Search results for "Zirconia"

showing 4 items of 144 documents

DFT Prediction of Enhanced Reducibility of Monoclinic Zirconia upon Rhodium Deposition.

2018

Oxides are an important class of materials and are widely used, for example, as supports in heterogeneous catalysis. In a number of industrial catalytic processes, oxide supports actively participate in chemical transformations by releasing lattice oxygen anions. While this is intuitively understood for reducible oxides, the reducibility of irreducible oxides may be modified via nanoengineering or upon inclusion of foreign species. Our calculations predict that the ability of irreducible monoclinic zirconia to release oxygen improves substantially upon deposition of rhodium. Through a comprehensive screening of Rh/ZrO2 with different size of the rhodium species, we find that a Rh adatom and…

oxidation-reduction reactionMaterials scienceOxidechemistry.chemical_element02 engineering and technologyNanoengineering010402 general chemistryHeterogeneous catalysis01 natural sciencesOxygencatalystsRhodiumCatalysischemistry.chemical_compoundkatalyytitnanorakenteetnanostructuresCubic zirconiahapetus-pelkistysreaktioPhysical and Theoretical Chemistryta116ta114tiheysfunktionaaliteoriazirkoniumoksidi021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral Energychemistry13. Climate actionoksiditoxideszirconium dioxidePhysical chemistry0210 nano-technologyMonoclinic crystal systemThe journal of physical chemistry. C, Nanomaterials and interfaces
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Resistive switching in memristors based on yttria-stabilized zirconia

2021

yttria-stabilized zirconiaresistive switchingResistive Random Access Memorylight- and noise-induced resistive switchingstochastic resonanceMemristormetal-insulator-metal structuremetal-insulator-semiconductor structurespace-charge-limited current
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Effect of pulse amplitude on depression and potentiation of ZrO2(Y)-based memristive synaptic device

2022

The effect of the amplitude of depressing and potentiating pulses on the synaptic plasticity (potentiation and depression) of a memristive device based on the Ta/ZrO2(Y)/Pt stack has been experimentally studied. It is shown that the amplitude of depressing and potentiating pulses affects the synaptic plasticity, namely, the value of current passing through the memristive device. The presented results demonstrate the prospects of using the ZrO2(Y)-based memristive devices as stable and low-power elements of neuromorphic systems.

yttria-stabilized zirconiasynaptic plasticitySettore FIS/02 - Fisica Teorica Modelli E Metodi Matematiciresistive switchingmemristor2022 6th Scientific School Dynamics of Complex Networks and their Applications (DCNA)
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Role of ZrO2 addition on the formation and stabilisation of anatase catalyst: XRD, SAXS and TEM investigation

2012

zirconia anatase SAXS TEM XRDSettore CHIM/02 - Chimica Fisica
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