Search results for "Volt"
showing 10 items of 2187 documents
Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles
2012
Two complementary models to describe the long-term corrosion of silver-copper coins, based on potential rate laws for smooth corrosion and those combined with diffusive law, for gross corrosion, are proposed. Theoretical kinetics can be tested using signatures of copper and silver corrosion products using the voltammetry of immobilized particles technique. The method is applied to silver coins minted during the 13th–14th centuries from the Libertad street hoard in Valencia (Spain) using non-invasive one-touch graphite pencil sampling. Voltammetric features yield functional dependences in agreement with the proposed model potentially useful for distinguishing between different mints.
Designing voltage multipliers with nanofluidic diodes immersed in aqueous salt solutions.
2016
[EN] Membranes with nanofluidic diodes allow the selective control of molecules in physiological salt solutions at ambient temperature. The electrical coupling of the membranes with conventional electronic elements such as capacitors suggests opportunities for the external monitoring of sensors and actuators. We demonstrate experimentally and theoretically the voltage multiplier functionality of simple electrical networks composed of membranes with conical nanopores coupled to load capacitors. The robust operation of half and full wave voltage multipliers is achieved in a broad range of experimental conditions (single pore and multipore membranes, electrolyte concentrations, voltage amplitu…
Origin of the substrate current after soft-breakdown in thin oxide n-MOSFETs
1999
In this paper is presented an experimental investigation on the origin of the substrate current after soft-breakdown in n-MOSFETs with 4.5 nm-thick oxide. At lower voltages this current shows a plateau that can be explained with the generation of hole-electron pairs in the space charge region and at the Si-SiO2 interface, and to carrier diffusion between the channel and the substrate. At higher voltages the substrate current steeply increases with voltage, due to trap-assisted tunneling from the substrate valence band to the gate conduction band, which becomes possible for gate voltages higher than the threshold voltage. Measurements on several devices at dark and in the presence of light, …
Tunable Wide‐Bandgap Monohalide Perovskites
2020
Herein the mechanochemical synthesis of inorganic as well as hybrid organic-inorganic monohalide perovskites with tunable bandgaps is reported. It is shown that the bandgap bowing known for iodide mixed Sn-Pb perovskites is also present in the pure bromide analogous. This results in technologically very interesting materials with bandgaps in the range of 1.7-1.9 eV. Similar bandgap perovskites are typically achieved by mixing two halides that are prone to segregate over time. This limits the achievable open circuit voltage. For monohalide perovskites this problem is eliminated, making these materials especially promising wide bandgap absorbers for tandem solar cells. Perovskite Thin-film Ph…
Metal Chalcohalides: Next Generation Photovoltaic Materials?
2021
Metal chalcohalides have recently been highlighted as so-far overlooked semiconductors that could play an important role in the future of photovoltaics (PV). Indeed, the blooming field of emergent PV technologies is still in search for stable, efficient, and environmentally-friendly light-harvesting materials to be used either in single-junction solar cells or multijunction devices in combination with silicon or another absorbers. Under the broad terms of metal chalcohalides, there exists a plethora of semiconductor materials with different chemical, structural, and optoelectronic characteristics. While some have already been implemented in solar cells with power conversion efficiencies up …
FAPb0.5Sn0.5I3: A Narrow Bandgap Perovskite Synthesized through Evaporation Methods for Solar Cell Applications
2020
The tunability of the optoelectrical properties upon compositional modification is a key characteristic of metal halide perovskites. In particular, bandgaps narrower than those in conventional lead‐based perovskites are essential to achieve the theoretical efficiency limit of single‐absorber solar cells, as well as develop multijunction tandem devices. Herein, the solvent‐free vacuum deposition of a narrow bandgap perovskite based on tin-lead metal and formamidinium cation is reported. Pinhole‐free films with 1.28 eV bandgap are obtained by thermal codeposition of precursors. The optoelectrical quality of these films is demonstrated by their use in solar cells with a power conversion effici…
Low Temperature, Vacuum-Processed Bismuth Triiodide Solar Cells with Organic Small-Molecule Hole Transport Bilayer
2021
Herein, the preparation of fully vacuum-processed bismuth triiodide solar cells with low annealing temperature is reported. Planar n-i-p devices are prepared using a thin compact SnO2 layer as the electron extraction layer and an electron blocking/hole extraction bilayer consisting of an intrinsic and doped organic hole-transport molecule. Using this configuration, herein, higher fill-factors and overall power conversion efficiencies than with conventional solution-processed hole transport materials are achieved.
Charge transport properties in CdZnTe detectors grown by the vertical Bridgman technique
2011
Presently, a great amount of effort is being devoted to the development of CdTe and CdZnTe (CZT) detectors for a large variety of applications such as medical, industrial, and space research. We present the spectroscopic properties of some CZT crystals grown by the standard vertical Bridgman method and by the boron oxide encapsulated vertical Bridgman method, which has been recently implemented at IMEM-CNR (Parma, Italy). In this technique, the crystal is grown in an open quartz crucible fully encapsulated by a thin layer of liquid boron oxide. This method prevents contact between the crystal and the crucible, thereby allowing larger single grains with a lower dislocation density to be obta…
Comparison of two portable solid state detectors with an improved collimation and alignment device for mammographic x-ray spectroscopy
2006
We describe a portable system for mammographic x-ray spectroscopy, based on a 2 X 2 X 1 mm3 cadmium telluride (CdTe) solid state detector, that is greatly improved over a similar system based on a 3 X 3 X 2 mm3 cadmium zinc telluride (CZT) solid state detector evaluated in an earlier work. The CdTe system utilized new pinhole collimators and an alignment device that facilitated measurement of mammographic x-ray spectra. Mammographic x-ray spectra acquired by each system were comparable. Half value layer measurements obtained using an ion chamber agreed closely with those derived from the x-ray spectra measured by either detector. The faster electronics and other features of the CdTe detecto…
Dynamic doping in bright and stable light emitting electrochemical cells.
2013
By using fast current density and luminance versus voltage (JL-V) analysis the device operation of sandwiched light emitting electrochemical cells (LECs) during their normal voltage driving operation mode is studied. In LECs the application of a voltage results in the movement of ions changing the state of the device, as a result the JL-V scans need to be performed fast and meet certain conditions to be meaningful. Space-charge limited current behavior is observed once the injection barriers are overcome. The increase of the current density after this point imply that the effective thickness of the devices is reduced which indicates the formation of more conductive regions adjacent to the e…