Search results for "Weathering"
showing 10 items of 138 documents
How to tackle the stringent sulfate removal requirements in mine water treatment-A review of potential methods.
2018
Abstract Sulfate (SO₄²⁻) is a ubiquitous anion in natural waters. It is not considered toxic, but it may be detrimental to freshwater species at elevated concentrations. Mining activities are one significant source of anthropogenic sulfate into natural waters, mainly due to the exposure of sulfide mineral ores to weathering. There are several strategies for mitigating sulfate release, starting from preventing sulfate formation in the first place and ending at several end-of-pipe treatment options. Currently, the most widely used sulfate-removal process is precipitation as gypsum (CaSO₄·2H₂O). However, the lowest reachable concentration is theoretically 1500 mg L⁻¹ SO₄²⁻ due to gypsum’s solu…
Zr- Hf Fractionation During Water-Rock Interaction
2017
International audience; Zr and Hf are two elements having same ionic charge and similar ionic size at a given coordination number. Despite the Zr/Hf ratio is considered to be quite constant in meteorites and lithospheric rocks, seawaters collected from the surface down to varying depths of several Pacific Ocean stations reveal that the Zr/Hf ratio increases by one order of magnitude. Very recent studies have shown that, in both ground waters and lake waters, the Zr/Hf ratio is either higher or lower compared to the interacting minerals displaying a large variability in the distribution of these twin elements. In this communication the possible processes responsible for such a large fraction…
Influence of photo-oxidation on the performance and soil degradation of oxo- and biodegradable polymer-based items for agricultural applications
2021
Abstract The examination of the aging behavior of polymers, blends, composites, items, etc. under different environmental conditions is a priority issue for assessing the possible applications and establishing the lifetime. In agriculture, plastic items (mulch films, irrigation tubes, etc.) are widely used and subjected to solar UV exposure that can induce photo-oxidation on macromolecular chains. Therefore, weathering under outdoor conditions and accelerated degradation tests are performed for simulating aging processes during the lifetime of materials and select appropriate stabilizers to be used. In the last decades, oxo- and biodegradable polymers have been investigated and used in agri…
Sequential leaching of silicified Archaean carbonates: A Rb-Sr, Sm-Nd and Pb-Pb isotopic contribution to their tectonic-thermal history (Kaapvaal Cra…
2021
Abstract Sequential leaching was completed by successive interactions of ultra-pure H2O, HAc, HCl and HNO3 with silicified/carbonated Archaean whole rocks from Barberton Greenstone belt of South Africa. The purpose of this experiment was an identification of the minerals interacting with each reagent and, therefore, a detailed succession of isotopically dated tectonic-thermal episodes recorded in these minerals. The contents of the major, trace and rare-earth elemental, together with the Sr, Nd and Pb isotopic compositions of untreated, leachate and residue triplets allowed identification and analysis of various types of carbonates and sulfates mixed with insoluble silicates. The samples yi…
Measure of a limestone weathering degree using Laser Scanner.
2013
The weathering degree of the building materials and natural stones is generally quantified as the decrement of some mechanical features that can be measured experimentally by means of compressive tests or point load tests in the laboratory or Schmidt hammer tests carried out in situ. Such destructive or damaging tests are unacceptable in case of cultural heritage since even small amounts of damage must be avoided. This work shows a correlation between Schmidt hammer rebound values and the reflectivity that is detected by means of terrestrial scanner laser; therefore it allows assessing the weathering degree of buildings or stones in situ. The results demonstrate that such an investigation c…
The Latomiae of Syracuse: A Geotechnical Mapping Through Rock Reflectivity
2014
The archeological site of the Latomia del Paradiso (Syracuse) is endangered by severe instability phenomena due to the shape of walls and underground excava-tion related with the poor mechanical characteristics of the weathered and wet rock. The failure of huge blocks from the ceiling of the underground areas and the detaching of rock "flakes" from the walls surface make the geotechnical zon-ing particularly complex. the zoning is based on the characteristics of the rock wall surface that, in first approximation, can be distinguished in regularized sur-faces because of mining , and in irregular surfaces characterized by fracture prop-agation. The elaboration of reflectivity values obtained …
Rock decay phenomena and collapse processes in the “Latomiae del Paradiso” in Syracuse (Sicily)
2014
The Latomiae (origin: Greek latomia, from laas, las stone plus –tomia tomy ) del Paradiso in Syracuse are Magna Graecia rock quarries, located in the coastal areas of Southern Italy and internationally renowned for their impressive environment. The few historical technical records do not help clarify the events that led to their current configuration since a series of instability phenomena occurred due to decay processes over time. Through a geotechnical back-analysis, this work highlights the failure phenomena, which may have led to the current configuration of the easterly side of the Latomiae del Paradiso. The back-analysis process was carried out by means of numerical modelling, support…
Extracting science from Mössbauer spectroscopy on Mars
2003
[1] Deployment by the Mars Exploration Rovers of backscatter Mossbauer spectrometers offers an incredible opportunity to (1) elucidate the iron mineralogies of rocks, soils, and atmospheric dust and (2) gain insight into the physical event by which the mineralogy came into existence and consequently acquire information having potential for yielding ancient planetary history relevant to broad issues including the question of life. Determining the mineralogy is done by subjecting raw data to reduction algorithms and generating products known as Mossbauer parameters, which are highly characteristic. Mixed mineralogies are treated through deconvolution. Through being able to exploit Mossbauer m…
Search for magnetic minerals in Martian rocks: Overview of the Rock Abrasion Tool (RAT) magnet investigation on Spirit and Opportunity
2008
[1] The Rock Abrasion Tool (RAT) on board the Mars Exploration Rovers (MER) is a grinding tool designed to remove dust coatings and/or weathering rinds from rocks and expose fresh rock material. Four magnets of different strengths that are built into the structure of the RAT have been attracting substantial amounts of magnetic material during RAT activities from rocks throughout both rover missions. The RAT magnet experiment as performed on Spirit demonstrates the presence of a strongly ferrimagnetic phase in Gusev crater rocks, which based on Mossbauer and visible/near-infrared reflectance spectra is interpreted as magnetite. The amount of abraded rock material adhering to the magnets vari…
Weathering of Fe-bearing minerals under Martian conditions, investigated by Mössbauer spectroscopy
2004
Abstract The surface of Mars is covered by weathered material. Mars' rusty red colour in particular is commonly ascribed to ferric iron-bearing minerals. The planet's surface is generally iron rich. Mossbauer spectroscopy is a powerful tool for quantitative mineralogical analysis of Fe-bearing minerals. Consequently, the miniaturized Mossbauer spectrometer MIMOS II is part of the payload of NASA's twin Mars Exploration Rovers “Spirit” and “Opportunity”, and ESA's ill-fated Mars Express lander “Beagle 2”. Both Mars Exploration Rovers are currently conducting successful surface operations on Mars. In this paper, we give a brief insight into mission operations with respect to the reconstructio…