Search results for "abstraction"

Implicit learning of non-local musical rules : A comment on Kuhn and Dienes

2009

International audience; In a recent study, G. Kuhn and Z. Dienes (2005) reported that participants previously exposed to a set of musical tunes generated by a biconditional grammar subsequently preferred new tunes that respected the grammar over new ungrammatical tunes. Because the study and test tunes did not share any chunks of adjacent intervals, this result may be construed as straightforward evidence for the implicit learning of a structure that was only governed by nonlocal dependency rules. It is shown here that the grammar modified the statistical distribution of perceptually salient musical events, such as the probability that tunes covered an entire octave. When the influence of t…

Benchmarking non-photorealistic rendering of portraits

2017

We present a set of images for helping NPR practitioners evaluate their image-based portrait stylisation algorithms. Using a standard set both facilitates comparisons with other methods and helps ensure that presented results are representative. We give two levels of difficulty, each consisting of 20 images selected systematically so as to provide good coverage of several possible portrait characteristics. We applied three existing portrait-specific stylisation algorithms, two general-purpose stylisation algorithms, and one general learning based stylisation algorithm to the first level of the benchmark, corresponding to the type of constrained images that have often been used in portrait-s…

An adaptive probabilistic approach to goal-level imitation learning

2010

Imitation learning has been recognized as a promising technique to teach robots advanced skills. It is based on the idea that robots could learn new behaviors by observing and imitating the behaviors of other skilled actors. We propose an adaptive probabilistic graphical model which copes with three core issues of any imitative behavior: observation, representation and reproduction of skills. Our model, Growing Hierarchical Dynamic Bayesian Network (GHDBN), is hierarchical (i.e. able to characterize structured behaviors at different levels of abstraction), and growing (i.e. skills are learned or updated incrementally - and at each level of abstraction - every time a new observation sequence…

"Un long voyage à travers des terres inconnues" : de la caricature à l'abstraction

2011

Pressure dependence in the methyl vinyl ketone + OH and methacrolein + OH oxidation reactions: an electronic structure study.

2005

High-level electronic structure calculations were carried out for the study of the reaction pathways in the OH-initiated oxidations of methyl vinyl ketone (MVK) and methacrolein (MACR). For the two conformers of MVK (called synperiplanar and antiperiplanar), the addition channels of OH to the terminal and central carbon atom of the double bond dominate the overall rate constant, whereas the abstraction of the methyl hydrogen atoms has no significant kinetic role. In the case of MACR, only the antiperiplanar conformer is important in its reactivity. In addition, the lower Gibbs free energy barrier for MACR corresponds to the aldehydic hydrogen abstraction reaction, which will be somewhat mor…

Polycondensed nitrogen heterocycles. Part25. Aminopyrrolo[1,2-f]-phenanthridines by decomposition of 2-(3-azidophenyl)-1-arylpyrroles

1994

Acid catalyzed decomposition of the azido derivatives 4a-c gave rise to amino-hydroxy-phenylpyrroles of type 7 and 8 upon hydrolysis of the intermediate aryl nitrenium ions, together with the hydrogen abstraction compounds of type 3. The aminopyrrolo[1,2-f]phenanthridines 10, 11, and 12 were obtained by treatment with TFMSA of the azide 4d in which the ring being attacked was made more nucleophilic by the introduction of the methoxy group.

ChemInform Abstract: Polycondensed Nitrogen Heterocycles. Part 25. Aminopyrrolo(1,2-f) phenanthridines by Decomposition of 2-(3-Azidophenyl)-1-arylpy…

2010

Acid catalyzed decomposition of the azido derivatives 4a-c gave rise to amino-hydroxy-phenylpyrroles of type 7 and 8 upon hydrolysis of the intermediate aryl nitrenium ions, together with the hydrogen abstraction compounds of type 3. The aminopyrrolo[1,2-f]phenanthridines 10, 11, and 12 were obtained by treatment with TFMSA of the azide 4d in which the ring being attacked was made more nucleophilic by the introduction of the methoxy group.

Dadaïsme, abstraction et décoration : la part de Sophie Taeuber dans les avant-gardes historiques

2007

Transferencia inter-dominios en resolución de problemas : una propuesta instruccional basada en el proceso de «traducción algebraica»

2009

Understanding a science and math word problem means constructing mental representations at different levels of abstraction. Secondary students have dificulties solving algebraic word problems due to the transition from the concrete representation to the mathematic representation. In order to facilitate the «algebraic translation» of the problems, we adapt a «rule to put a problem into equations» by Puig (1998) and insert it in an experimental methodology devoted to improving the inter-domain transfer in science. Results show the power of the instructional methodology to overcome most of the students’ dificulties, no matters their average academic performance.

Oxidative Dehydrogenation of Ethanol on Gold : Combination of Kinetic Experiments and Computation Approach to Unravel the Reaction Mechanism

2021

Abstract Selective alcohol dehydrogenation on heterogeneous catalysts is a key industrial reaction for production of aldehydes, ketones, and carboxylic compounds. Design of catalysts with improved activity and selectivity requires understanding of the reaction mechanism and kinetics. Herein, experiments, density functional theory (DFT) and kinetic modelling were combined to elucidate the mechanism and kinetics of ethanol oxidative dehydrogenation to acetaldehyde on gold catalysts. Catalytic experiments clearly emphasized the role of oxygen in this reaction. Ethanol conversion was rather independent on the gold cluster size. Formation of minor products, acetic acid and ethyl acetate was stru…