Search results for "Weathering"
showing 10 items of 138 documents
Pedogenesis in disturbed alpine soils (NW Italy)
2002
In alpine environments, natural or man-induced disturbances are fairly common and acknowledged as determining factors in pedogenesis and soil distribution. We have selected a representative alpine valley in the Italian Northwestern Alps to evaluate the effects of perturbations of different intensity and frequency on soil development and weathering during the last few centuries. In order of decreasing disturbances, we selected: (i) an active avalanche shoot; (ii) a man-built terrace; (iii) a park-like forest; and (iv) a coniferous forest. In the two most disturbed sites, independently of the intensity and frequency of the disturbances, the active pedogenic processes are restricted to the top…
The influence of weathering processes on labile and stable organic matter in Mediterranean volcanic soils
2008
The relationship and mechanisms among weathering processes, cation fluxes, clay mineralogy, organic matter composition and stability were studied in soils developing on basaltic material in southern Italy (Sicily). The soils were transitions between Phaeozems and Vertisols. Intense losses of the elements Na, Ca and Mg were measured indicating that weathering has occurred over a long period of time. The main weathering processes followed the sequence: amphibole, mica, volcanic glass or if ash was the primary source→smectite→interstratified smectite–kaolinite→kaolinite. Kaolinite formation was strongly related to high Al, Mg and Na losses. The good correlation between oxyhydroxides and kaolin…
Hafnium-neodymium isotope evidence for enhanced weathering and tectonic-climate interactions during the Late Cretaceous
2022
<p>Over million-year timescale the carbon cycle evolution is driven by mantle CO<sub>2</sub> degassing (source) and by continental weathering that drawdowns atmospheric CO<sub>2</sub> through silicate weathering reactions (sink). Based on a novel geochemical proxy of chemical weathering intensity (i.e. using measurements of Hf and Nd isotope ratios in clay-size fractions of sediments) and clay mineralogy, we discuss the links between tectonic, continental weathering and climate evolution during the late Cretaceous. That period records the very first step of the last greenhouse to icehouse transition and is concomitant to …
Effectiveness of Preservative Treatments on Coloured Ruditic Building Stones
2009
: The dark grey Breccia di Billiemi and the Ammonitico Rosso of Piana degli Albanesi, two coloured stones widely used in monuments both outdoor and indoor in Sicily, undergo significant decay as effect of weathering: colour change and development of surface microcracks which affect not only the chromatic aspect but also the state of aggregation. In a previous study (Fracture and Failure of Natural Building Stones, 2006, Springer, Dordrecht, The Netherlands: 329), such effects were successfully reproduced on laboratory samples by means of artificial accelerated weathering and the different response of veins and grains to the ageing agents was related to the microstructure of stones. In this…
Solution and recrystallisation processes and associated landforms in gypsum outcrops of Sicily
2003
Abstract Four small areas of Messinian (Upper Miocene) age gypsum, outcropping in western Sicily, are described. Messinian age evaporites are found in Sicily over a 1000-km 2 area. Here, gypsum outcrops extensively as a consequence of soil erosion induced by human impact. Geomorphological maps show how the rocky surfaces are characterized by a wide range of forms. There are large, medium, small, and microsized forms, which can be identified as belonging to different morphotypes. The morphotypes can be classified into two main categories: those that originated by solution and those that originated through recrystallisation. Four areas, illustrated by geomorphological maps, were specifically …
Seasonal variability in silicate weathering signatures recorded by Li isotopes in cave drip-waters
2021
Abstract Silicate weathering is a critical process in Earth’s carbon cycle, but the fundamental controls on weathering are poorly understood and its response to future climate change is uncertain. In particular, the potential for changes in seasonality or extreme weather events to control silicate weathering rates or mechanisms has been little studied. Here, we use lithium (Li) isotope measurements in bimonthly sampled drip-waters from two caves in the Yorkshire Dales (U.K.) to assess the response of silicate weathering processes to changes in temperature and hydrology over seasonal timescales. While the caves are contained in limestone bedrock, the drip-water Li isotope signal predominantl…
Lightning-induced weathering of Cascadian volcanic peaks
2020
Abstract The process of meteorological lightning-induced modification of coherent volcanic rocks is examined by geochemical, textural, and experimental analysis of fulgurites from South Sister volcano, Oregon Cascades, USA. Lightning's effects on volcanic target rocks was simulated with an arc-welding device in order to reproduce the geochemical and textural features of natural fulgurites and to constrain temperatures of melting and devolatilization behavior during lightning strikes. Melting of volcanic target rocks produces melts of exceptional compositional diversity, ranging from those with pure mineral compositions (e.g., diopside and plagioclase), resulting from congruent melting react…
Fluorine speciation in topsoils of three active volcanoes of Sicily (Italy)
2008
Fluorine is one of the many environmental harmful elements released by volcanic activity. The content of total oxalate-extractable and water-extractable fluorine was determined in 96 topsoils of three active volcanic systems of southern Italy (Mt Etna, Stromboli and Vulcano). Total fluorine (F) content (F TOT) ranges from 112 to 7,430 mg kg−1, F extracted with oxalate (F OX) ranges from 16 to 2,320 mg kg−1 (2–93% of F TOT) and F extracted with distilled water ( $$ F_{{{\text{H}}_{{\text{2}}} {\text{O}}}} $$ ) ranges from 1.7 to 159 mg kg−1 (0.2–40 % of F TOT). Fluorine in the sampled topsoils derives both from the weathering of volcanic rocks and ashes and from the enhanced deposition due t…
Trace metal modeling of groundwater–gas–rock interactions in a volcanic aquifer: Mount Vesuvius, Southern Italy
2005
We report a detailed study of trace metals in groundwaters from the Somma-Vesuvius volcanic complex and present a model of the chemical processes that control the fate of these components during gas–water–rock interactions. Trace metal concentrations in Vesuvian groundwaters range from 0.01 to 0.1 Ag/l for ultra-trace elements (Sb, Cs, Co, Cd, and Pb) up to 0.1–10 mg/l for minor elements (Fe and Sr), leading to water–rock ratios from ~0.5 to 10 � 9 when normalized to trace element concentrations in the host rocks. Our results indicate non-isochemical dissolution of local volcanic rocks by groundwaters, during which mobile trace elements (As, Se, Mo, V, Li) are enriched and elements such as …
Des particules charbonneuses, t�moins des variations de l'�rosion chimique d'un bassin versant calcaire durant l'holoc�ne (bassin de chaillexon, doub…
1999
Matter fluxes result from chemical and mechanical weathering that vary as a function of climate, relief, lithology and human activities. The aim of this paper is to characterize chemical weathering variations in the past using coaly particles found in both the geological substratum and the Holocene lacustrine sediments of a calcareous basin (Chaillexon lake, Doubs, France). Results point out that chemical weathering was the predominant erosional process in the watershed, which may be due to the calcareous nature of the bedrock. The significant variability of this process relative to mechanical weathering during the Holocene period can be interpreted as a consequence of the development of th…