Search results for "VIBRATION"
showing 10 items of 823 documents
Disorder-induced vibrational anomalies from crystalline to amorphous solids
2021
The origin of boson peak -- an excess of density of states over Debye's model in glassy solids -- is still under intense debate, among which some theories and experiments suggest that boson peak is related to van-Hove singularity. Here we show that boson peak and van-Hove singularity are well separated identities, by measuring the vibrational density of states of a two-dimensional granular system, where packings are tuned gradually from a crystalline, to polycrystals, and to an amorphous material. We observe a coexistence of well separated boson peak and van-Hove singularities in polycrystals, in which the van-Hove singularities gradually shift to higher frequency values while broadening th…
Structural disorder and silanol groups content in amorphousSiO2
2009
We present a study on the features of the Urbach edge in amorphous silicon dioxide $(a{\text{-SiO}}_{2})$. The effects of temperature on the absorption edge in the range from 4 to 300 K were studied in both materials having negligible (dry, $l{10}^{17}\text{ }{\text{cm}}^{\ensuremath{-}3}$) and significant (wet, $g{10}^{19}\text{ }{\text{cm}}^{\ensuremath{-}3}$) silanol groups contents. Remarkable differences in the values and in the temperature dependence of the Urbach energy in the dry and wet samples were observed. These differences are interpreted as a consequence of a drastic reduction in the degree of disorder in wet materials, which turn out to be characterized by an electronic struc…
Mechanical Coupling in Gold Nanoparticles Supermolecules Revealed by Plasmon-Enhanced Ultralow Frequency Raman Spectroscopy
2016
International audience; Acoustic vibrations of assemblies of gold nanoparticles were investigated using ultralow frequency micro-Raman scattering and finite element simulations. When exciting the assemblies resonantly with the surface plasmon resonance of electromagnetically coupled nano-particles, Raman spectra present an ultralow frequency band whose frequency lies below the lowest Raman active Lamb mode of single nanoparticles that was observed. This feature was ascribed to a Raman vibration mode of gold nanoparticle " supermolecules " , that is, nanoparticles mechanically coupled by surrounding polymer molecules. Its measured frequency is inversely proportional to the nanoparticle diame…
Repeatability of the resonance frequency analysis values in implants with a new technology
2019
Background Assess the reliability (by means of reproducibility and repeatability) of the PenguinRFA system, analyse the ISQ values of different implant types and correlate the ISQ with the insertion torque during the placement of the implant. Material and Methods 120 rough surface implants were placed in bovine bone (type II and III). The implants were divided into groups, according to its design. Once the implants were in place, the exact insertion torque was registered. Then, primary stability was measured by means of the resonance frequency analysis with the PenguinRFA and the Osstell ISQ devices. In each implant two transducers of each device were used. Three measurements were obtained …
Raman and infrared studies ofLa1−ySryMn1−xMxO3(M=Cr, Co, Cu, Zn, Sc or Ga): Oxygen disorder and local vibrational modes
2006
We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La1-ySryMn1-xMxO3 manganites in the temperature range between 77 and 320 K. In our samples, a part of the Mn atoms is substituted by M = Cr, Co, Cu, Zn, Sc, or Ga with x in the range 0-0.1. The hole concentration was kept at the optimal value of about 32% by tuning the Sr content y. We have monitored distortions of the oxygen sublattice by the presence of broad bands in the Raman spectra, the increase of dc resistivity extracted from the infrared reflectivity, and the change of the critical temperature of the ferromagnetic transition. Our results support the idea that these proper…
A Magnetostrictive Electric Power Generator for energy harvesting from traffic: Design and experimental verification
2015
In the last decades, the growth in energy demand, the decrease of fossil fuels available in the market and the impact of anthropogenic factors on climate change has given new impulse to research on renewable energy systems, particularly those known as energy harvesting devices (EHDs) [1]. A large number of EHDs have been proposed, using different operating principle [1-4]. Among them, piezoelectric and magnetostrictive seem to be particularly suitable for the application in EHD. In these materials the application of external mechanical stress induces a change in the level of magnetization and therefore an electromotive force (emf) can be generated and collected in order to produce electrica…
Acoustic modes in metallic nanoparticles: atomistic versus elasticity modeling
2009
The validity of the linear elasticity theory is examined at the nanometer scale by investigating the vibrational properties of silver and gold nanoparticles whose diameters range from about 1.5 to 4 nm. Comparing the vibration modes calculated by elasticity theory and atomistic simulation based on the Embedded Atom Method, we first show that the anisotropy of the stiffness tensor in elastic calculation is essential to ensure a good agreement between elastic and atomistic models. Second, we illustrate the reduction of the number of vibration modes due to the diminution of the number of atoms when reducing the nanoparticles size. Finally, we exhibit a breakdown of the frequency-spectra scalin…
Temperature- and Magnetic-Field-Dependent Longitudinal Spin Relaxation in Nitrogen-Vacancy Ensembles in Diamond
2011
We present an experimental study of the longitudinal electron-spin relaxation time (T1) of negatively charged nitrogen-vacancy (NV) ensembles in diamond. T1 was studied as a function of temperature from 5 to 475 K and magnetic field from 0 to 630 G for several samples with various NV and nitrogen concentrations. Our studies reveal three processes responsible for T1 relaxation. Above room temperature, a two-phonon Raman process dominates, and below, we observe an Orbach-type process with an activation energy, 73(4) meV, which closely matches the local vibrational modes of the NV center. At yet lower temperatures, sample dependent cross relaxation processes dominate, resulting in temperature …
FERROELECTRIC LIQUID CRYSTAL GLASSES FOR AMBLYOPIA RESEARCH
2008
ABSTRACT Ferroelectric Liquid Crystal (FLC) filters offer the speed of electronic light shutters and the vibration free operation. These characteristics make them ideal for applications requiring short exposure times and minimal blur, offering switching times of 0.0002 of a second. FLC filters can be used as the optical shutters for machine vision purposes, also in vision research. On the basis of FLC filters we have developed ferroelectric glasses, allowing temporal separation of optical information for both eyes. In the case of amblyopia (“lazy eye”) the only way to oblige the “lazy” eye to work is to close the other better-seeing eye. We advice an appliance for dynamic visual system trai…
Depth profiling of optical and vibrational properties in GaN/AlN quantum dot superlattices
2009
Spatially resolved confocal μ-Raman and μ-photoluminescence experiments were performed to analyze the vibrational and optical properties of GaN/AlN quantum dots as a function of depth. Two approaches have been followed. First, spectra were taken by defocusing the microscope objective at various depths on the sample surface. In a second set of experiments a bevel at an angle of 20° with respect to the surface normal was prepared by mechanical polishing of the surface, and spectra were taken across the bevel. The E2h vibrational modes ascribed to the GaN QDs and the AlN spacer redshift towards the surface, indicating the progressive relaxation of the QDs and a considerable increase of the ten…