Search results for "alloys"
showing 9 items of 1689 documents
An Easy Route Towards Regioselectively Difunctionalized Cyclens and New Cryptands.
2006
Reductive amination of various aldehydes with cyclen represents a very convenient method for the synthesis of a wide range of 1,7-difunctionalized cyclens, as well as new cryptands.
2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion
2016
Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]22− with a cavity volume of 165 Å3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50 : 50 ratio in the crystal lattice. peerReviewed
Applications and non-idealities of submicron Al–AlOx–Nb tunnel junctions
2016
We have developed a technique to fabricate sub-micron, 0.6µm×0.6µm Al-AlOx-Nb tunnel junctions using a standard e-beam resist, angle evaporation and double oxidation of the tunneling barrier, resulting in high quality niobium, as determined by the the high measured values of the critical temperature TC ∼ 7.5 K and the gap ∆ ∼ 1.3 meV. The devices show great promise for local nanoscale thermometry in the temperature range 1 - 7.5 K. Electrical characterization of the junctions was performed at sub-Kelvin temperatures both with and without an external magnetic field, which was used to suppress superconductivity in Al and thus bring the junction into a normal-metal-insulator-superconductor (NI…
Dirakův kužel a pseudogapped hustota stavů v topologické polovině Heuslerovy sloučeniny YPtBi
2016
Topologické izolátory (Tis) jsou zajímavé materiály, které vykazují nebývalé vlastnosti. . Zde jsme prozkoumali sloučeniny YPtBi jako příklad ze třídy polovu-Heuslerových materiálů. Topological insulators (TIs) are exciting materials, which exhibit unprecedented properties, such as helical spinmomentum locking, which leads to large torques for magnetic switching and highly efficient spin current detection. Here we explore the compound YPtBi, an example from the class of half-Heusler materials, for which the typical band inversion of topological insulators was predicted. We prepared this material as thin films by conventional cosputtering from elementary targets. By in situ time-of-flight mo…
Mechanisms of irreversible aquaporin-10 inhibition by organogold compounds studied by combined biophysical methods and atomistic simulations
2021
Abstract The inhibition of glycerol permeation via human aquaporin-10 (hAQP10) by organometallic gold complexes has been studied by stopped-flow fluorescence spectroscopy, and its mechanism has been described using molecular modelling and atomistic simulations. The most effective hAQP10 inhibitors are cyclometalated Au(III) C^N compounds known to efficiently react with cysteine residues leading to the formation of irreversible C–S bonds. Functional assays also demonstrate the irreversibility of the binding to hAQP10 by the organometallic complexes. The obtained computational results by metadynamics show that the local arylation of Cys209 in hAQP10 by one of the gold inhibitors is mapped int…
Synergistic effect of W incorporation and pulsed current mode on wear and tribocorrosion resistance of coatings grown by plasma electrolytic oxidatio…
2019
Ceramic coatings were grown by plasma electrolytic oxidation on 7075 Al alloy using unipolar and bipolar pulsed current waveforms with 20 and 40% cathodic duty cycles, from a silicate-based bath without and with the addition of Na2WO4. Pancake-like morphology was dominant on the coatings grown by unipolar waveform, while the bipolar waveforms promoted volcano-like morphology, increased the roughness of the coating surface and the formation of more compact layers. The coatings produced using the bipolar waveforms provided higher resistances toward both tribocorrosion and dry sliding conditions, while further improvement was achieved by the presence of tungsten. The coatings produced in tungs…
High Entropy Alloys for Energy Conversion and Storage: A Review of Grain Boundary Wetting Phenomena
2022
This research was funded by the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945 grant no. 13.2251.21.0013). Support from the University of the Basque Country (project GIU19/019) and from the Basque Government (project IT1714-22) is also acknowledged.
Teenage Violence Toward Parents – in Search of the Theoretical Bases of a Research Tool
2020
The article contains an analysis of results of the available research on the phenomenon of children’s violence toward their parents. The main purpose of this interpretation is to search for the theoretical structure of a prepared research tool, initially called the Teen Violence Scale Toward Parents (TVSTP). The subject of the analyzes were works and research reports as well as police statistics containing information on the phenomenon of domestic violence, including teenage violence toward parents. As a result of the analysis, the theoretical function of the proposed research tool was distinguished, referring to types of violence possible to diagnose within this area. The proposed tool was…
Contribution to the modeling of microstructural corrosion on aluminium alloys : definition of a methodology to study the bimetallic corrosion phenome…
2008
The initiation and the propagation of aluminum alloys microstructural corrosion is mainly based on the bimetallic corrosion phenomenon. This type of corrosion is caused by galvanic coupling at a local scale between the different phases contained in the alloy. The description of the localized corrosion phenomenon has been largely studied. Their complexity can explain why they are so difficult to predict by the way of numerical tools and why the works that have been done on this subject are so scarce. The present thesis brings a new contribution to this field by suggesting a methodology based on the complementary use of local electrochemical techniques and the finite element simulation of bim…