Search results for "Vapo"
showing 10 items of 1217 documents
The chemistry of acetone at extreme conditions by density functional molecular dynamics simulations
2011
Density functional molecular dynamics simulations have been performed in the NVT ensemble (moles (N), volume (V) and temperature (T)) on a system formed by ten acetone molecules at a temperature of 2000 K and density ρ = 1.322 g cm(-3). These conditions resemble closely those realized at the interface of an acetone vapor bubble in the early stages of supercompression experiments and result in an average pressure of 5 GPa. Two relevant reactive events occur during the simulation: the condensation of two acetone molecules to give hexane-2,5-dione and dihydrogen and the isomerization to the enolic propen-2-ol form. The mechanisms of these events are discussed in detail.
Isobaric vapor–liquid equilibria for the system 1-pentanol–1-propanol–water at 101.3 kPa
2001
Consistent vapor–liquid equilibrium data for the ternary system 1-pentanol–1-propanol–water is reported at 101.3 kPa at temperatures in the range of 362–393 K. The VLE data were satisfactorily correlated with UNIQUAC model. The authors wish to thank the Generalitat Valenciana (Spain) for the financial help of the Project GV-3174/95 and DGES for the financial aids of the Project PB96-0338.
Development of a general model to estimate the instantaneous, daily, and daytime net radiation with satellite data on clear-sky days
2015
Net radiation is a key variable in computing evapotranspiration and is a driving force in many other physical and biological processes. Remote sensing techniques provide an unparalleled spatial and temporal coverage of land-surface attributes, and thus several studies have attempted to estimate net radiation by combining remote sensing observations with surface and atmospheric data. However, remote sensing provides instantaneous data, when many applications and models need information at other temporal scales. In this work, a new general methodology is proposed to estimate daily and daytime net radiation and to retrieve the diurnal cycle of net radiation. Four images were acquired on differ…
Evaluation of Terra/MODIS atmospheric profiles product (MOD07) over the Iberian Peninsula: a comparison with radiosonde stations
2014
Remote sensing techniques are a useful tool for continuous observation of the Earth at global scale. However, products derived from remote sensing data require a rigorous validation using in situ data. Moderate Resolution Imaging Spectroradiometer (MODIS) is not really a sounding instrument, but it does have 16 infrared bands (bands 20–36 covering the spectral range from 3 µm to 14 µm) that allow the retrieval of temperature and moisture profiles as well as total column integrated magnitudes. In this paper we show the results obtained in the evaluation of MOD07 daytime and nighttime products over the Iberian Peninsula during the decade from 2000 to 2010 using nine radiosonde stations. Altho…
Analyzing the anisotropy of thermal infrared emissivity over arid regions using a new MODIS land surface temperature and emissivity product (MOD21)
2015
Abstract The MOD21 Land Surface Temperature and Emissivity (LST&E) product will be included in forthcoming Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 6. Surface temperature and emissivities for thermal bands 29 (8.55 μm), 31 (11 μm) and 32 (12 μm) will be retrieved using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Temperature and Emissivity Separation (TES) method adapted to MODIS at-sensor spectral radiances, previously corrected with the Water Vapor Scaling method (MOD21 algorithm). We simulated MOD21 product estimates over two different sandy deserts (i.e. White Sands and Great Sands) using a series of MODIS scenes from 2010 to 2013. T…
Eulerian-Eulerian modelling and computational fluid dynamics simulation of wire mesh demisters in MSF plants
2014
Purpose – The purpose of this study is to focus on simulation of wire mesh demisters in multistage flash desalination (MSF) plants. The simulation is made by the use of computational fluid dynamics (CFD) software. Design/methodology/approach – A steady state and two-dimensional (2D) model was developed to simulate the demister. The model employs an Eulerian-Eulerian approach to simulate the flow of water vapor and brine droplets in the demister. The computational domain included three zones, which are the vapor space above and below the demister and the demister. The demister zone was modeled as a tube bank arrange or as a porous media. Findings – Sensitivity analysis of the model showed t…
Eulerian–Lagrangian modeling and computational fluid dynamics simulation of wire mesh demisters in MSF plants
2016
Abstract This study focuses on computational fluid dynamics model (CFD) for simulation of demisters in multistage flash desalination (MSF). The Eulerian–Lagrangian model (steady-state and two-dimensional) was developed to simulate the demister. The model was used to simulate the flow of water vapor and brine droplets in the demister. The computational domain includes the following three zones: the vapor space above the demister, the vapor space below the demister, and the demister. The demister zone was modeled as tube banks. A sensitivity analysis of the model revealed that vapor velocity is the main parameter that affects demister performance. Additionally, the analysis indicated that vap…
η⇌μ exchange bonding mode of bidentate tmeda ligand. Molecular structure of [Y(tmhd)3]2(μ-tmeda)
2003
Abstract The reaction between the yttrium β-diketonate complexes Y(tmhd)3(H2O)x (x=0 or 1) and 0.5 or 1 equivalent of N,N,N′,N′-tetramethylethylenediamine (tmeda=Me2NCH2CH2NMe2) in hexane at room temperature afforded [Y(tmhd)3]2(tmeda) (1) and Y(tmhd)3(tmeda) (2) derivatives, respectively. They have been characterized by FT-IR, 1H NMR spectroscopy and by single crystal X-ray diffraction for 1. Variable temperature 1H NMR experiments indicated an equilibrium between 1 and 2. Their thermal behaviors were characterized by TGA and sublimation experiments. 2 is converted into compound 1 by heating over 100 °C. These precursors were used for the growth of Y2O3 and YBa2Cu3O7 − x films by pulsed in…
Exergy analysis and thermoeconomic cost accounting of a CHP steam cycle integrated with MED-TVC desalination
2016
In this paper exergy analysis and thermoeconomic cost accounting of a CHP steam cycle integrated with MED-TVC plant is performed; the purpose is to show how this methodology provides a rational criterion to allocate production costs on electricity and freshwater. After a brief overview on methodology and a description of reference plant, exergy analysis is carried out in order to calculate exergy flows and plant exergetic performance. A detailed description of the adopted thermoeconomic model is given. Cost accounting is performed considering two scenarios: in the first, the concentrated brine is disposed back to sea, thus being its exergy content definitively wasted; in the second, convers…
Energy performance improvements of a DEC system due to wet heat exchangers
2011
This work concerns an innovative desiccant and evaporative cooling (DEC) system for building air conditioning. The original system is an experimental DEC air handling unit installed at the Solar Laboratory of the University of Palermo and recently modified and updated. With the aim to increase the cooling effect due to water evaporation in the return air flow rate, the sensible heat exchanger was replaced with two cross flow flat plate heat exchangers installed in series, with continuous humidification of the secondary air flow. The new thermodynamic cycle is theoretically described and the realization of the real application is shown. Detailed operational data and energy performance indica…