Search results for "Weak interactions"
showing 6 items of 36 documents
Preparation of potentially porous, chiral organometallic materials through spontaneous resolution of pincer palladium conformers.
2013
Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous resolution of conformers of a PCP pincer palladium complex ({2,6-bis[(di-t-butylphosphino)methyl]phenyl}palladium(II)halide). The crystallisation is controlled by weak hydrogen bonding giving rise to chiral qtz-nets and channel structures, as shown by 16 such crystal structures for X = Cl and Br with various solvents like pentane and bromobutane. The fourth ligand (in addition to the pincer ligand) on palladium plays a crucial role; the chloride and the bromide primaril…
Muon-electron lepton-flavor-violating transitions : Shell-model calculations of transitions in 27Al
2018
In this paper we present the results of large-scale shell-model calculations of muon-to-electron lepton-flavorviolating transitions for the case of the target nucleus 27Al. We extend the previous shell-model calculations, done in the sd model space, by including also the p orbitals in order to see whether the negative-parity states produce any significant effect in the conversion rate. The analysis of the results shows the dominance of coherent transitions mediated by isovector operators and going by the ground state of the target, with practically null influence of excited positive- or negative-parity states. peerReviewed
Analysis of light neutrino exchange and short-range mechanisms in 0νββ decay
2020
Neutrinoless double beta decay (0νββ) is a crucial test for lepton number violation. Observation of this process would have fundamental implications for neutrino physics, theories beyond the Standard Model and cosmology. Focusing on so-called short-range operators of 0νββ and their potential interplay with the standard light Majorana neutrino exchange, we present the first complete calculation of the relevant nuclear matrix elements, performed within the interacting boson model (IBM-2). Furthermore, we calculate the relevant phase space factors using exact Dirac electron wave functions, taking into account the finite nuclear size and screening by the electron cloud. The obtained numerical r…
Theoretical study of neutrino scattering off the stable even Mo isotopes at low and intermediate energies
2011
A systematic study of the cross sections of neutral-current neutrino scattering off the stable even Mo isotopes (mass number A = 92, 94, 96, 98, 100), at low and intermediate neutrino energies (E(nu) <= 130 MeV), is presented and discussed. The required wave functions for the initial (ground state) and all accessible final nuclear states are constructed in the context of the quasi-particle random-phase approximation (QRPA) and tested against data on the low-lying energy spectra of the isotopes in question. The individual contributions coming from the polar-vector and axial-vector components of the hadronic current for the coherent and incoherent channels of each isotope are investigated. Th…
Weak Interactions between Trivalent Pnictogen Centers: Computational Analysis of Bonding in Dimers X3E···EX3 (E = Pnictogen, X = Halogen)
2009
The nature of weak interactions in dimers X3E···EX3 (E = N−Bi, X = F−I) was investigated by wave function and density functional theory (DFT)-based methods. Out of the 20 systems studied, 10 are found to be bound at the CP-MP2 and LMP2 levels of theory. Detailed partition of the interaction energy into different components revealed that dispersion is the primary force holding the dimers together but there also exists an important ionic component whose contribution increases with increasing halogen size. As expected, standard density functionals fail to describe bonding in the studied systems. However, the performance of DFT methods can be easily improved via empirical dispersion correction …
New Tetraphosphane Ligands {(X2P)2NC6H4N(PX2)2} (X = Cl, F, OMe, OC6H4OMe-o): Synthesis, Derivatization, Group 10 and 11 Metal Complexes and Catalyti…
2008
The reaction of p-phenylenediamine with excess PCl3 in the presence of pyridine affords p-C6H4[N(PCl2)2]2 (1) in good yield. Fluorination of 1 with SbF3 produces p-C6H4[N(PF2)2]2 (2). The aminotetra(phosphonites) p-C6H4[N{P(OC6H4OMe-o)2}2]2 (3) and p-C6H4[N{P(OMe)2}2]2 (4) have been prepared by reacting 1 with appropriate amount of 2-(methoxy)phenol or methanol, respectively, in the presence of triethylamine. The reactions of 3 and 4 with H2O2, elemental sulfur, or selenium afforded the tetrachalcogenides, p-C6H4[N{P(O)(OC6H4OMe-o)2}2]2 (5), p-C6H4[N{P(S)(OMe)2}2]2 (6), and p-C6H4[N{P(Se)(OMe)2}2]2 (7) in good yield. Reactions of 3 with [M(COD)Cl2] (M = Pd or Pt) (COD = cycloocta-1,5-diene)…