Search results for "absorption."
showing 10 items of 2682 documents
<title>In-situ x-ray absorption fine structure and x-ray diffraction studies of hydrogen intercalation in tungsten oxides</title>
1997
We present in-situ x-ray absorption fine structure (XAFS) (at the W L 3 -edge) and x-ray diffraction (XRD) studies of hydrogen intercalation into stable monoclinic (m-WO 3 ) and metastable hexagonal (h-WO 3 ) and cubic (c-WO 3 ) phases of tungsten oxide. The analysis of XAFS and XRD data allowed us to reconstruct the local environment around tungsten ions in the first coordination shell. The obtained results are compared with the existing structural models.
Addressing optical pixel bits in a slab of dense optical material via intrinsic optical bistability
2007
It is well known that dense materials with local-field effects can show "intrinsic" optical bistability when they are directly irradiated by a light beam. This has been shown theoretically in a number of works and also experimentally in several cases, in gas media and also in doped solid-state materials where nonlinearities based on standard local-field effects can be reinforced with other ion interaction effects. Although from the point of view of applications nonlinearities stronger than those found so far would be desirable, the fact that no optical resonator is needed to achieve bistability makes these materials potentially interesting for applications in optical information storage and…
Addressing subphthalocyanines and subnaphthalocyanines features relevant to fluorescence imaging
2018
International audience; A series of new synthetic subphthalocyanines bear structural features aimed at allowing either fluorescence activation or a bathochromic shift of the absorption band towards the near-infrared window, relevant to optical imaging. X-ray diffraction studies of four subphthalocyanines are reported. Spectrofluorimetric studies on subnaphthalocyanines and activatable subphthalocyanine pro-fluorophores are reported.
Photoluminescence in Carborane–Stilbene Triads : A Structural, Spectroscopic, and Computational Study
2016
A set of triads in which o- and m-carborane clusters are bonded to two stilbene units through Ccluster -CH2 bonds was synthesized, and their structures were confirmed by X-ray diffraction. A study on the influence of the o- and m- isomers on the absorption and photoluminescence properties of the stilbene units in solution revealed no charge-transfer contributions in the lowest excited state, as confirmed by (TD)DFT calculations. The presence of one or two B-I groups in m-carborane derivatives does not affect the emission properties of the stilbenes in solution, probably due to the rather large distance between the iodo substituents and the fluorophore. Nevertheless, a significant redshift o…
Structural and magnetic properties of Fe2CoGa Heusler nanoparticles
2012
Abstract Fe2CoGa Heusler nanoparticles are synthesized by a chemical method. The structure and magnetic properties of Fe2CoGa Heusler nanoparticles are investigated by x-ray diffraction, extended x-ray absorption fine structure and Mössbauer spectroscopy. The crystal structure of Fe2CoGa nanoparticles is described by the X-type structure (prototype: Li2AgSb). Magnetic measurements reveal the presence of small Fe2CoGa nanoparticles and lower magnetic moments compared with the theoretically predicted values.
Enhanced chemosensing of ammonia based on the novel molecular semiconductor-doped insulator (MSDI) heterojunctions
2011
Abstract A series of new molecular semiconductor-doped insulator (MSDI) heterojunctions as conductimetric transducers to NH3 sensing were fabricated based on a novel semiconducting molecular material, an amphiphilic tris(phthalocyaninato) rare earth triple-decker complex, Eu2[Pc(15C5)4]2[Pc(OC10H21)8], quasi-Langmuir–Shafer (QLS) film, as a top-layer, and vacuum-deposited and cast film of CuPc as well as copper tetra-tert-butyl phthalocyanine (CuTTBPc) QLS film as a sub-layer, named as MSDIs 1, 2 and 3, respectively. MSDIs 1–3 and respective sub-layers prepared from three different methods were characterized by X-ray diffraction, electronic absorption spectra and current–voltage (I–V) measu…
Local structure relaxation in nanosized tungstates
2014
Abstract The atomic structure of nanosized and microcrystalline tungstates MeWO 4 (Me=Co, Ni, Cu, Zn), synthesized by co-precipitation technique, has been studied by x-ray absorption spectroscopy at the W L 3 -edge and Co/Ni/Cu/Zn K-edges, x-ray diffraction, Raman and Fourier transform infrared spectroscopies. The distortion of metal–oxygen octahedra is caused by the electron–lattice coupling and is further enhanced in nanosized tungstates due to formation of the double tungsten–oxygen bonds at the nanoparticle surface.
Atomistic simulations of the FeK-edge EXAFS in FeF3using molecular dynamics and reverse Monte Carlo methods
2016
Atomistic simulations of the experimental Fe K-edge extended x-ray absorption fine structure (EXAFS) of rhombohedral (space group ) FeF3 at T = 300 K were performed using classical molecular dynamics and reverse Monte Carlo (RMC) methods. The use of two complementary theoretical approaches allowed us to account accurately for thermal disorder effects in EXAFS and to validate the developed force-field model, which was constructed as a sum of two-body Buckingham-type (Fe–F and F–F), three-body harmonic (Fe–F–Fe) and Coulomb potentials. We found that the shape of the Fe K-edge EXAFS spectrum of FeF3 is a more sensitive probe for the determination of potential parameters than the values of stru…
Crossing the boundary between face-centred cubic and hexagonal close packed: the structure of nanosized cobalt is unraveled by a model accounting for…
2014
The properties of nanostructured cobalt in the fields of magnetic, catalytic and biomaterials depend critically on Co close packing. This paper reports a structural analysis of nanosized cobalt based on the whole X-ray diffraction (XRD) pattern simulation allowed by the Debye equation. The underlying structural model involves statistical sequences of cobalt layers and produces simulated XRD powder patterns bearing the concurrent signatures of hexagonal and cubic close packing (h.c.p. and f.c.c.). Shape, size distribution and distance distribution between pairs of atoms are also modelled. The simulation algorithm allows straightforward fitting to experimental data and hence the quantitative …
Ultraviolet holographic recording in photopolymers
2011
Norland Optical Adhesive (NOA) acrylate based photopolymers were studied as a medium for Bragg grating fabrication. NOA photopolymers have absorption maximum in near UV region, but they are transparent in visible light region. Photopolymers were irradiated by He-Cd laser 325 nm line interference patterns during holographic recording. In light irradiated regions photopolymerization takes place and volume grating can be recorded. Diffraction efficiency in dependence on sample thickness, recording beams polarization state and intensity was investigated on transmission mode. Enlargement of sample thickness allows to achieve better angular selectivity of diffracted beam, therefore thickness of p…