Search results for "VIBRATION"

Vibrational Resonance in inhomogeneous and space-dependent nonlinear damped systems

2020

International audience; The properties of nonlinear systems have attracted a considerable interest these past years since they can be used to develop bio-inspired applications ranging from signal detection to image processing. Among these nonlinear signatures is Vibrational Resonance (V.R.) which expresses the ability of a nonlinear system to take benefit of a high frequency perturbation in order to enhance its response to a weak low frequency excitation . Since its introduction in mechanical systems and electronic devices, this effect has been widely reported in various systems and for different applications. Indeed, V.R can be used to detect subthreshold signals or to enhance the percepti…

Vibrational Spectra of Polyatomic Molecules through an Algebraic Approach

1987

The study of molecular oscillators may be performed with algebraic methods based upon dynamical chains and their realization in terms of boson operators. From the dynamical algebra U(p+1) for p equivalent oscillators, associated with stretching modes, the local, pseudo-normal and normal limits are obtained through appropriate subgroup chains and various realizations of the U(p+1) generators. Similar technics can be applied to bending modes. Application to XY4 molecules will be presented.

Rovibrational interactions in the local-mode limit. The (n000) stretching overtone bands of spherical tops.

1993

Analytical chemistry on many-center chiral compounds based on vibrational circular dichroism: Absolute configuration assignments and determination of…

2019

The absolute configuration of a chiral molecule is key to its biological activity. Being able to find out what this configuration is, is thus crucial for a wide range of applications. The difficulties associated with such a determination steeply rise as the number of chiral centers in a given compound becomes larger. Concurrently, it becomes increasingly more challenging to determine the levels and identity of potential stereochemical contaminants in a given sample with one and the same technique, leading in practice to extensive and laborious efforts employing multiple analytical techniques. Here, experimental and theoretical studies based on Vibrational Circular Dichroism (VCD) are presen…

Noise contribution to resonance phenomena and information propagation in non linear electronic networks

2015

This manuscript presents research aiming to show possible positive effects of deterministic and stochastic perturbations on the responses of different nonlinear systems. To that end, both numerical and experimental studies were carried out on two kinds of structures : an elementary electronic FitzHugh-Nagumo oscillator and an electrical line developed by resistively coupling 45 elementary cells. In the first section, the elementary cell characterization was undertaken in a deterministic regime. In the presence of a bichromatic stimulus, it is shown that when the low frequency component is subthreshold, its detection can be maximized for an optimal magnitude of the second component thanks to…

The lineshape of the electronic spectrum of the green fluorescent protein chromophore, part I: gas phase.

2014

The vibronic spectra of the green fluorescent protein chromophore analogues p-hydroxybenzylidene-2,3-dimethylimidazolinone (HBDI) and 3,5-tert-butyl-HBDI (35Bu) are similar in the vacuum, but very different in water or ethanol. To understand this difference, we have computed the vibrationally resolved solution spectra of these chromophores, using the polarizable continuum model (PCM) to account for solvent effects on the (harmonic) potential energy surfaces (PES). In agreement with experiment, we found that the vibrational progression increases with the polarity of the solvent, but we could neither reproduce the broadening, nor the large difference between the absorption spectra of HBDI and…

Application of FTIR Spectroscopy to Analyze RNA Structure

2020

Fourier transform infrared (FTIR) spectroscopy has been widely used for the analysis of both protein and nucleic acid secondary structure. This is one of the vibration spectroscopy methods that are extremely sensitive to any change in molecular structure. While numerous reports describe how to proceed to analyze protein and deoxyribonucleic acid (DNA) structures using FTIR, reports related to the analyses of ribonucleic acids (RNAs) are few. Nevertheless, RNAs are versatile molecules involved in a multitude of roles in the cell. In this chapter, we present applications of FTIR for the structural analysis of RNA, including the analysis of helical parameters and noncanonical base pairing, oft…

Interprétation tribologique de la perception tactile de surfaces texturées

2018

International audience; Ces dernières années, l’industrie a porté un intérêt grandissant à la qualité sensorielle de leurs produits, et notamment à la sensation tactile qu’ils procurent. Selon Hollins et al, l’ensemble des surfaces matérielles peuvent être définies selon quatre dimensions psycho-perceptives tactiles : « glissant/collant », « lisse/rugueux », « chaud/froid » et « dur/mou » [1]. La texturation de surface est un moyen de parvenir à la réalisation d’une variété de surfaces appartenant, du point de vue de la perception tactile, aux deux premières dimensions susnommées. Néanmoins, les liens entre les paramètres topographiques des textures et la sensation ressentie lors du toucher…

Protein dynamics: conformational disorder, vibrational coupling and anharmonicity in deoxy-hemoglobin and myoglobin.

1993

In this work we study the temperature dependence of the Soret band lineshape of deoxymyoglobin and deoxyhemoglobin, in the range 300-20 K. To fit the measured spectra we use an approach originally proposed by Champion and coworkers (Srajer et al. 1986; Srajer and Champion 1991). The band profile is modelled as a Voigt function that accounts for the coupling with low frequency vibrational modes, whereas the coupling with high frequency modes is responsible for the vibronic structure of the spectra. Moreover, owing to the position of the iron atom out of the mean heme plane, inhomogeneous broadening brings about a non-Gaussian distribution of 0-0 electronic transition frequencies. The reporte…

Dynamic properties of some β-chain mutant hemoglobins

1995

The thermal behavior of the Soret band relative to the carbonmonoxy derivatives of some beta-chain mutant hemoglobins is studied in the temperature range 300-10 K and compared to that of wild-type carbonmonoxy hemoglobin. The band profile at various temperatures is modeled as a Voigt function that accounts for homogeneous broadening and for the coupling with high- and low-frequency vibrational modes, while inhomogeneous broadening is taken into account with a gaussian distribution of purely electronic transition frequencies. The various contributions to the over-all bandwidth are singled out with this analysis and their temperature dependence, in turn, gives information on structural and dy…