Search results for "VIBRATION"
showing 10 items of 823 documents
Stato dell’arte degli interventi sul mezzo recettore e di propagazione per la mitigazione delle vibrazioni generate da sistemi di trasporto su ferro
2008
La generazione e la propagazione delle onde vibrazionali da una sorgente, ferroviaria o tranviaria, all’ambiente circostante è un problema complesso che risulta influenzato da vari fattori tra loro correlati: le caratteristiche e le condizioni della sovrastruttura, il peso, la velocità e le caratteristiche meccaniche del veicolo, le proprietà dinamiche e stratigrafiche del terreno, le caratteristiche dinamiche degli edifici recettori. Di tali aspetti occorre tenere conto ai fini della realizzazione di efficaci misure di mitigazione. Nella presente memoria vene riportato lo stato dell’arte relativo agli interventi sul mezzo di propagazione (suolo e sottosuolo) e sul mezzo recettore (opere di…
Raman and optical reflection spectra of germanate and silicate glasses
2005
Abstract Germanate and phosphosilicate glasses made in oxygen surplus conditions were studied by Raman and optical reflection methods. We found that the optical reflection spectra of the germanate glasses are quite similar to the one those of a GeO 2 crystal with the α-quartz structure. The reflection of phosphosilicate glasses is very close to silica glass-related spectra. Hence, the determining influence of the tetrahedral structure on reflection spectra is revealed. The Raman spectra of germanate samples are similar to those reported the one known in the literature. Octahedral entities, namely bands similar to stishovite vibration modes, were difficult to detect in phosphosilicate glasse…
INNOVATIVE MASS-DAMPING-BASED APPROACHES FOR SEISMIC DESIGN OF TALL BUILDINGS
2021
Mass damping is a well known principle for the reduction of structural vibrations and applied in tall building design in a variety of configurations. With mass usually small (around 1% of building mass), the properly “tuned” mass damper (TMD) shows great effectiveness in reduc-ing wind vibrations, but minor advantages under earthquake excitations. The above limitation can be surpassed by utilizing relatively large mass TMD. For this pur-pose, two different solutions are here proposed. In both cases, the idea is to separate the building into two or more parts, thus allowing for a relative motion between them, and acti-vating the mass damping mechanism. In the first solution, the building is …
Frequency composition of traction and tillage forces on a mole plough
1997
Field experiments were carried out in order to quantify the variations of the traction and tillage forces on a mole plough, in the case of four clayey soils of Eastern France. The same tractor-implement system, the same forward working speed (1 m s−1) and the same length of ploughing (20 m) were used. Specially designed strain gauge transducers applied to the system delivered a signal which was numerised and analysed in terms of power spectral density (PSD) function. The frequency composition of the traction and tillage forces consisted of interactions between soil and tool as well as vibrations of the tractor-implement system. Low frequencies (0–2 Hz range) were related to the random prope…
Dynamic Stabilization of the Ligand-Metal Interface in Atomically Precise Gold Nanoclusters Au68 and Au144 Protected by meta-Mercaptobenzoic Acid
2017
Ligand-stabilized, atomically precise gold nanoclusters with a metal core of a uniform size of just 1–3 nm constitute an interesting class of nanomaterials with versatile possibilities for applications due to their size-dependent properties and modifiable ligand layers. The key to extending the usability of the clusters in applications is to understand the chemical bonding in the ligand layer as a function of cluster size and ligand structure. Previously, it has been shown that monodispersed gold nanoclusters, stabilized by meta-mercaptobenzoic acid (m-MBA or 3-MBA) ligands and with sizes of 68–144 gold atoms, show ambient stability. Here we show that a combination of nuclear magnetic reson…
Experimental and theoretical studies on corals. I. Toward understanding the origin of color in precious red corals from Raman and IR spectroscopies a…
2009
An attempt to explain the origin of the vivid red color in precious pink and red corals was undertaken. Raman and IR spectroscopies were applied to characterize white, pink and red corals. The position of the Raman signal near 1500 cm −1 of some corals and pearls was associated by several authors with the presence of the mixture of all-trans-polyenic pigments, containing 6 – 16 conjugated C C bonds or β-carotenoids. This hypothesis was examined theoretically by performing extensive B3LYP-DFT calculations of vibrational spectra of the model polyenic compounds. The B3LYP/6-311++G ∗∗ predicted positions of the dominating Raman mode depend on the number of C Cu nits (Cn parameter) and can be ac…
The protein dynamical transition does not require the protein polypeptide chain
2011
We give experimental evidence that the main features of protein dynamics revealed by neutron scattering, i.e., the “protein dynamical transition” and the “boson peak”, do not need the protein polypeptide chain. We show that a rapid increase of hydrogen atoms fluctuations at about 220 K, analogous to the one observed in hydrated myoglobin powders, is also observed in a hydrated amino acids mixture with the chemical composition of myoglobin but lacking the polypeptide chain; in agreement with the protein behavior, the transition is abolished in the dry mixture. Further, an excess of low-frequency vibrational modes around 3 meV, typically observed in protein powders, is also observed in our mi…
Effect of physical aging on the low-frequency vibrational density of states of a glassy polymer
2003
The effects of the physical aging on the vibrational density of states (VDOS) of a polymeric glass is studied. The VDOS of a poly(methyl methacrylate) glass at low-energy (<15 meV), was determined from inelastic neutron scattering at low-temperature for two different physical thermodynamical states. One sample was annealed during a long time at temperature lower than Tg, and another was quenched from a temperature higher than Tg. It was found that the VDOS around the boson peak, relatively to the one at higher energy, decreases with the annealing at lower temperature than Tg, i.e., with the physical aging.
Analysis of the intensities of the longitudinal acoustic vibrations inn-alkanes and polyethylene
1980
Simple theoretical considerations indicate, that the integral intensity of the „longitudinal acoustic modes” (LAM) in the Raman spectrum ofn-alkanes should be independent of the chain length. The experiment in fact confirms this expectation. Using this property it becomes possible for polyethylene samples, to derive from the measured LAM-intensity the mass fraction of all-turns sequences contributing to this band. For solution crystallized samples this fraction coincides with the crystallinity, whereas in melt crystallized samples it generally turns out as smaller. The observed difference is likely to be due to the occurrence of local conformational defects (kinks, chain torsions) which int…
Vibronic structure in triatomic molecules : The hydrocarbon flame bands of the formyl radical (HCO). A theoretical study
1998
A theoretical study of the vibrational structure of the math 2A′ ground and math 2A′ excited states of the formyl radical, HCO, and its deuterated form, DCO, has been performed. The potential energy surfaces have been computed by means of a multiconfigurational perturbative method, CASPT2. The computed geometries and the harmonic and anharmonic frequencies are successfully compared to the available experimental information. The vibrational intensities of the transition math 2A′↔math 2A′ have been computed both for absorption and emission. The results lead to accurate determinations of several structural parameters and some reassignments of the vibrational transitions of the so-called hydroc…