Search results for "absorption."
showing 10 items of 2682 documents
Excitonic absorption and Urbach's tail in bismuth sulfide single crystals
1988
The absorption coefficient of bismuth sulfide single crystals has been measured through more than four orders of magnitude and in the range of energies from 1.25 to 1.70 eV. A detailed study as a function of temperature has been carried out from 29 to 300 K. An Urbach tail for low values of absorption has been found. This tail and its temperature evolution fit the expression for ionic materials. An excitonic region appears at low temperature and the shape of the exciton peak is Gaussian, which corresponds to a strong exciton-phonon coupling. The exciton binding energy is estimated (28±3 meV) and then the energy gap at 29 K is obtained (Eg=1.523±0.003 eV). The fundamental electronic transiti…
Multiconfigurational Quantum Chemistry Determinations of Absorption Cross Sections (σ) in the Gas Phase and Molar Extinction Coefficients (ε) in Aque…
2021
Theoretical determinations of absorption cross sections (σ) in the gas phase and molar extinction coefficients (e) in condensed phases (water solution, interfaces or surfaces, protein or nucleic acids embeddings, etc.) are of interest when rates of photochemical processes, J = ∫ ϕ(λ) σ(λ) I(λ) dλ, are needed, where ϕ(λ) and I(λ) are the quantum yield of the process and the irradiance of the light source, respectively, as functions of the wavelength λ. Efficient computational strategies based on single-reference quantum-chemistry methods have been developed enabling determinations of line shapes or, in some cases, achieving rovibrational resolution. Developments are however lacking for stron…
Tailored pump-probe transient spectroscopy with time-dependent density-functional theory: controlling absorption spectra
2016
Recent advances in laser technology allow us to follow electronic motion at its natural time-scale with ultra-fast time resolution, leading the way towards attosecond physics experiments of extreme precision. In this work, we assess the use of tailored pumps in order to enhance (or reduce) some given features of the probe absorption (for example, absorption in the visible range of otherwise transparent samples). This type of manipulation of the system response could be helpful for its full characterization, since it would allow us to visualize transitions that are dark when using unshaped pulses. In order to investigate these possibilities, we perform first a theoretical analysis of the non…
PROMINENCE PLASMA DIAGNOSTICS THROUGH EXTREME-ULTRAVIOLET ABSORPTION
2013
In this paper we introduce a new diagnostic technique that uses prominence EUV and UV absorption to determine the prominence plasma electron temperature and column emission measure, as well as He/H relative abundance; if a realistic assumption on the geometry of the absorbing plasma can be made, this technique can also yield the absorbing plasma electron density. This technique capitalizes on the absorption properties of Hydrogen and Helium at different wavelength ranges and temperature regimes. Several cases where this technique can be successfully applied are described. This technique works best when prominence plasmas are hotter than 15,000 K and thus it is ideally suited for rapidly hea…
Remitted photon path lengths in human skin: in-vivo measurement data
2020
The remitted photon path lengths in human skin can be estimated by modelling; however, there are very few experimental data available to validate the simulations. This study exploited the photon time of flight method where picosecond laser pulses at seven wavelength bands in the spectral range 560-800 nm were launched into in-vivo forearm skin of 10 volunteers via an optical fiber. The pulses of back-scattered light were detected via another optical fiber placed at variable distance (1, 8, 12, 16 or 20 mm) from the input fiber, with subsequent analysis of their shapes for all 35 spectral-spatial combinations. Using a deconvolution algorithm, the distribution functions of remitted photon arr…
A perfect Fresnel acoustic reflector implemented by a Fano-resonant metascreen
2018
We propose a perfectly reflecting acoustic metasurface which is designed by replacing the curved segments of the traditional Fresnel reflector by flat Fano-resonant sub-wavelength unit cells. To preserve the original Fresnel focusing mechanism, the unit cell phase follows a specific phase profile which is obtained by applying the generalized Snell's law and Fermat's principle. The reflected curved phase fronts are thus created at the air-metasurface boundary by tailoring the metasurface dispersion as dictated by Huygens' principle. Since the unit cells are implemented by sub-wavelength double slit-shaped cavity resonators, the impinging sound waves are perfectly reflected producing acoustic…
Sound conversion phenomena at the free surface of liquid helium. II. Experimental determination of acoustic coefficients and surface absorption coeff…
1983
The acoustic coefficients of reflection, transmission, and transformation of first-, second-, and gas sound waves incident normally on the free surface of liquid helium have been determined. The experimental results are compared with the theory developed in Part I of this paper. It is shown that equilibrium theories of boundary conditions disagree with the experiments. Nonequilibrium theories, however, which take into account that mass and energy transport processes occur at the liquid-vapor interface of helium II, lead to a very good description of the experimental data below 2 K. Within experimental accuracy the measurements fully confirm several kinetic models of evaporation and energy t…
Theoretical studies of the propagation of sound in narrow channels filled with helium II. I. The dispersion relations of fourth sound and of the fift…
1971
The wave propagation in helium II bounded by two plane-parallel plates forming a narrow channel is considered. The theory is based on the complete linearized set of the Khalatnikov equations. These equations are exactly averaged over the width of the channel taking into account the boundary conditions and symmetry relations. It is shown that in narrow channels three solutions of these equations exist; (a) fourth sound, (b) the so-called fifth-wave mode, and (c) another wave mode, which is very strongly damped. The dispersion relations of these wave modes are calculated with regard to all kinetic coefficients and to the coefficient of thermal expansion. The phase velocities and absorption co…
Ab-Initio Studies of Electronic and Spectroscopic Properties of MgO, ZnO and CdO
2008
We present ab-initio calculations of excited-state properties within single-particle and two-particle approaches in comparison with corresponding experimental results. For the theoretical treatment of the electronic structure, we compute eigenvalues and eigenfunctions by using a spatially nonlocal exchange-correlation potential. From this starting point, quasiparticle energies within the fully frequency-dependent G(0)W(0) approximation are obtained. By solving the Bethe-Salpeter equation, we evaluate optical properties, including the electron-hole attraction and the local-field effects. The results are compared with experimental spectra from soft X-ray emission, as well as from X-ray photoe…
Complete hyperfine Paschen-Back regime at relatively small magnetic fields realized in potassium nano-cell
2015
A one-dimensional nano-metric-thin cell (NC) filled with potassium metal has been built and used to study optical atomic transitions in external magnetic fields. These studies benefit from the remarkable features of the NC allowing one to use $\lambda/2$- and $\lambda$-methods for effective investigations of individual transitions of the K D_1 line. The methods are based on strong narrowing of the absorption spectrum of the atomic column of thickness L equal to $\lambda/2$ and to $\lambda$(with $\lambda = 770\un{nm}$ being the resonant laser radiation wavelength). In particular, for a $\pi$-polarized radiation excitation the $\lambda$-method allows us to resolve eight atomic transitions (in…