Search results for "Zircon"
showing 10 items of 693 documents
Multiple zircon growth within early Archaean tonalitic gneiss from the Ancient Gneiss Complex, Swaziland
1988
Abstract U Pb age determinations by ion microprobe reveal multiple episodes of zircon growth and recrystallization within a single sample of tonalitic gneiss from the Ancient Gneiss Complex. The oldest episode at3644 ± 4Ma(2σ) produced the dominant type of zircon, characteristically purplish-brown and massive in texture; this probably constitutes unaltered zircon precipitated from the original magma. Recrystallization accompanied (and obscured) by early Pb loss took place within the oldest grains at3504 ± 6Ma and3433 ± 8Ma. Whole new grains grew at these times also. We interpret the post-3644 Ma growth as due to episodic deformational and metamorphic events that transformed the tonalite plu…
Local structural investigation of hafnia-zirconia polymorphs in powders and thin films by X-ray absorption spectroscopy
2019
Björn Matthey (Fraunhofer IKTS, Dresden) is acknowledged for providing HfO2 and ZrO2 powders on short notice after DESY’s renowned customs office punished us. Parts of this research were carried out at Petra III at DESY, a member of the Helmholtz Association (HGF). The experiments on single Si:HfO2 thin film samples were performed at the CLAESS beamline at ALBA Synchrotron with the collaboration of ALBA staff. We would like to thank Edmund Welter for assistance (in using beamline P65) and DESY for enabling this research for proposal no. 20160591 and for travel support. T.S. acknowledges the German Research Foundation (DFG) for funding this work in the frame of the project “Inferox” (project…
Rapid chemical separation procedures
1976
Fast, discontinuous separation procedures are described for zirconium, niobium, technetium and antimony from fission products. Other rapid separation methods from aqueous solutions are summarized. The combination of a gas jet recoil transport system with a continuous solvent extraction technique and with a thermochromatographic separation method is presented. The application of such procedures to the investigation of new and already known short-lived nuclides is illustrated by some examples.
Zirconia in fixed prosthesis. A literature review
2014
Statement of problem: Evidence is limited on the efficacy of zirconia-based fixed dental prostheses. Objective: To carry out a literature review of the behavior of zirconium oxide dental restorations. Material and Methods: This literature review searched the Pubmed, Scopus, Medline and Cochrane Library databases using key search words “zirconium oxide,” “zirconia,” “non-metal restorations,” “ceramic oxides,” “veneering ceramic,” “zirconia-based fixed dental prostheses”. Both in vivo and in vitro studies into zirconia-based prosthodontic restoration behavior were included. Results: Clinical studies have revealed a high rate of fracture for porcelain-veneered zirconia-based restorations that …
Petrogenesis of synorogenic diorite–granodiorite–granite complexes in the Damara Belt, Namibia: Constraints from U–Pb zircon ages and Sr–Nd–Pb isotop…
2015
The synorogenic Palmental complex (central Damara Belt, Nambia) consists of ca. 545 Ma old quartz diorites and rare granodiorites and ca. 520 Ma-old leucogranites, representing one of the earliest and most primitive phase of crustal plutonism predating the main high-T regional metamorphism. Most quartz diorites and one granodiorite evolved through multistage, polybaric evolutionary processes involving fractionation from a lithospheric mantle-derived melt, followed by fractional crystallization of mainly hornblende, plagioclase and apatite which is shown by decreasing MgO, FeO, CaO, TiO2 and P2O5 with increasing SiO2. Assimilation of felsic basement gneisses was also important during formati…
Carboniferous high-potassium I-type granitoid magmatism in the Eastern Pontides: The Gümüşhane pluton (NE Turkey)
2010
The Gumushane pluton, a high-K calc-alkaline I-type granodionte/granite complex, forms an important component of the pre-Liassic basement of the Eastern Pontides (NE Turkey) In its eastern part, the pluton shows a compositional zonation ranging from biotite-hornblende granodiorite in the NW through biotite-hornblende granite to leucogranite/granophyre in the SE Numerous mafic microgranular enclaves (up to similar to 40 cm in diameter) suggest the former presence of globules of mafic melt during crystallization Emplacement of the pluton occurred during the latest Early Carboniferous, as shown by the 320 +/- 4 Ma Ar-40-Ar-39 bionte/homblende and 324 +/- 6 Ma LA-ICP-MS U-Pb zircon ages. In Har…
Vanadium‐Doped Zircon and Zirconia Materials Prepared from Gel Precursors as Site‐Selective Electrochemical Sensors
2003
Abstract Polymer film electrodes incorporating vanadium‐doped zircon (V x ZrSiO4, 0.00 < x < 0.10) and vanadium‐doped monoclinic and tetragonal zirconias (V x ZrO2, 0.00 < x < 0.15), prepared by heat treatment of gel precursors, exhibit a significant site‐selective electrocatalytic activity towards the oxidation of amino acids, polyalcohols, and polyhydroxycarboxylic acids in alkaline media. Catalysis of the oxidation of carboxylate and alcohol groups involves a relatively slow chemical reaction between the substrate and vanadium centers, while the oxidation of thiolate in cysteine can be attributed to the oxidation of an adduct formed by vanadium centers and the substrate.
Zircon ages of metamorphic and magmatic rocks within peridotite-bearing mélanges: Crucial time constraints on early Carboniferous extensional tectoni…
2013
Abstract We dated and geochemically characterized peridotite-bearing melanges in the Chinese South Tianshan and within the Main Tianshan Shear Zone. The Yushugou-Tonghuashan melange in the Chinese South Tianshan exposes a tectonic juxtaposition of a diapirically emplaced metaperidotite (predominantly lherzolite) massif with a high-grade metamorphic terrane (ca. 10 km long; protolith age ≥ ca. 445–466 Ma). Metamorphic zircons of a mafic granulite (eNd(t) = 5.0) yielded a weighted mean 206Pb/238U age of 341 ± 8 Ma that we interpret as the time of granulite-facies metamorphism. The youngest zircon rims of an intermediate granulite (eNd(t) = − 4.3) have a mean age of 332 ± 13 Ma that records a …
Anatectic amphibole and restitic garnet in Variscan migmatite from NE Sardinia, Italy: insights into partial melting from mineral trace elements
2014
We report results of a laser-ICP-MS investigation of trace element contents in the main constituent minerals of an amphibole-bearing migmatite from the Variscan orogen in northeastern Sardinia. The migmatite is associated with migmatised orthogneiss and Al-silicate-bearing pelitic migmatites. The protolith of the amphibole-bearing migmatite was a mid-Ordovician igneous rock of intermediate composition characterised by a biotite + plagioclase + quartz assemblage. The migmatite consists of mesosomes and tonalitic (or, less frequently, granodioritic) leucosomes, characterised by amphibole crystals (potassian ferropargasite) up to 2 cm in size. The tonalitic leucosomes are made up of quartz, pl…
SHRIMP zircon U–Pb ages and REE partition for high-grade metamorphic rocks in the North Dabie complex: Insight into crustal evolution with respect to…
2012
Abstract We present SHRIMP U–Pb ages and REE data for zircon of two granulites, a garnet pyroxenite and a clinopyroxene amphibolite from the North Dabie complex. The North Dabie complex is a major fault-bounded petrotectonic unit in the Dabie continental collisional orogen between the South and North China Blocks. Zircon REE data are applied to link ages to specific petrological processes. In addition to SHRIMP zircon U–Pb dating, measurements were made on monazites from a HP–UHT metapsammitic granulite. Metamorphic zircon grains and coeval overgrowths on detrital cores from one granulite yielded a weighted mean 207Pb/206Pb age of 2042 ± 7 Ma, corresponding to peak HP/UHT metamorphism. The …