Search results for "WASTE"

Illustration of constrained composition statistical methods in the interpretation of radionuclide concentrations in the moss Pleurozium schreberi.

2013

In this work we have used moss Pleurozium schreberi as a bioindicator of radioactive materials in environment. The following radionuclides were determined in moss samples: (137)Cs, (40)K, (210)Pb, (212)Pb, (214)Pb, (214)Bi, (231)Th, (235)U and (228)Ac, but not all of them in each sample. The highest activity concentrations were found for naturally occurring (210)Pb, (40)K and the artificial isotope (137)Cs. Activities of radioisotopes were recalculated into mass concentrations and the statistical methods intended for constrained data processing were used. Analysis of our results showed at most a weak relationship between radioisotope mass concentrations in moss. It was supposed that concent…

Assessment of Gamma Dose Rate at Mine Waste Dump

2013

Abstract Exploitation of coal deposits in Upper Silesia is associated with production of large quantities of waste deposited at dumps. The tested samples from five dumps showed different radioactivity from each other. Radioactivity measurements made it possible to analyze the degree of risk with the factors specified by UNSCEAR such as radium equivalent activity Raeq, internal Ein and external Eex occupancy factor. There is a raised level of radiation in dumps as compared with outside dump areas. In the study area, however, there is no risk associated with elevated levels of radiation in relation to standards established by the Council of Ministers of the ionizing radiation dose limits.

Naturally occurring137Cs,90Sr and226Ra radionuclides in raw milk in the Sibiu province of Romania

2012

Milk is a sensitive indicator of the levels of contamination existing in the environment following nuclear incidents, for example at Chernobyl 1986 (Ukraine) and the most recent one in 2011 in Fukushima (Japan). The levels of three radionuclides, caesium 137Cs, strontium 90Sr and radium 226Ra, were determined in cow’s milk from various locations of Sibiu county from 2010 to 2011. The results were compared with the results taken after the explosion at Chernobyl in 1986. The values were within normal limits with insignificant increases of the milk that was collected in the area of Copsa-Mica and Sibiu.

Effects of radiation and hydrogen-loading on the performances of raman-distributed temperature fiber sensors

2015

International audience; The integration of Raman-distributed temperature fiber-based sensors (RDTS) into the envisioned French deep geological repository for nuclear wastes, called Cigéo requires evaluating how the performances of RDTS evolve in harsh environments, more precisely in presence of H2 or γ-rays. Both H2 and radiations are shown to affect the temperature measurements made with the single-ended RDTS technology. The amplitudes of the observed effects depend on the different classes of multimode fibers varying in terms of composition and coatings. By selecting the most tolerant fiber structure for the sensing, we could maintain the RDTS performances for such application. A hardeni…

Oczyszczanie ścieków w mikrobiologicznym ogniwie paliwowym z katodą z niklu Raneya

2016

SOLAR DESALINATION: A CHALLENGE FOR SUSTAINABLE FRESH WATER IN THE 21ST CENTURY

2007

generate a sustainable source of fresh water as well as energy. This combination is highly valued as it limits and reduces air pollutant emissions and green house gases generated by combustion of fossil fuels. Increase in energy demand during the first half of this century is expected to continue, which makes the cost of renewable solar energy highly competitive against fossil fuels. Desalination has been relied on to provide fresh water for large cities and countries across the world. The desalination industry continues to grow in countries in arid regions. Various aspects of solar desalination processes, solar energy, and conventional desalination are discussed. Scenarios for combination …

Laser Ablation of Poly(lactic acid) Sheets for the Rapid Prototyping of Sustainable, Single-Use, Disposable Medical Microcomponents

2018

The employment of single-use, disposable medical equipment has increased the amount of medical waste produced and the advent of point-of-care diagnostics in lab-on-chip format is likely to add further volume. Current materials used for the manufacture of these devices are derived from petroleum sources and are, therefore, unsustainable. In addition, disposal of these plastics necessitates combustion to reduce infection risk, which has, depending on material composition, an undesirable environmental impact. To address these issues, we have developed a general approach for the rapid prototyping of single-use point-of-care cartridges prepared from poly(lactic acid), a sustainable material whic…

Thermal characterisation of Bio Based Building Materials

2006

This paper describes how the characterization of indigenous renewable biomass sources that are applicable for making bio-based building (BBB) materials is crucial as it can significantly affect the cost of production and the quality of material. Nowadays, in any specific area, wide ranges of biomass sources are usually available but only a few sources may be suitable for making BBB material. Therefore the suited sources should be determined. In this paper, the use of BBB materials is focused on Insulation Materials which are widely used in the buildings. Compared with currently used materials, these materials are bio-degradable. Insulation material with a good energy-adsorbing property and …

Nickel-catalyzed carboxylation of aryl zinc reagent with CO2: A theoretical and experimental study

2019

Abstract Two Ni-complexes with 1,1′-bis(diphenylphosphino)ferrocene (dppf) and tricyclohexylphosphine (PCy3) ligands were tested for the Ni-catalyzed cross-coupling of aryl zinc reagent with CO2 to form aryl carboxylic acid. Theoretical study with the aid of density functional theory (DFT) was carried out to understand the detailed reaction mechanism. The reasonable reaction pathway was deduced. The simulation results suggested that the free energy barrier of the rate-limiting step with (dppf)Ni is only 1.64 kcal mol−1 higher than the barrier with (PCy3)2Ni. However, our experiment provided an unexpectedly low yield by using (dppf)Ni complex as the catalyst. Further theoretical study ascrib…

Kinetics of homogeneous catalytic chlorination of acetic acid

2007

The kinetics of the chlorination of acetic acid (HAc) to monochloroacetic acid (MCA) and the physical solubility of chlorine in HAc and its mixtures with MCA were investigated in a laboratory scale semibatch reactor. The temperature dependence of the Henry's constant was determined from solubility data obtained at temperatures between 70°C and 110°C. The kinetic experiments were performed at 75–100°C with 3–13 mol % acetyl chloride (AcCl) and 0–5 weight % H2SO4 added as catalysts. Gas chromatography was used to determine the concentrations of HAc, MCA, dichloroacetic acid and AcCl during the experiments. The results indicate that the reaction rate is independent of the concentrations of HAc…