Search results for "VISCOSITY"
showing 10 items of 542 documents
Investigation of compatibility of a dicyanate ester monomer and polysulfone by size-exclusion chromatography and viscometry
2003
The influence of solvent on the compatibility behaviour of Arocy B10, a cyanate ester monomer, and polysulfone (PSF) was investigated by means of dilute solution viscometry and of the preferential solvation parameter at 25 °C. The ternary systems under study are: tetrahydrofuran/Arocy B10/polysulfone (PSF), N,N-dimethylformamide/Arocy B10/PSF and dichloromethane/Arocy B10/PSF. Values of the specific viscosity of PSF in a ‘binary solvent’ formed by Arocy B10 + solvent have been used to determine the compatibility of the polymer blend Arocy B10/PSF. An interaction parameter Δb that depends on concentration has been determined. The preferential solvation parameter was measured by size-exclusio…
Jacobian-free approximate solvers for hyperbolic systems: Application to relativistic magnetohydrodynamics
2017
Abstract We present recent advances in PVM (Polynomial Viscosity Matrix) methods based on internal approximations to the absolute value function, and compare them with Chebyshev-based PVM solvers. These solvers only require a bound on the maximum wave speed, so no spectral decomposition is needed. Another important feature of the proposed methods is that they are suitable to be written in Jacobian-free form, in which only evaluations of the physical flux are used. This is particularly interesting when considering systems for which the Jacobians involve complex expressions, e.g., the relativistic magnetohydrodynamics (RMHD) equations. On the other hand, the proposed Jacobian-free solvers hav…
Jacobian-Free Incomplete Riemann Solvers
2018
The purpose of this work is to present some recent developments about incomplete Riemann solvers for general hyperbolic systems. Polynomial Viscosity Matrix (PVM) methods based on internal approximations to the absolute value function are introduced, and they are compared with Chebyshev-based PVM solvers. These solvers only require a bound on the maximum wave speed, so no spectral decomposition is needed. Moreover, they can be written in Jacobian-free form, in which only evaluations of the physical flux are used. This is particularly interesting when considering systems for which the Jacobians involve complex expressions. Some numerical experiments involving the relativistic magnetohydrodyn…
Characterization of blends of polypropylene with a semirigid liquid-crystal copolyester
1991
Abstract Blends with a liquid-crystal polymers (LCP) as one component show, in general, very interesting properties. Reduction of shear viscosity and improvement of mechanical properties are very remarkable. High melting temperatures and high costs of the LCP limit the use of these blends. A new class of thermotropic LCPs with flexible spaces, with relatively low melting temperatures, can overcome the first problem. In this work, rheological and mechanical properties of blends of polypropylene with low contents of this LCP are presented. Torque during extrusion and viscosity decrease with LCP content. Elastic modulus is remarkably increased when the LCP phase is oriented.
Thermomechanical degradation of filled polypropylene
2003
The main problem in post-consumer plastics recycling is due to the thermomechanical stress acting on the melt during the reprocessing operations. The macromolecules break because of the temperature and of the mechanical stress. The extent of degradation is then correlated to the level of mechanical stress which, in turn, is proportional to the viscosity of the melt. The presence of fillers increases the viscosity of the polymers and then it is expected that the level of thermomechanical degradation of these systems is larger than that of the unfilled material. In this work the thermomechanical degradation kinetic of a polypropylene sample is investigated as a function of the calcium carbona…
Multifunctional polyurethane foams with thermal energy storage/release capability
2020
In this work, polyurethane (PU) insulating panels containing different amounts of a microencapsulated paraffin with a nominal melting temperature of 24 °C, used as phase change material (PCM), were produced. The resulting panels behaved as multifunctional materials able to thermally insulate and simultaneously storing/releasing thermal energy near room temperature. The panels were characterized from a microstructural, thermal and mechanical point of view. Viscosity measurements highlighted an increase in the viscosity values of the PU liquid precursors due to the addition of the capsules, and this could lead to some difficulties during the production stages, especially in the mixing and foa…
Singularity formation and separation phenomena in boundary layer theory
2009
In this paper we review some results concerning the behaviour of the incompressible Navier–Stokes solutions in the zero viscosity limit. Most of the emphasis is put on the phenomena occurring in the boundary layer created when the no-slip condition is imposed. Numerical simulations are used to explore the limits of the theory. We also consider the case of 2D vortex layers, i.e. flows with internal layers in the form of a rapid variation, across a curve, of the tangential velocity.
Singularities for Prandtl's equations.
2006
We used a mixed spectral/finite-difference numerical method to investigate the possibility of a finite time blow-up of the solutions of Prandtl's equations for the case of the impulsively started cylinder. Our toll is the complex singularity tracking method. We show that a cubic root singularity seems to develop, in a time that can be made arbitrarily short, from a class of data uniformely bounded in H^1.
Two-phase flow of liquid–liquid mixture in the range of the water droplet pattern
2002
Abstract Phenomena accompanying flow of water–oil mixture during droplet flow of water in oil have been described. Aims used in the determination of characteristic parameters in two-phase liquid–liquid flow have been presented. The method for calculating the equivalent viscosity and pressure drop during flow of liquid–liquid mixture in the range of the water droplet pattern has been given.
$C^{1,��}$ regularity for the normalized $p$-Poisson problem
2017
We consider the normalized $p$-Poisson problem $$-��^N_p u=f \qquad \text{in}\quad ��.$$ The normalized $p$-Laplacian $��_p^{N}u:=|D u|^{2-p}��_p u$ is in non-divergence form and arises for example from stochastic games. We prove $C^{1,��}_{loc}$ regularity with nearly optimal $��$ for viscosity solutions of this problem. In the case $f\in L^{\infty}\cap C$ and $p>1$ we use methods both from viscosity and weak theory, whereas in the case $f\in L^q\cap C$, $q>\max(n,\frac p2,2)$, and $p>2$ we rely on the tools of nonlinear potential theory.