Search results for "Wavenumber"
showing 10 items of 35 documents
A mathematical study on effective wavenumber, an operative computation procedure, and its use with radiance-temperature relationships
2003
In this paper we study the existence of effective wavenumber for any sensor by means of simple mathematics. We implement a numeric algorithm, based on the developed mathematical background, into a computer program named 'srf2radi', which is freely available via anonymous File Transfer Protocol (FTP) at ftp://ftp.uv.es/pub/src/. The number of effective wavenumbers for each temperature and their accuracy are also computed and studied for NOAA-16 Advanced Very High Resolution Radiometer Version 3 (AVHRR/3) channel 4. These effective wavenumbers can be used to obtain radiance-temperature relationships with physical meaning for any sensor in user-defined temperature intervals.
Raman spectra of (PbS)1.18(TiS2)2 misfit compound
2007
Abstract A Raman study on the (PbS)1.18(TiS2)2 semiconductor structure with incommensurate layers (misfit) is reported. The different bands observed in the spectra are attributed to both the TiS2 host layers, at 219 (Eg) and 333 (A1g) cm−1, and the intercalated PbS layers: the LO(Γ), 2LO and 3LO phonons at 203, 412 and 634 cm−1, respectively. A phonon peak probably related to the superposition of TiS2 and PbS vibrations, was observed near 286 cm−1. The decrease of the phonon wave numbers (of the modes located at 203, 333, 412, and 634 cm−1) with increasing laser power pointed out negative temperature coefficients of these modes. A peak appearing with laser power near 151 cm−1 is discussed. …
DFT studies on the structural and vibrational properties of polyenes
2015
Detailed density functional theory (DFT) calculations on the structure and harmonic frequencies of model all-trans and all-cis polyenes were undertaken. For the first time, we report on the convergence of selected B3LYP/6-311++G** and BLYP/6-311++G** calculated structural parameters resulting from a systematic increase in polyene size (chains containing 2 to 14 C = C units). The limiting values of the structural parameters for very long chains were estimated using simple three-parameter empirical formulae. BLYP/6-311++G** calculated ν(C = C) and ν(C–C) frequencies for all-trans and all-cis polyenes containing up to 14 carbon–carbon double bonds were used to estimate these values for very lo…
Computer simulations of SiO2 and GeO2
2004
Classical Molecular Dynamics (MD) simulations are used to study structural and dynamic properties of amorphous germania (GeO2) in comparison to those of silica (SiO2). The total structure factor, as obtained from these simulations, is in very good agreement with that of neutron scattering experiments, both for germania and silica. The tetrahedral network structure in silica and germania leads to a prepeak in the structure factor that appears at slightly smaller wavenumbers in GeO2 than in SiO2. At high temperatures the diffusion constants are very similar in both systems whereas at low temperatures diffusion is significantly faster in germania than in silica. We also outline the strategy fo…
Discerning the Origins of the Amplitude Fluctuations in Dynamic Raman Nanospectroscopy
2012
International audience; We introduce a novel experimental and analytical method for discerning rare surface-enhanced Raman scattering (SERS) events observable at the nanoscale. We show that the kinetics of the Raman activity recorded on an isolated nanostructure is punctuated by intense and rare events of large amplitude and spectral variations. The fluctuations of thousands of SERS spectra were analyzed statistically in terms of power density functions, and the occurrence of the rare events was quantified by a wavenumber statistics. Our analysis enables one to extract valuable and unique spectroscopic signature of Raman variations usually hidden in time-average or space-average measurement…
Investigations of Low Temperature Phase Transitions in BiFeO3Ceramic by Infrared Spectroscopy
2011
In this paper, results of new infrared FIR-MIR measurements (wavenumber range of 4000–100 cm−1) in the range of the temperature 300 ÷ 8 K of the BiFeO3 ceramic are presented. Below 200 K only one symmetric band at ca. 800 cm−1 is visible. The full width at half maximum of this band decreases exponentially on cooling. The shape of the band at ca. 545 cm−1connected with A1 (TO) mode also changes between 60–40 K, this is in the vicinity of the phase transition at 50 K. Initially a broad band reveals its components as shoulder bands. Theirs FWHM decrease with cooling.
Inter-Chain Structure Factors of Flexible Polymers in Solutions: A Monte Carlo Investigation
1997
Off-lattice Monte Carlo simulations of both the single chain structure factor h(q) and the inter-chain structure factor HD(q) of flexible polymers in solutions are presented over a wide range of both wavenumber q and concentration c from the dilute to the concentrated regime, for chain lengths up to N = 256. The single chain properties $\{$gyration radius 〈Rg2〉, $h(q)\}$ are in reasonable agreement with the expected theoretical behavior, showing a crossover from swollen chains $\{\langle R_{\rm g}^2\rangle \propto N^{2\nu} ,~ h(q) \propto q^{-1/\nu}\}$ to Gaussian chains, and the data comply with a scaling description, with a correlation length ξ∝c-ν/(3ν-1). However, the inter-chain structu…
Surface waves in solar granulation observed with {\sc Sunrise}
2010
Solar oscillations are expected to be excited by turbulent flows in the intergranular lanes near the solar surface. Time series recorded by the IMaX instrument aboard the {\sc Sunrise} observatory reveal solar oscillations at high resolution, which allow studying the properties of oscillations with short wavelengths. We analyze two times series with synchronous recordings of Doppler velocity and continuum intensity images with durations of 32\thinspace min and 23\thinspace min, resp., recorded close to the disk center of the Sun to study the propagation and excitation of solar acoustic oscillations. In the Doppler velocity data, both the standing acoustic waves and the short-lived, high-deg…
Vibrational excitations in systems with correlated disorder
2007
We investigate a $d$-dimensional model ($d$ = 2,3) for sound waves in a disordered environment, in which the local fluctuations of the elastic modulus are spatially correlated with a certain correlation length. The model is solved analytically by means of a field-theoretical effective-medium theory (self-consistent Born approximation) and numerically on a square lattice. As in the uncorrelated case the theory predicts an enhancement of the density of states over Debye's $\omega^{d-1}$ law (``boson peak'') as a result of disorder. This anomay becomes reinforced for increasing correlation length $\xi$. The theory predicts that $\xi$ times the width of the Brillouin line should be a universal …
Modeling vibrating panels excited by a non-homogeneous turbulent boundary layer
2021
Abstract Predicting the vibration response of an elastic structure excited by a turbulent flow is of interest for the civil and military transportation sector. The models proposed in the literature are generally based on the assumption that the turbulent boundary layer (noted TBL in the following) exciting the structure is spatially homogeneous. However, this assumption is not always fulfilled in practice, in particular when the excited area is close to the starting point of the TBL or with curved structures. To overcome this issue, this work proposes to extend two approaches generally used for dealing with homogeneous TBL, namely the spatial and the wavenumber approaches. The extension of …