantiomers in the bound drug fraction using affinity EKC (AEKC)-partial filling technique and HSA as chiral selector. The result…
Performance of an outdoor membrane photobioreactor for resource recovery from anaerobically treated sewage
2018
[EN] The objective of this work was to evaluate the performance of a pilot scale membrane photobioreactor (MPBR) for treating the effluent of an anaerobic membrane bioreactor (AnMBR) system. In particular, new experimental data on microalgae productivity, nutrient recovery, CO2 biofixation and energy recovery potential was obtained under different operating conditions, which would facilitate moving towards cost-effective microalgae cultivation on wastewater. To this aim, a 2.2-m(3) MPBR equipped with two commercial-scale hollow-fibre ultrafiltration membrane modules was operated treating the nutrient-loaded effluent from an AnMBR for sewage treatment. The influence of several design, enviro…
Factors that affect the permeability of commercial hollow-fibre membranes in a submerged anaerobic MBR (HF-SAnMBR) system
2013
A demonstration plant with two commercial HF ultrafiltration membrane modules (PURON (R), Koch Membrane Systems, PUR-PSH31) was operated with urban wastewater. The effect of the main operating variables on membrane performance at sub-critical and supracritical filtration conditions was tested. The physical operating variables that affected membrane performance most were gas sparging intensity and back-flush (BF) frequency. Indeed, low gas sparging intensities (around 0.23 Nm(3) h(-1) m(-2)) and low BF frequencies (30s back-flush for every 10 basic filtration relaxation cycles) were enough to enable membranes to be operated sub-critically even when levels of mixed liquor total solids were hi…
Sub-critical long-term operation of industrial scale hollow-fibre membranes in a submerged anaerobic MBR (HF-SAnMBR) system
2012
The aim of this study was to evaluate the long-term performance of hollow-fibre (HF) membranes used to treat urban wastewater in a submerged anaerobic MBR when operating sub-critically. To this end, a demonstration plant with two industrial scale HF ultrafiltration membrane modules was operated under different conditions. The main factor affecting membrane performance was the concentration of mixed liquor total solids (MLTS). The reversible fouling rate remained low even when MLTS levels (about 25 g L−1) in the membrane tank were high. No chemical cleaning was conducted whilst operating the plant for more than one year because no irreversible fouling problems were detected. The almost compl…
Mass spectrometric investigations of the kinetic stability of chromium and copper complexes with humic substances by isotope-labelling experiments
1999
Isotope-labelling exchange experiments were carried out to investigate the kinetic stability of Cr(III) complexes with humic substances (HS). To compare the results with those of an ion, not expected to form kinetically stable HS complexes with respect to its electron configuration, Cu(II) was investigated under the same conditions. HS solutions of different origin were therefore spiked with 53Cr(III) or 65Cu(II) after saturation of HS with chromium and copper of natural isotopic composition. In fractions of metal/HS complexes with different molecular weight, obtained by ultrafiltration and HPLC/ICP-MS using size exclusion chromatography (SEC), respectively, the isotope ratios of chromium a…
Caseicin 80: purification and characterization of a new bacteriocin from Lactobacillus casei
1990
When grown in complex or synthetic media, Lactobacillus casei B 80 synthesizes a mitomycin C-inducible polypeptide with very specific bactericidal activity against the sensitive strain Lactobacillus casei B 109. The amount of secreted bacteriocin in the culture solution was low, about 1 mg/l. The bacteriocin which we called caseicin 80, was also detectable in cell extracts, although only 2% of the total activity was retained intracellularly. Caseicin 80 was concentrated by ultrafiltration and purified by cation exchange chromatography with Cellulose SE-23 and Superose. The molecular weight was in the range of M r=40,000–42,000 and the isoelectric point was pH 4.5.
Effect of acidosis and anoxia on iron delocalization from brain homogenates.
1992
Abstract Cortical homogenates were prepared from rat brain in Krebs-Ringer phosphate media adjusted to pH 7, 6 or 5 and incubated for 1 hr under aerotic or anaerobic conditions in the presence of dipyridyl, an iron chelator. Low molecular weight species (LMWS) iron was measured spectrophotometrically after passing of the homogenates through a 10,000- M , ultrafiltration membrane. Following aerobic incubation, LMWS iron reached 1.24 μg/g tissue at pH 7, and increased 1.7-fold at pH 6 and 3.1-fold at pH 5. Anoxia enhanced significantly the amount of ultrafiltrable iron at the three pH values, the LMWS iron level being increased by 190% at pH 7, by 113% at pH 6, and by 77% at pH 5. Addition of…