Search results for "aggregates"

showing 2 items of 82 documents

Review: Mass spectrometry of surfactant aggregates

2011

In contrast with the enormous amount of literature produced during many decades in the field of surfactant aggregation in liquid, liquid crystalline and solid phases, only a few investigations concerning surfactant self-assembling in the gas phase as charged aggregates have been carried out until now. This lack of interest is disappointing in view of the remarkable theoretical and practical importance of the inherent knowledge. The absence of surfactant–solvent interactions makes it easier to study the role of surfactant–surfactant forces in determining their peculiar self-assembling features as well as the ability of these assemblies to incorporate selected solubilizate molecules. Thus, th…

surfactants charged aggregates gas phase reverse micelles mass spectrometry ESI-MS
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SERS detection of cell surface and intracellular components of microorganisms using nano-aggregated Ag substrate

2016

Abstract The intracellular and cell surface composition and structural features of gram-positive and gram-negative bacteria were identified using near-infrared surface-enhanced Raman scattering (SERS). The structural differences of components that reside in the cell envelope are manifested by their SERS spectra, e.g. gram-negative vs. gram-positive. Silver particles were used as a SERS substrate by exploiting the existence of strong local electromagnetic fields (hot spots) within nanoscale aggregates of the particles. The aggregation of silver nanoparticles was induced by magnesium ions. These hot spots reduce the screening length of the double layer. The obtained SERS spectra showed excell…

ta221Analytical chemistry02 engineering and technology01 natural sciencesSilver nanoparticleBacterial cell structuresymbols.namesaken-acetyl-D-glucosamine (NAG)bacteriaMagnesium ionSpectroscopyn-acetylmuramic acid (NAM)Double layer (biology)ChemistrySERS010401 analytical chemistrySubstrate (chemistry)silver nano-aggregates021001 nanoscience & nanotechnology0104 chemical sciencessymbolsBiophysicsCell envelope0210 nano-technologyRaman scatteringIntracellularVibrational Spectroscopy
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