Search results for "WEIGHT"
showing 10 items of 2980 documents
Keyhole Limpet Hemocyanin Type 2 (KLH2): Detection and Immunolocalization of a Labile Functional Unit h
2000
Keyhole limpet hemocyanin (KLH) is a mixture of two hemocyanin isoforms, termed KLH1 and KLH2. Within KLH1 eight oxygen-binding functional units (FUs), 1-a to 1-h, have been identified, in contrast to KLH2, which was previously thought to be organized in seven FUs (2-a to 2-g). By limited proteolysis of KLH2 subunits, isolation of the polypeptide fragments, and N-terminal sequencing, we have now identified an eighth FU of type h, with a molecular mass of 43 kDa. This is unusually small for a FU h from a gastropodan hemocyanin. It is also shown that KLH2 didecamers can be split into a stable and homogeneous population of decamers by dialysis against 50 mM Tris/HCl, pH 7.5, in the absence of …
Comparative toxicity and cell-tissue distribution study on nanoparticular iron complexes using avian embryos and HepG2-cells
2007
In this study the toxicity and intracellular availability of iron from iron dextran (FeD), iron sucrose (FeS), and iron gluconate (FeG) was compared in organs of avian (turkey) embryos and in isolated cells (HepG2) in cell culture. Iron uptake was more pronounced in embryonic liver than in renal tissue. Cellular iron uptake in liver and kidney was more or less similar for the different compounds. Only some experiments showed slightly greater iron concentrations in liver and kidney with FeG compared with FeD and FeS. Significant differences were found in the survival ratios of the eggs and the embryo weights depending on the type of iron complex administered. The rank order of toxicities was…
Purification and spectroscopic studies on catechol oxidases from Lycopus europaeus and Populus nigra: evidence for a dinuclear copper center of type …
1999
We purified two catechol oxidases from Lycopus europaeus and Populus nigra which only catalyze the oxidation of catechols to quinones without hydroxylating tyrosine. The molecular mass of the Lycopus enzyme was determined to 39,800 Da and the mass of the Populus enzyme was determined to 56,050 Da. Both catechol oxidases are inhibited by thiourea, N-phenylthiourea, dithiocarbamate, and cyanide, but show different pH behavior using catechol as substrate. Atomic absorption spectrosopic analysis found 1.5 copper atoms per protein molecule. Using EPR spectroscopy we determined 1.8 Cu per molecule catechol oxidase. Furthermore, EPR spectroscopy demonstrated that catechol oxidase is a copper enzym…
Effect of electron beam irradiation and plastic deformation on molar mass of medical grade ultra-high molecular weight polyethylene
2010
Badano wpływ sterylizacji metodą napromieniania strumieniem elektronów oraz deformacji plastycznej (zgniatania, rys. 1) polietylenu ultrawielkocząsteczkowego (UHMW-PE), stosowanego do wytwarzania panewek endoprotez stawu biodrowego, na masę molową polimeru. Stwierdzono, że sterylizacja wpływa na utleniającą destrukcję makrocząsteczek polimeru, której stopień zależy od użytej dawki promieniowania (zmniejszenie masy molowej masowo średniej). Procesowi temu towarzyszy sieciowanie makrocząsteczek (wzrost udziału frakcji nierozpuszczalnej). Z kolei sama deformacja plastyczna wydaje się nie mieć wyraźnego wpływu na proces degradacji. Tymczasem łączne zastosowanie obydwu czynników zewnętrznych pro…
The Effect of Impact Pressure on Positron Lifetime in Ultra High Molecular Weight Polyethylene (PE-UHMW)Chirulen®1120
2010
The paper presents the results of investigations of the effect of impact pressure (in the range of both elastic and plastic deformations) on the parameters of the positron lifetime spectra in PE-UMHW polymer known under the trade mark Chirulen1120. The changes in the long-living component of the positron lifetime spectrum, connected with the annihilation of o-Ps in the pick-off process, are analyzed in dependence on the impact energy. The impact duration in the Charpy’s tests depending on the impact energy was measured, too. The dependencies of the radius of the volume of empty spaces in which the positronium annihilates, on the impact pressure were determined applying the Eldrup-Tao model.
Immobilization of natural anti-oxidants on carbon nanotubes and aging behavior of ultra-high molecular weight polyethylene-based nanocomposites
2014
The use of natural antioxidants is an attractive way to formulate nanocomposites with extended durability and with potential applications in bio-medical field. In this work, Vitamin E (VE) in the form of α-tocopherol and Quercetin (Q) are physically immobilized on the outer surface of multi-walled carbon nanotubes (CNTs). Afterward, the CNTs-VE and CNTs-Q are used to formulate thermally stable ultra high molecular weight polyethylene based nanocomposites. The obtained results in the study of the thermo-oxidation behavior suggest a beneficial effect of the natural anti-oxidant carbon nanotubes systems. The unexpected excellent thermo-resistance of the nanocomposites seems to be due to a syne…
α-Tocopherol-induced radical scavenging activity in carbon nanotubes for thermo-oxidation resistant ultra-high molecular weight polyethylene-based na…
2014
?-Tocopherol, a natural antioxidant molecule, was physically immobilized on the outer surface of multi-walled carbon nanotubes (CNTs), and the resulting functionalised particles (f-CNTs) were dispersed in ultra-high molecular weight polyethylene aiming at improving its thermo-oxidation resistance. The success of the functionalization was assessed through spectroscopic and thermal analysis, and the influence of the filler on the thermo-oxidative stability of the nanocomposites was investigated through rheological analyses and infrared spectroscopy. We found that the addition of only 1 wt.% of f-CNTs brings about a surprisingly high oxidation resistance, with a five/ten-fold increase of the i…
Synthesis of Ultra-High-Molecular-Weight Polyethylene
1984
The catalytic activity of organometallic Ti-Al complexes with donor ligands in the low-pressure polymerization of ethylene was studied. These complexes were obtained by the reaction of ethylaluminium compounds like AlEt2Cl or Al2Et3Cl3 and titanium compound of the type Ti(OR)nCl4-n (where: R = C2—C10 alkyl, C6H5, C6H4X; X — m-CH3, p-CH3, m-OCH3, p-OCH3, m-Cl, p-Cl, p-Br; n = 1—4). The optimum conditions for the synthesis of these compounds, as well as their physico-chemical properties were studied by means of EPR and polarographic methods. The effect of the type and number of OR ligands in a catalytic system on the yield of polyethylene and on its properties was examined. Ti-Al catalysts wi…
Remarks on the environmental adaptation of man.
1971
In this paper the geographical variability of some morphological, physiological and serological traits of man is discussed with respect to the question, how far this variability can be considered as the result of selective adaptation processes. Though there is already some evidence supporting such an assumption, much more detailed and exactly planned research is necessary to clear the indubitable relations between the distribution patterns of anthropological traits and the various environmental conditions of human biotops. Particularly much more work is required to understand the causative mechanisms on which these relations are based.
Classical operators on weighted Banach spaces of entire functions
2013
We study the operators of differentiation and of integration and the Hardy operator on weighted Banach spaces of entire functions. We estimate the norm of the operators, study the spectrum, and analyze when they are surjective, power bounded, hypercyclic, and (uniformly) mean ergodic.