Search results for "X-rays."

showing 10 items of 443 documents

Self-assembly mechanism of nanoparticles of Ni-based Prussian Blue analogues at the air/liquid interface: a synchrotron X-ray reflectivity study.

2015

Prussian Blue analogue (PBA) nanoparticles can be self-assembled at air/liquid interfaces to build novel materials with interesting magnetic features. Herein, we study the influence of the size of PBA Cs0.4 Ni[Cr(CN)6 ]0.9 and K0.25 Ni[Fe(CN)6 ]0.75 nanoparticles on the self-assembly behavior by synchrotron X-ray reflectivity. Both nanoparticles show similar Z-potential values. The phospholipid dipalmitoylphosphatidylcholine and the amino surfactant dimethyldioctadecylammonium have been used as Langmuir monolayers to anchor the PBA nanoparticles and study the interplay of forces directing the self-assembly of the nanoparticles at the surfactant/liquid interface. Whereas Cs0.4 Ni[Cr(CN)6 ]0.…

Prussian blueMaterials scienceX-RaysSupramolecular chemistryNanoparticleAtomic and Molecular Physics and OpticsX-ray reflectivityCrystallographychemistry.chemical_compoundchemistryPulmonary surfactantChemical engineeringNickelDipalmitoylphosphatidylcholineMonolayerNanoparticlesSelf-assemblyPhysical and Theoretical ChemistrySynchrotronsFerrocyanidesChemphyschem : a European journal of chemical physics and physical chemistry
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The contribution of hydrogen peroxide to the radiosensitizing effect of gold nanoparticles

2019

Abstract Plasmid DNA in aerated aqueous solution is used as a probe to determine whose of the reactive oxygen species (ROS) generated after absorption of ultra-soft X-rays (USX) take part in biomolecule damage in the presence and in absence of Gold Nano-Particles (GNP) and specific scavengers. Citrate-coated GNPs with core sizes of 6, 10 and 25 nm are synthetized and characterized, especially in terms of plasmon band shift, ζ-potential and hydrodynamic radii (respectively 9, 21 and 30 nm). We confirm the radiosensitizing effect of GNP and show that the SSB number per plasmid increases when, for a same mass of gold element, the core size of the gold nanoparticles decreases. Hydroxyl radicals…

Radiation-Sensitizing AgentsFormatesRadicalMetal Nanoparticles02 engineering and technologyPhotochemistry01 natural sciencesCitric AcidMetalchemistry.chemical_compoundColloid and Surface ChemistryPyruvic Acid0103 physical sciences[CHIM]Chemical SciencesMoleculeDimethyl SulfoxideDNA Breaks Single-StrandedParticle SizeTromethaminePhysical and Theoretical ChemistryHydrogen peroxideComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationReactive oxygen speciesQuenching (fluorescence)Aqueous solution010304 chemical physicsHydroxyl RadicalX-RaysFree Radical ScavengersHydrogen PeroxideSurfaces and InterfacesGeneral Medicine021001 nanoscience & nanotechnologySolutionschemistryColloidal goldvisual_artvisual_art.visual_art_mediumGold0210 nano-technologyPlasmidsBiotechnologyColloids and Surfaces B: Biointerfaces
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X-ray emitting MHD accretion shocks in classical T Tauri stars. Case for moderate to high plasma-beta values

2009

AIMS. We investigate the stability and dynamics of accretion shocks in CTTSs, considering the case of beta >= 1 in the post-shock region. In these cases the 1D approximation is not valid and a multi-dimensional MHD approach is necessary. METHODS. We model an accretion stream propagating through the atmosphere of a CTTS and impacting onto its chromosphere, by performing 2D axisymmetric MHD simulations. The model takes into account the stellar magnetic field, the gravity, the radiative cooling, and the thermal conduction (including the effects of heat flux saturation). RESULTS. The dynamics and stability of the accretion shock strongly depends on the plasma beta. In the case of shocks with…

Radiative coolingAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesX-rays: starsAstrophysicsstars: pre-main sequenceInstabilitymagnetohydrodynamics (MHD)Settore FIS/05 - Astronomia E AstrofisicaAstrophysics::Solar and Stellar AstrophysicsChromosphereSolar and Stellar Astrophysics (astro-ph.SR)Astrophysics::Galaxy AstrophysicsPhysicsHigh Energy Astrophysical Phenomena (astro-ph.HE)accretion accretion disksStellar magnetic fieldStellar atmosphereAstronomy and Astrophysicsshock wavesAccretion (astrophysics)T Tauri starAstrophysics - Solar and Stellar AstrophysicsSpace and Planetary ScienceinstabilitiesMagnetohydrodynamicsAstrophysics - High Energy Astrophysical Phenomena
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Structural dynamics in F1ATPase during the first reaction cycle of ATP hydrolysis

1991

Abstract The velocity of ATP hydrolysis, catalyzed by purified F 1 ATPase from Micrococcus luteus , was decelerated on decreasing the temperature. At 13′C one reaction cycle is completed after 20 s. Hydrolysis was triggered upon rapid mixing of the enzyme with ATP. During the first reaction cycle, succeeding structural alterations of the F 1 ATPase were traced by time resolved X-ray scattering. The scattering spectra obtained from consecutive intervals of 1 s, revealed the F 1 ATPase to pass a conformational state exhibiting an expanded (6%) molecular shape. The expanded state was observed between 45% and 65% of the time required to complete the reaction cycle. This pointx out a conformatio…

Reaction mechanismProtein ConformationStereochemistryATPaseBiophysicsTime resolved X-ray scatteringBiochemistryMicrococcusCatalysisF1ATPaseHydrolysisMolecular dynamicsAdenosine TriphosphateStructural BiologyATP hydrolysisGeneticsMolecular Biologychemistry.chemical_classificationbiologyHydrolysisX-RaysReaction cycleCell Biologybiology.organism_classificationKineticsProton-Translocating ATPasesEnzymechemistryDynamic structure transitionbiology.proteinMicrococcus luteusFEBS Letters
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Discovery of hard phase lags in the pulsed emission of GRO J1744-28

2016

We report on the discovery and energy dependence of hard phase lags in the 2.14 Hz pulsed profiles of GRO J1744-28. We used data from XMM-Newton and NuSTAR. We were able to well constrain the lag spectrum with respect to the softest (0.3--2.3 keV) band: the delay shows increasing lag values reaching a maximum delay of $\sim$ 12 ms, between 6 and 6.4 keV. After this maximum, the value of the hard lag drops to 7 ms, followed by a recovery to a plateau at 9 ms for energies above 8 keV. NuSTAR data confirm this trend up to 30 keV, but the measurements are statistically poorer, and therefore, less constraining. The lag-energy pattern up to the discontinuity is well described by a logarithmic fun…

Reverberation010504 meteorology & atmospheric sciencesLogarithmLine: identificationLagAstrophysics::High Energy Astrophysical Phenomenaformation; Line: identification; Stars: individual: (GRO J1744-28); X-rays: binaries; X-rays: general; Astronomy and Astrophysics; Space and Planetary Science [Line]Phase (waves)FOS: Physical sciencesAstrophysicsX-rays: generalPlateau (mathematics)01 natural sciencesSettore FIS/05 - Astronomia E Astrofisica0103 physical sciences010303 astronomy & astrophysics0105 earth and related environmental sciencesHigh Energy Astrophysical Phenomena (astro-ph.HE)PhysicsRange (particle radiation)Stars: individual: (GRO J1744-28)Line: formationAstronomy and AstrophysicsRadiusAstronomy and AstrophysicX-rays: binarieDiscontinuity (linguistics)Space and Planetary ScienceAstrophysics - High Energy Astrophysical Phenomena
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Current-induced domain wall motion in nanoscale ferromagnetic elements

2011

The manipulation of a magnetic domain wall (DW) by a spin polarized current in ferromagnetic nanowires has attracted tremendous interest during the last years due to fundamental questions in the fields of spin dependent transport phenomena and magnetization dynamics but also due to promising applications, such as DW based magnetic memory concepts and logic devices. We comprehensively review recent developments in the field of geometrically confined domain walls and in particular current induced DW dynamics. We focus on the influence of the magnetic and electronic transport properties of the materials on the spin transfer effect in DWs. After considering the different DW structures in ferrom…

Ring StructuresAcoustics and Ultrasonics02 engineering and technology01 natural sciencesThreshold Current010305 fluids & plasmasGeneral Materials SciencePermalloy NanowiresAnisotropyComputer Science::DatabasesSpin-½electrical [Condensed matter]PhysicsSpin polarizationCondensed matter physicsGiant Magnetoresistance021001 nanoscience & nanotechnologyCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDynamicsDomain wall (magnetism)magnetic and optical SurfacesMechanics of MaterialsCharge carrierThin0210 nano-technologyCurrent PulsesAngular momentumCurrent-induced domain wall motionMagnetic domain530 PhysicsNanowirePerpendicular Magnetic-AnisotropyGiant magnetoresistanceMagnetizationMemory0103 physical sciencesddc:530010306 general physicsMagnetization dynamicsNanowiresX-RaysMechanical EngineeringPhase-DiagramSpin engineering530 PhysikDomain Wallinterfaces and thin filmsFerromagnetismTorqueShift RegisterIon IrradiationNanoscale science and low-D systemsSpin-Polarized CurrentSpin Torque
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Simultaneous Kepler/K2 and XMM-Newton observations of superflares in the Pleiades

2019

Flares are powerful events ignited by a sudden release of magnetic energy. With the aim of studying flares in the 125-Myr-old stars in the Pleiades observed simultaneously in optical and X-ray light, we obtained new XMM-Newton observations of this cluster during the observations of Kepler K2 Campaign 4. Our objective is to characterize the most powerful flares observed in both bands and to constrain the energy released in the optical and X-ray, the geometry of the loops, and their time evolution. We aim to compare our results to existing studies of flares occurring in the Sun and stars at different ages. We selected bright X-ray/optical flares occurred in 12 known members of the Pleiades fr…

Rotation period010504 meteorology & atmospheric sciencesAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesContext (language use)Astrophysics01 natural scienceslaw.inventionSettore FIS/05 - Astronomia E Astrofisicalaw0103 physical sciencesAstrophysics::Solar and Stellar Astrophysics010303 astronomy & astrophysicsSolar and Stellar Astrophysics (astro-ph.SR)0105 earth and related environmental sciencesX-rays:stars–stars:flarePhysicsHigh Energy Astrophysical Phenomena (astro-ph.HE)Solar flareComputer Science::Information RetrievalAstronomy and AstrophysicsLight curveStarsAstrophysics - Solar and Stellar AstrophysicsSpace and Planetary SciencePhysics::Space PhysicsPleiadesAstrophysics - High Energy Astrophysical PhenomenaSuperflareFlare
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The early B-type star Rho Oph A is an X-ray lighthouse

2017

We present the results of a 140 ks XMM-Newton observation of the B2 star $\rho$ Ophiuchi A. The star has exhibited strong X-ray variability: a cusp-shaped increase of rate, similar to that which we partially observed in 2013, and a bright flare. These events are separated in time by about 104 ks, which likely corresponds to the rotational period of the star (1.2 days). Time resolved spectroscopy of the X-ray spectra shows that the first event is caused by an increase of the plasma emission measure, while the second increase of rate is a major flare with temperatures in excess of 60 MK ($kT\sim5$ keV). From the analysis of its rise, we infer a magnetic field of $\ge300$ G and a size of the f…

Rotation periodStars: activity010504 meteorology & atmospheric sciencesMagnetismAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesHot spot (veterinary medicine)Astrophysics01 natural sciencesSpectral linelaw.inventionStars: early-typelaw0103 physical sciencesAstrophysics::Solar and Stellar AstrophysicsX-rays: star010303 astronomy & astrophysicsSolar and Stellar Astrophysics (astro-ph.SR)Astrophysics::Galaxy Astrophysics0105 earth and related environmental sciencesPhysicsHigh Energy Astrophysical Phenomena (astro-ph.HE)Stars: magnetic fieldStarspotStars: individual: Rho OphiuchiInstitut für Physik und AstronomieAstronomy and AstrophysicsRadiusAstronomy and AstrophysicAstrophysics - Solar and Stellar AstrophysicsSpace and Planetary ScienceStarspotAstrophysics::Earth and Planetary AstrophysicsLow MassAstrophysics - High Energy Astrophysical PhenomenaFlare
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X-raying the interstellar medium: the study of SNR shells at the OAPa

2006

SM: clouds ISM: general ISM: individual objects: Vela Supernova Remnant ISM: structure ISM: supernova remnants X-rays: ISM
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A High-resolution Survey of the physical and chemical Inhomogeneities in the Vela SNR

2007

SNR X-rays Vela SNR
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