Search results for "Zen"
showing 10 items of 3479 documents
Control of catalytic properties of ZSM-5 made by fast and template- free synthesis.
1989
Abstract The fast template-free synthesis of ZSM-5 was accomplished in both static and stirred autoclaves employing sodiumwaterglass.silica hydrogel and pyrogenic silicas as silica sources. Highly pure crystalline ZSM-5 was obtained in the sodiumwaterglass reaction system in the stirred autoclaves without seeds within 3 hours. Addition of 2% (w/w) of seeds reduced the reaction time to 2 hours. The catalytic activity and shape selectivity of the H-ZSM-5, tested by the disproportionation of ethylbenzene, was found to be largely controlled by the synthesis parameters and by the posttreatments. The homogeneous aluminum distribution across the crystals achieved by this synthetis route resulted i…
Dependence of the Optical Constant Parameters of p-Toluene Sulfonic Acid-Doped Polyaniline and Its Composites on Dispersion Solvents
2020
The optical constants of Para-Toluene sulfonic acid-doped polyaniline (PANI), PANIchitosan composites, PANI-reduced graphene-oxide composites and a ternary composite comprising of PANI, chitosan and reduced graphene-oxide dispersed in diluted p-toluene sulfonic acid (PTSA) solution and N-Methyl-2-Pyrrolidone (NMP) solvent have been evaluated and compared. The optical constant values were extracted from the absorbance spectra of thin layers of the respective samples. The potential utilization of the materials as the active sensing materials of surface plasmon resonance biosensors has also been assessed in terms of the estimated value of the penetration depth through a dielectric medium. The …
Star-Shaped Conjugated Systems
2010
The present review deals with the preparation and the properties of star-shaped conjugated compounds. Three, four or six conjugated arms are attached to cross-conjugated cores, which consist of single atoms (B, C+, N), benzene or azine rings or polycyclic ring systems, as for example triphenylene or tristriazolotriazine. Many of these shape-persistent [n]star compounds tend to π-stacking and self-organization, and exhibit interesting properties in materials science: Linear and non-linear optics, electrical conductivity, electroluminescence, formation of liquid crystalline phases, etc.
Comparative study of different approaches for the flow injection-fourier transform infrared determination of toluene in gasolines.
1994
Abstract A single channel flow injection manifold has been employed to carry out the direct determination of toluene in gasolines by FT—IR without any sample pretreatment and by using different strategies. Toluene can be directly determined by measuring the absorbance at 728 cm −1 , using a base line established between 835 and 575 cm −1 ; and in this case a limit of detection of 0.01% (v/v) can be obtained with a dynamic range up to 2% (v/v). In some cases it could be convenient to determine toluene by derivative flow-injection FT—IR in order to avoid matrix interferences in the analysis of some types of gasolines. Carrying out the first order derivative FI—FT—IR measurements on the 728 cm…
Holographic properties of azobenzene oligomers with differently bonded chromophore groups
2007
Holographic properties of two types (I and II, specified in the text) of azobenzene oligomers (ABO) have been experimentally studied in the spectral region of low absorption at 633 nm. In the case of type I ABO the chromophore groups were covalently bonded to either tolyl-polyurethane or hexamethylene-polyurethane matrix. In the case of type II ABO azobenzene chromophores were dispersed in polystyrene matrix, and their concentration was varied from 0.005 to 0.200 mol/l. Samples were in the form of 10 µm thick films. In both cases the diffraction efficiency exposure time dependences were measured for the holographic grating period of 2 (m at 633 nm. The diffraction efficiency of more than 2%…
Über synthetische Matrizenreaktionen
2007
Molecularly homogeneous, polynuclear phenolic compounds were esterified with acrylic acid and methacrylic acid chlorides. The pcresyl esters of acrylic and methacrylic acid react in high dilution in boiling benzene with a large excess of radicals derived from AIBN in such manner that the growth step of the free-radical polymerization is prevented; this may be denoted a “suppressed” polymerization. The application of these conditions to the previously mentioned poly-nuclear esters results in the formation of molecularly homogeneous cyclooligomers (ladder oligomers). Alkaline hydrolysis of these oligomers permits recovery of the polynuclear phenols and yields molecularly homogeneous oligoacry…
Vibrational characterization of the 1:1 iodine-benzene complex isolated in solid krypton.
2008
The structure and properties of a 1:1 iodine-benzene complex isolated in an inert krypton matrix at low temperature have been studied with infrared and resonance Raman spectroscopy and with MP2 calculations. The structure of the ground-state complex is found to be unsymmetric, and the I-I vibrational frequency is found to be red-shifted by 3.94 cm(-1) upon complexation. The experimental data agree well with computational results, leading to the conclusion that the I2-Bz complex structure is not axial but of above-bond type, identically with other halogen-benzene complexes.
Gli aspetti fiscali delle attività di rigenerazione e riuso di beni a fini di interesse generale.
2017
E’ possibile attribuire un riconoscimento, una legittimazione ed una regolamentazione giuridica all'opera prestata dai privati nell'attività di rigenerazione e riuso di beni di interesse comune? La leva fiscale può essere considerata come strumento per favorire lo sviluppo di queste attività? Alla prima domanda possiamo rispondere che il concetto, oggi in evoluzione, di sussidiarietà orizzontale, sembra essere lo strumento più idoneo per inquadrare giuridicamente le azioni di privati cittadini che volontariamente decidono di prendersi cura di beni comuni ai più diversi livelli (beni immobili o mobili concernenti il patrimonio artistico/culturale o, più in generale, fruibili da una collettiv…
Three Approaches to School Health Education as a Means to Higher Levels of Health Literacy
2014
It is widely acknowledged that school health education is an important means for supporting the development of pupils’ health literacy. A growing number of papers have described or suggested a variety of classroom-based and whole-school practices for developing health literacy. However, few of these papers have systematically addressed the various ways of approaching health education in schools or sought to analyze how these approaches differ from each other. This paper aims to do this. It does so by representing three approaches to school health education: the facts and skills approach, the individual thinking approach, and the personal growth and citizenship approach. The approaches diffe…
Frozen embryos, frozen law. Brevi notazioni, in chiave comparatistica, su una recente decisione in tema di procreazione medicalmente assistita
2021
The essay deals with the effects of the withdrawal of the consent to use stored embryos the creation of which was brought about in vitro, once the two partners have broken up and only the woman wants to receive medical assistance to carry a child. The analysis focuses on two opposite Italian judicial decisions, which are compared to an English one. This broader perspective on the subject provides for two diverging possible solutions, each based not on a formally different legislative framework, but a different balance between the values of life, dignity, personal autonomy and health underlying – both in civil law and common law – the medically assisted procreation (MAP).