Search results for "adsorbtion"
showing 3 items of 3 documents
Observation and analysis of Fano-like lineshapes in the Raman spectra of molecules adsorbed at metal interfaces
2015
Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the anti-Stokes (AS) electronic Raman signal increases at the same time while no vibrational AS scattering is seen. These observations are analyzed by assuming that the molecule-metal coupling contains an intensity dependent contribution (resulting from light-induced charge transfer transitions as well as renormalization of the molecule metal tunneling barrier). We find that interference between vibrational and electronic inelastic scattering routes is possible in …
New tailor-made bio-organoclays for the remediation of olive mill waste water
2013
A systematic study aimed at obtaining new organoclays for the treatment of Olive Mill Waste water (OMW) has been performed. Several organoclays have been prepared by loading different amounts of the biocompatible surfactant Tween20 onto the K10 montmorillonite (MMT). Complementary kinetic and equilibrium studies on the adsorption of the Tween20 onto the MMT have been carried out and the characterization of the new tailor-made bio-materials has been performed by means of the XRD and FT-IR measurements. Finally the prepared bio-organoclays have been successfully applied for the OMW remediation and they proved to be highly effective in decreasing the organic content (OC) to an extent that depe…
Water capillary absorption in porous media in different wettability conditions studied by Quantitative MRI and X-ray CT
2007
X-ray computed tomography (CT) and magnetic resonance imaging (MRI) have been successfully applied to study both the capillary properties of several samples of Lecce stone and the performances of treatments used for protection and conservation of historical stone artifacts. The presence of water inside the sample may be visualized by both MRI and X-ray CT. For the treated samples, the different dynamics of water absorption gives indirectly the efficacy of the polymer in the rock.