Search results for "absorption."
showing 10 items of 2682 documents
Speciation of methylmercury in market seafood by thermal degradation, amalgamation and atomic absorption spectroscopy
2014
Sample thermal decomposition followed by mercury amalgamation and atomic absorption has been employed for the determination of methylmercury (MeHg) in fish. The method involves HBr leaching of MeHg, extraction into toluene, and back-extraction into an aqueous l-cysteine solution. Preliminary studies were focused on the extraction efficiency, losses, contaminations, and species interconversion prevention. The limit of detection was 0.018µgg(-1) (dry weight). The intraday precision for three replicate analysis at a concentration of 4.2µgg(-1) (dry weight) was 3.5 percent, similar to the interday precision according to analysis of variance (ANOVA). The accuracy was guaranteed by the use of for…
The effect of the in-medium Θ+ pentaquark on the kaon optical potential
2005
The kaon nuclear optical potential is studied including the effect of the $\Theta^+$ pentaquark. The one-nucleon contribution is obtained using an extension of the J\"ulich meson-exchange potential as bare kaon-nucleon interaction. Significant differences between a fully self-consistent calculation and the usually employed low-density $T\rho$ approach are observed. The influence of the one-nucleon absorption process, $K N \to \Theta^+$, on the kaon optical potential is negligible due to the small width of the pentaquark. In contrast, the two-nucleon mechanism, $K N N \to \Theta^+ N$, estimated from the coupling of the pentaquark to a two-meson cloud, provides the required amount of addition…
Hole burning and pressure phenomena in chromoproteins
1993
Abstract We investigated the behavior of spectral holes under pressure at various frequencies within the inhomogeneous band for two proteins, namely myoglobin and horseradish peroxidase. In order to achieve narrow bandwidth hole burning, the heme chromophore was replaced by protoporphyrin IX and mesoporphyrin IX, respectively. In myoglobin, we found that the pressure induced shift of the holes varied in a strongly non-linear fashion, when the burn-frequency was tuned across the absorption band. In horseradish peroxidase the pressure shift was linear with burn-frequency but changed in a dramatic fashion upon complex formation with a substrate molecule. These observations are interpreted with…
Partition Behavior of Anilines in Bulk‐Phase and High‐Performance Liquid Chromatographic Systems: Influence on Correlation with Biological Constants
1992
Abstract The partition behavior of a mixed series of ring‐substituted anilines in reversed‐phase high‐performance liquid chromatographic systems is substantially different from that observed in a classical bulk‐phase partition system with n ‐heptane as the aprotic reference solvent. On the basis of the equivalence of each ring substituent in the p ‐straight‐chain methylene groups (ν value) as a function of the fraction of organic solvent (acetonitrile or methanol) in the mobile phase, the biased partition behavior for imperfect homologues and heterologues is verified relative to that of perfect homologues. This behavior was tentatively attributed, mainly, to differences in the hydrogen bond…
Synthesis, size control, and passivation of CdS nanoparticles in water/AOT/n-heptane microemulsions
2003
Abstract CdS nanoparticles have been synthesised by adding tetrabutylammonium hydrogen sulphide to water/sodium bis(2-ethylhexyl) sulfosuccinate/ n -heptane microemulsions containing CdSO 4 . Analysis of UV–Vis absorption spectra recorded at various times indicates that an initial rapid formation of CdS nanoparticles is followed by a very slow growth process which can be well described by a power law. The growth process is totally inhibited by the addition of an appropriate amount of bis(2-ethylhexyl)amine (BEA) leading to the formation of stable nanosized CdS particles coated by an oriented monolayer of chemically bonded BEA molecules. Depending on the BEA addition time, the growth inhibit…
Synthesis and characterization of CdS nanoparticles embedded in a polymethylmethacrylate matrix
2005
CdS nanopowder capped with sodium bis(2-ethylhexyl)sulfosuccinate was synthesized by using water-in-oil microemulsions. The CdS nanoparticles of about 5 nm obtained were embedded in polymethylmethacrylate matrix by a photocuring process. The transparent yellow solid compound was characterized by optical absorption and emission spectroscopy, high-resolution transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The properties of this compound were compared with those of the nanopowder dispersed in heptane and in methylmethacrylate. The results obtained indicate that the nanoparticles are homogeneously dispersed in the matrix and do not change in size during the embedding…
Atmospheric pressure plasma polymerisation of metalloporphyrins containing mesoporous membranes for gas sensing applications
2013
Abstract Metalloporphyrins are embedded in an organosilicon matrix by an easily up-scalable atmospheric pressure dielectric barrier discharge method. The integrity of the metalloporphyrins, followed by UV–visible spectroscopy, is successfully preserved and their aggregation prevented. The single molecule properties, rather than the bulk ones, are thus enhanced. Exposure to triethylamine, which reaches the metalloporphyrins through the pores of the organosilicon membrane, led to a shift in the absorption spectrum and confirms the gas sensing potential of such coatings.
Evidence for a resonant cyclotron line in IGR J16493-4348 from the Swift-BAT hard X-ray survey
2012
Resonant absorption cyclotron features are a key diagnostic tool to directly measure the strength of the magnetic field of accreting neutron stars. However, typical values for cyclotron features lie in the high-energy part of the spectrum between 20 keV and 50 keV, where detection is often damped by the low statistics from single pointed observations. We show that long-term monitoring campaign performed with Swift-BAT of persistently, but faint, accreting high-mass X-ray binaries is able to reveal in their spectra the presence of cyclotron features. We extracted the average Swift-BAT 15-150 keV spectrum from the 54 months long Swift-BAT survey of the high-mass X-ray source IGR J16493-4348. …
Multi-frequency observations of SWIFT J1626.6-5156
2011
SWIFT J1626.6-5156 is an X-ray pulsar that was discovered in December 2005 during an X-ray outburst. Although the X-ray data suggest that the system is a high-mass X-ray binary, very little information exists on the nature of the optical counterpart. We have analysed all RXTE observations since its discovery, archived optical spectroscopic and photometric data and obtained for the first time near-IR spectra. The K-band spectrum shows HeI 20581 A and HI 21660 A (Brackett-gamma) in emission, which confine the spectral type of the companion to be earlier than B2.5. The H-band spectrum exhibits the HI Br-18-11 recombination series in emission. The most prominent feature of the optical band spec…
The Chameleon on the branches: spectral state transition and dips in NGC 247 ULX-1
2021
Soft Ultra-Luminous X-ray (ULXs) sources are a subclass of the ULXs that can switch from a supersoft spectral state, where most of the luminosity is emitted below 1 keV, to a soft spectral state with significant emission above 1 keV. In a few systems, dips have been observed. The mechanism behind this state transition and the dips nature are still debated. To investigate these issues, we obtained a long XMM-Newton monitoring campaign of a member of this class, NGC 247 ULX-1. We computed the hardness-intensity diagram for the whole dataset and identified two different branches: the normal branch and the dipping branch, which we study with four and three hardness-intensity resolved spectra, r…