Search results for "Wetting"
showing 10 items of 235 documents
Toward a density functional description of liquid pH2.
2010
A finite-temperature density functional approach to describe the properties of parahydrogen in the liquid-vapor coexistence region is presented. The first proposed functional is zero-range, where the density-gradient term is adjusted so as to reproduce the surface tension of the liquid-vapor interface at low temperature. The second functional is finite-range and, while it is fitted to reproduce bulk pH2 properties only, it is shown to yield surface properties in good agreement with experiments. These functionals are used to study the surface thickness of the liquid-vapor interface, the wetting transition of parahydrogen on a planar Rb model surface, and homogeneous cavitation in bulk liquid…
Droplets pinned at chemically inhomogenous substrates: A simulation study of the two-dimensional Ising case
2016
As a simplified model of a liquid nanostripe adsorbed on a chemically structured substrate surface, a two-dimensional Ising system with two boundaries at which surface fields act is studied. At the upper boundary, the surface field is uniformly negative, while at the lower boundary (a distance L apart), the surface field is negative only outside a range of extension b, where a positive surface stabilizes a droplet of the phase with positive magnetization for temperatures T exceeding the critical temperature Tw of the wetting transition of this model. We investigate the local order parameter profiles across the droplet, both in the directions parallel and perpendicular to the substrate, vary…
Magnetically actuated micropatterns for switchable wettability.
2014
Arrays of actuated magnetic micropillars that can be tilted, twisted, and rotated in the presence of a magnetic field gradient were obtained. The type and extent of the movements are dependent on the distribution (isotropic, anisotropic) of the magnetizable particles inside the pillars and the strength and the direction of the magnetic field gradient. Independent motion of groups of pillars in the same or opposite directions or homogeneous motion of the whole pattern has been realized. Changing the pattern geometry causes changes in the roll-off angle (ROA) of water droplets on the surface. We show magnetically induced changes in the ROA and direction-dependent ROAs as a consequence of the …
Temperature dependence of surface reorganization characteristics of amphiphilic block copolymer in air and in water studied by scanning force microsc…
2015
We have investigated the surface reorganization characteristics of a novel amphiphilic diblock copolymer, poly(acetic acid-2-(2-(4-vinyl-phenoxy)-ethoxy)-ethylester)-block-polystyrene (PAEES-b-PS), in response to varying interfaces from air to water and vice-versa at various temperatures. The surface reorganization characteristics of the block copolymer films was monitored by scanning force microscopy, in order to delineate the kinetically controlled morphological process of surface reorganization of a diblock copolymer, with a particular emphasis on the phase contrast signal which allowed the determination of local composition patterns of PAEES-b-PS at the surface. Upon heating a water-an…
Comparison of leaf surface roughness analysis methods by sensitivity to noise analysis
2015
International audience; Surface roughness is of great interest in agricultural spraying because it is used to characterise leaf surface wettability to predict the behaviour of droplets on a leaf surface. In recent years, the use of texture analysis to estimate surface roughness has emerged. In this paper we propose to estimate leaf surface roughness by using an optimisation of the Generalized Fourier Descriptors method. This approach is then compared with two other standard methods in the literature, one based on grey level intensity variation and the other on wavelet decomposition. Since roughness has many definitions and each method is calculated differently, we propose a new approach to …
PHASE TRANSITIONS AT INTERFACES
1989
The interface between two phases may exhibit significant structural changes if one of them comes close to a phase transition in its bulk. Surface critical phenomena, critical adsorption, and wetting phenomena, like e.g. surface melting or surface induced disorder, can occur. The grazing incidence of X rays and neutrons is particularly well suited in order to obtain precise informations about these kind of critical phenomena which link the space dimensions two and three.
Continuous Phase Transitions at Surfaces of CuAu Alloy Models — A Monte Carlo Study of Surface Induced Order and Disorder
1996
The influence of surface on phase transitions has found significant attention in recent years, and a number of excellent reviews exists. [1, 2, 3] A variety of complex phenomena occur which are also related to the physics of adsorption and wetting. The scenario of wetting requires three distinct phases, for instance the vacuum, the bulk phase and a third phase intervening in between at equilibrium. In case of surface induced disorder (SID, a film of disordered layers at the surface “wets” the bulk phase as the temperature approaches the bulk transition temperature T c,b. The transition at the surface may be continuous (standard critical wetting phenomena), and, as theoretically investigated…
Does Young's equation hold on the nanoscale? A Monte Carlo test for the binary Lennard-Jones fluid
2010
When a phase-separated binary ($A+B$) mixture is exposed to a wall, that preferentially attracts one of the components, interfaces between A-rich and B-rich domains in general meet the wall making a contact angle $\theta$. Young's equation describes this angle in terms of a balance between the $A-B$ interfacial tension $\gamma_{AB}$ and the surface tensions $\gamma_{wA}$, $\gamma_{wB}$ between, respectively, the $A$- and $B$-rich phases and the wall, $\gamma _{AB} \cos \theta =\gamma_{wA}-\gamma_{wB}$. By Monte Carlo simulations of bridges, formed by one of the components in a binary Lennard-Jones liquid, connecting the two walls of a nanoscopic slit pore, $\theta$ is estimated from the inc…
Power laws and crossovers in off-critical surface-directed spinodal decomposition.
2000
We study the dynamics of phase separation in binary mixtures near a surface with a preferential attraction for one of the components of the mixture. We obtain detailed numerical results for a range of mixture compositions. In the case where the minority component is attracted to the surface, wetting layer growth is characterized by a crossover from a surface-potential-dependent growth law to a universal law. We formulate a simple phenomenological model to explain our numerical results.
Spinodal decomposition in thin films: Molecular-dynamics simulations of a binary Lennard-Jones fluid mixture
2005
We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A) with the same strength. The pair-wise interactions between the particles is modeled by the Lennard-Jones potential, with symmetric parameters that lead to a miscibility gap in the bulk. In the thin-film geometry, an interesting interplay occurs between surface enrichment and phase separation. We study the evolution of a mixture with equal amounts of A and B, which is rendered unstable by a temperature quench. We find that A-rich surface enrichment layers fo…