Search results for "absorption."
showing 10 items of 2682 documents
Properties of Human Hemoglobins with Increased Polarity in the α- or β-Heme Pocket
1998
The spectroscopic, conformational, and functional properties of mutant carbonmonoxy hemoglobins in which either the β-globin Val67(E11) or the α-globin Val62(E11) is replaced by threonine have been investigated. The thermal evolution of the Soret absorption band and the stretching frequency of the bound CO were used to probe the stereodynamic properties of the heme pocket. The functional properties were investigated by kinetic measurements. The spectroscopic and functional data were related to the conformational properties through molecular analysis. The effects of this nonpolar-to-polar isosteric mutation are: (i) increase of heme pocket anharmonic motions, (ii) stabilization of the A 0 co…
Triterpene saponins from Billia rosea.
2017
Five previously undescribed triterpene saponins, billiosides A-E, and a known analogue, were isolated from the seeds of Billia rosea (Planch. & Linden) C. Ulloa & P. Jorg. Their structures were elucidated on the basis of extensive 1D and 2D NMR experiments (1H, 13C, DEPT, COSY, TOCSY, NOESY, ROESY, HSQC, and HMBC) and mass spectrometry as (3β,21β,22α)-3-[(2-O-β-D-glucopyranosyl-O-[α-L-arabinopyranosyl-(1 → 4)]-β-D-glucopyranosyl)oxy]-21-[((2E,6S)-2,6-dimethyl-6-hydroxyocta-2,7-dienoyl)oxy]-22-(acetyloxy)-24-hydroxyolean-12-en-28-oic acid, (3β,21β,22α)-3-[(2-O-β-D-galactopyranosyl-β-D-glucopyranosyl)oxy]-21,22-dihydroxyolean-12-en-28-yl O-α-L-arabinopyranosyl-(1 → 4)-β-D-glucopyranoside, (3β…
Microparticles derived from marine sponge collagen (SCMPs): preparation, characterization and suitability for dermal delivery of all-trans retinol.
2002
Abstract Collagen microparticles were prepared using marine sponge collagen. For this purpose a previous method by Rossler et al. (J. Microencapsul. 12 (1995) 49) of emulsification and cross-linking of native calf collagen was modified. The modified method for sponge collagen microparticles (SCMPs) achieved a yield of 10%. Scanning electromicroscopic photographs showed spherical particles with a diameter of 120–300 nm and photon correlation spectroscopic measurements indicated particle size range from 126 (±2.9) to 2179 (±342) nm. This broad size distribution was caused by some agglomerates that could not be destroyed by ultrasonication. The surface charge was measured as a function of pH. …
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
2017
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
Concave macrobicycles: Absorption spectra, luminescence properties, and endocavital complexation of neutral organic guests
1996
By a mild modified Eglinton coupling a series of diynebridged macrobicyclic hosts capable of endocavital complexation were synthesized and their structures and complexation properties investigated by X-ray analysis. The inclusion of DMSO in 7 suggests a direct correlation between steric fit and orientation of the guest. On the basis of this hypothesis, the orientation of acetone in an endocavital inclusion of 2 was predicted and verified by X-ray analysis. Comparison of the single-crystal X-ray structures of the vacant macrobicycle 3 and of a family of macrobicycles showing endocavital or “pocket” complexation of neutral organic guests suggests that torsion of the cavities upon complexation…
Panel Summary:Multistimuli and Different Sensory Modalities
1999
Our everyday environment in which we live is characterised by stimuli capable of eliciting our actions (or reactions). Generally our actions are influenced by a number of stimuli which are multimodal.
Mechanical and acoustical behavior of sugarcane and flax fibres reinforced biocomposite
2017
For reasons of comfort, modern constructions require acoustic and thermal insulating materials, offering good mechanical performances. In this context, the valorization of plant fibres from the agro-food industry presents economic and environmental benefits. Thus, the aim of the present study is to develop a multifunctional sugarcane fibres reinforced epoxy porous composite combining good acoustic and mechanical properties.The study of the bagasse fibres geometry has shown that fibres’ length and diameter distribution can be fitted by lognormal laws. Composites manufactured by thermocompression process with an epoxy matrix were characterized using an experimental design whose parameters wer…
Near-Edge X-ray Absorption Fine Structure Investigation of the Quasi-One-Dimensional Organic Conductor (TMTSF)2PF6
2016
We present high-resolution near-edge X-ray absorption fine structure (NEXAFS) measurements at the P L2/3-edges, F K-edge, C K-edge and Se M2/3-edges of the quasi-one-dimensional (1D) conductor and superconductor (TMTSF)2PF6. NEXAFS allows probing the donor and acceptor moieties separately; spectra were recorded between room temperature (RT) and 30 K at normal incidence. Spectra taken around RT were also studied as a function of the angle (θ) between the electric field of the X-ray beam and the 1D conducting direction. In contrast with a previous study of the S L2/3-edges spectra in (TMTTF)2AsF6, the Se M2/3-edges of (TMTSF)2PF6 do not exhibit a well resolved spectrum. Surprisingly, the C K-…
Spectral broadening by spatial effects in X-ray microcalorimeters with superconducting absorber and NTD-Ge thermal sensor
2004
We discuss how the sensitivity to the position of absorption of the photons can affect the spectral resolution of X-ray microcalorimeters with superconducting Sn absorber and NTD-Ge thermal sensor. Data obtained through the computer simulations are reported for microcalorimeters with different geometries and phonon transmission probabilities at the interface between the absorber and thermistor.
Experimental evidence of an incomplete thermalization of the energy in an x-ray microcalorimeter with a TaAu absorber.
2008
We have conducted an experimental test at our XACT facility using an x-ray microcalorimeter with Ta∕Au absorber and neutron transmutation doped germanium thermal sensor. The test was aimed at measuring the percentage of energy effectively thermalized after absorption of x-ray photons in superconducting tantalum. Moreover, in general, possible formation of long living quasiparticles implies that by using a superconducting absorber, a fraction of the deposited energy could not be thermalized on the useful time scale of the thermal sensor. To investigate this scenario, we exploited an absorber made of gold, where no energy trapping is expected, with a small piece of superconducting tantalum at…