Search results for "advanced oxidation"
showing 10 items of 21 documents
Association of redox and inflammation-related biomarkers with prognosis in IgA nephropathy: A prospective observational study.
2022
IgA nephropathy (IGAN) has a variable prognosis. Risk stratification tools are usually based on clinical parameters combined with histologic Oxford-MEST-C score. Circulating redox- and inflammation-related biomarkers may be related to histological changes in IGAN. Therefore, we studied the performance of these biomarkers in predicting the rate of GFR-loss in IGAN.This was an observational prospective study. Fifty-seven stable patients with IGAN were examined at baseline and after a mean observational time of 5.9 ± 1.1 years. The main outcome measure was eGFR-loss per year with predefined groups, stable (1.5 ml/min/1,73 mFifteen patients were in the progressive, 11 in the intermediate, and 3…
Elevated advanced oxidation protein products (AOPPs) indicate metabolic risk in severely obese children.
2012
Abstract Background and aims The assessment of oxidative stress may aid in the identification of subsequent metabolic risk in obese children. The objective of this study was to determine whether the plasma level of advanced oxidation protein products, analyzed with a recently proposed modified assay that involves a delipidation step (mAOPPs), was related to metabolic risk factors (MRFs) in severely obese children. Methods and results The plasma levels of mAOPPs were determined by spectrophotometry in 54 severely obese and 44 healthy children. We also measured lipid peroxidation biomarkers (thiobarbituric acid-reactive substances, malondialdehyde, and 8-isoprotane F 2α ) and sulfhydryl group…
Photocatalytic membrane reactors for water treatment
2015
Abstract Heterogeneous photocatalysis is an advanced oxidation process largely studied in the field of environment recovery by the total degradation of organic and inorganic pollutants and for synthesis. In this chapter, the basic principles of photocatalysis are discussed with the advantages related to its coupling with a membrane separation in photocatalytic membrane reactors (PMRs). The types of membranes most widely used and their criteria of selection are briefly discussed. PMRs’ classification based on their configuration and on the type of membrane operation is also discussed, evidencing as their appropriate choice is a key step in view of large-scale implementation. Finally, some ca…
Electrochemical Abatement of Organic Pollutants in Water by Electro- Fenton with Natural Heterogeneous Catalysts Under Pressure
2020
In recent decades, electrochemical advanced oxidation processes (EAOPs) have proved as alternative technologies to conventional processes. Indeed, EAOPs can often allow to treat wastewater containing toxic and POPs. Among them, electro-Fenton (EF) is considered particularly promising for the treatment of recalcitrant organics, since it presents various advantages, including high abatements for many organic pollutants, simplicity of equipment and operations, relatively low cost and low consumption of chemicals. Recently, the utilization of some natural heterogeneous catalysts was proposed in order to avoid some disadvantages of the conventional EF process. In this frame, in this work EF proc…
Treatment of aqueous solutions of oxytetracycline by different electrochemical approaches: anodic oxidation, pressurized electro-Fenton and oxidation…
2023
The tetracycline group (TCs) includes the most common antibiotics for treatment of both human and animal infections. TCs are resistant to biological degradation; hence, conventional wastewater treatments are unable to remove these contaminants. Here, the utilization of different electrochemical processes, such as electro-Fenton (EF), direct anodic oxidation (AO) and indirect oxidation by electrogenerated active chlorine (EAC), for the treatment of aqueous solutions of oxytetracycline (OTC), which is one of the TCs, was studied. The effect of various operating conditions was evaluated to optimize the selected processes. EAC gave the fastest abatement of OTC, but the lowest removal of TOC and…
Process for the production of bromine
2016
A process for the preparation of molecular bromine, by means of advanced oxidation processes or their combination is disclosed
Heterogeneous photocatalysis: a promising advanced oxidation process
2018
This chapter reports the fundamentals of heterogeneous PC. In particular, different kinetic models and the influence of some parameters (such as pH, temperature, light intensity) on the rate of PC are described, and the effects of some photocatalyst modifications are discussed. Methods for photoreactor modeling are analyzed and the coupling of PC with other AOPs using H2O2, O3, and peroxydisulfate are discussed.
Removal of selected antibiotics and antiretroviral drugs during post‐treatment of municipal wastewater with UV, UV/chlorine and UV/hydrogen peroxide
2020
Active pharmaceutical ingredients (APIs) are only partially removed by convectional wastewater treatment plants. This study aimed at assessing the post‐treatment degradation of selected antibiotics and antiretroviral drugs by direct UV photolysis and advanced oxidation processes (UV/H2O2 and UV/Cl2) using low‐pressure mercury lamp. The rate of degradation largely followed pseudo first‐order reaction kinetics. Amongst the six studied APIs, sulfamethoxazole, ciprofloxacin and zidovudine were readily degraded by more than 90% using direct UV photolysis. Addition of Cl2 and H2O2 to the UV process led to an increase in the rate of degradation for all the compounds. The effectiveness UV/Cl2 proce…
Ibuprofen degradation using a Co-doped carbon matrix derived from peat as a peroxymonosulphate activator
2021
The wider presence of pharmaceuticals and personal care products in nature is a major cause for concern in society. Among pharmaceuticals, the anti-inflammatory drug ibuprofen has commonly been found in aquatic and soil environments. We produced a Co-doped carbon matrix (Co-P 850) through the carbonization of Co2+ saturated peat and used it as a peroxymonosulphate activator to aid ibuprofen degradation. The properties of Co-P 850 were analysed using field emission scanning electron microscopy, energy filtered transmission electron microscopy and X-ray photoelectron spectroscopy. The characterization results showed that Co/Fe oxides were generated and tightly embedded into the carbon matrix …
Degradation of Antibiotic Vancomycin by UV Photolysis and Pulsed Corona Discharge Combined with Extrinsic Oxidants
2023
Antibiotics are the most frequently detected pharmaceuticals in the environment creating conditions for the development of resistant genes in bacteria. Degradation and mineralization of glycopeptide antibiotic vancomycin (VMN) were examined by UV photolysis, pulsed corona discharge (PCD), and their combinations with extrinsic oxidants, hydrogen peroxide (HP), peroxydisulfate (PDS), and peroxymonosulfate (PMS). Both combinations were effective in VMN degradation and faster at pH 11 than in acidic or neutral media. Combined with the UV photolysis, HP showed a higher oxidation rate than other oxidants, whereas PMS and PDS proved to be more efficient in combinations with PCD. In contrast to low…