Search results for "absorption spectroscopy"
showing 10 items of 828 documents
Luminescence of impyrity and radiation defects in magnesium oxide irradiated by fast neutrons
2009
Abstract The photoluminescence, its excitation and absorption spectra of MgO single crystals are investigated before and after the irradiation with fast neutrons. It is shown that the fast neutron irradiation leads to the formation of two types of centers: the interstitial proton H + i and the Mg(OH) 2 microphase. From the behaviour of the photoluminescence (PL) and its excitation (PLE) spectra we suppose that the photoluminescence band at 730 nm of the MgO crystals belongs to the complex V − OH − Fe 3+ centers, which is transformed during the irradiation with fast neutrons. The obtained results allow assume that the transitionions play an important role in the migration of vacancies and in…
The Effect of Ni Doping on the Performance and Electronic Structure of LSCF Cathodes Used for IT-SOFCs
2018
We investigated the effect of nickel doping on the electronic structure and performance of nanostructured La0.6Sr0.4Co0.2Fe0.8-0.03Ni0.03O3-delta prepared by the one-pot sol gel method. The commercial undoped La0.6Sr0.4Co0.2Fe0.8O3-delta (ISCF0.8) was used as reference. Moreover, for comparison, Ni (3 mol %) was deposited by wetness impregnation over the La0.6Sr0.4Co0.2Fe0.8O3-delta. We show by in situ X-ray absorption spectroscopy at 900 degrees C under air flow that nickel enters the B perovskite site of the material and favors the stabilization of the cobalt oxidation state, as evidenced by the delay in the decrease of the average Co valence with respect to undoped samples. Our results a…
X-ray absorption spectroscopy studies of the off-center Ni2+ions in Ni c Mg 1-c O solid solutions
1996
In this work we present the x-ray absorption spectroscopy study of NicMg1-cO (0.01 <EQ c <EQ 1) solid solutions. The extended x-ray absorption fine structure (EXAFS) above the Ni K-edge was analyzed using the multi-shell fitting procedure. It was found that nickel ions are located in a distorted environment and shift upon dilution to the off- center positions. This fact follows from two main results: (1) in the first shell, the average Ni- O distance increases linearly upon dilution; (2) in the second shell, the average Ni-Ni distance remains unchanged and decreases slightly at low nickel concentration while the dependence of the Ni-Mg distance has a break at c approximately equals 0.6 and …
A tetranuclear organorhenium(i) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4˙−
2008
The radical complex {(mu(4)-TCNQF4)[Re(CO)(3)(bpy)](4)}(PF(6))(3), as prepared and isolated from the reaction between TCNQF4 and [Re(CO)(3)(bpy)(MeOH)](PF(6)), was studied electrochemically and by IR vibrational spectroscopy, UV-Vis-NIR absorption spectroscopy, and by EPR at 9.5, 190 and 285 GHz. The isotropic g factor of 2.0058, the detectable g anisotropy, and the (185,187)Re EPR hyperfine coupling of 0.95 mT for four equivalent metal nuclei support predominant, but not exclusive, spin localisation at the bridging ligand. Nitrile and metal carbonyl stretching frequencies as well as the typically structured near infrared absorption band lend further support to (TCNQF4 (-))(Re(I))(4) as the…
Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule
2004
The speciation of Mn, Fe, As and Zn in a fast-growing (0.02mm/yr), shallow-marine ferromanganese nodule has been examined by micro X-ray fluorescence, micro X-ray diffraction, and micro X-ray absorption spectroscopy. This nodule exhibits alternating Fe-rich and Mn-rich layers reflecting redox variations in water chemistry. Fe occurs as two-line ferrihydrite. The As is strictly associated with Fe and is mostly pentavalent, with an environment similar to that of As sorbed on or coprecipitated with synthetic ferrihydrite. The Mn is in the form of turbostratic birnessite with ~;10 percent trivalent manganese in the layers and probably ~;8 percent corner-sharing metal octahedra in the interlayer…
Radiation effects in Li2B4O7 oxide crystals
2000
Abstract The lithium tetraborate single crystal has been irradiated by neutrons and the optical properties of these crystals are studied. Irradiation induces optical absorption bands at 42 000, 33 000, and 20 000 cm −1 . The intensities of these bands depend on the energy of the neutrons, on the irradiation temperature, and on the presence of an external electric field. An applied electric field induces the displacement of charged particles, creating the micrononhomogeneous regions in the crystal leading to a decrease of the intensities of the absorption bands. It has been established that the irradiation damages not only the surface of the crystal but also the deeper layers.
LiF crystals irradiated with 150MeV Kr ions: Peculiarities of color center creation and thermal annealing
2013
Abstract Color centers in LiF crystals are studied under irradiation at room temperature with 150 MeV Kr ions in the fluence (Φ) range of 1010–1014 ions/cm2 with a beam current density of 10, 50, and 100 nA/cm2, corresponding to flux of 4.46 × 109, 2.23 × 1010 and 4.46 × 1010 ions/(cm2 × s), respectively. At Φ ⩾ 3 × 1012 ions/cm2 besides F and Fn centers also charged F 3 + centers are created. Thermal annealing of irradiated LiF crystals with Φ ⩾ 1013 ions/cm2 at 400 K leads to a decrease of F centers (due to annihilation with H centers) and an enhancement of complex Fn color centers (neutral and charged) due to interaction with thermally activated anion vacancies. Annealing LiF crystals at…
Radiation displacement defect formation in some complex oxide crystals
2000
The work is devoted to an analysis of the formation processes of radiation displacement defects (RDDs) and color centers (CCs) under irradiation of complex oxide crystals. The results of the displacement process simulation as well as the analysis of the RDDs and CCs accumulation kinetics in some complex oxide crystals are presented. New experimental results on additional absorption spectra induced by neutron irradiation of LiNbO3 (LNO) crystals doped with Fe and Cr and YAlO3 (YAP) crystals doped with Nd and Er as well are presented. Dose dependencies are compared and their peculiarities are discussed. ” 2000 Elsevier Science B.V. All rights reserved.
Color centers and nanodefects in LiF crystals irradiated with 150MeV Kr ions
2012
Abstract The modifications of structure, optical and nano-mechanical properties of LiF crystals after irradiation with 150-MeV Kr +14 ions at a fluence of 6 × 10 12 ions cm −2 have been studied using optical absorption spectroscopy, scanning electron and atomic force microscopy, and nanoindentation. Optical spectroscopy shows the saturation of F centers and a comparatively high number of F n centers. AFM and SEM imaging reveals a nanostructured region with columnar nanocrystallites (size 30–90 nm). Nanostructuring occurs in depths up to 10 μm, where the ion energy loss surpasses a critical threshold of about 10 keV/nm. At a lower energy loss a zone enriched with dislocations is observed. S…
Comparative quantum chemistry study of the F-center in lanthanum trifluoride
2020
Abstract In this study we report the results of first principle quantum chemical modeling of electronic structure and spatial configuration of LaF3 crystal containing the F-center. Theoretical predictions of atomic and electronic properties of LaF3 are given by means of density functional theory. From our modeling we predict that the F-center placed at fluorine ion position between the lanthanum planes at tysonite LaF3 is the most energetically stable. In order to interpret the structure of the optical absorption spectrum of X-irradiated LaF3 we performed calculations of excited and transition states of the F-center within the embedded cluster formalism using time dependent density function…