Search results for "aluminoxanes"

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Ethene/norbornene copolymerization with (isodicyclopentadienyl)titanium complex-MAO catalyst

2007

Norbornene (NB) homopolymerization and ethene/NB copolymerizations with a silylene-bridged (isodicyclopentadienyl)(tert-butylamido)titanium dichloride-methylalumoxane (MAO) catalyst system were investigated. This catalytic system shows no efficiency towards NB homopolymerization but produces poly(ethene-co-norbornene)s. An increase in the initial NB feed content leads to a loss of copolymerization activity as well as NB copolymer incorporation. The structure of the isodicyclopentadienyl fragment (IsodiCp) has a strong limiting effect on comonomer incorporation possibilities.

010405 organic chemistryChemistryComonomeriso(dicyclopentadienyl)titaniumchemistry.chemical_elementGeneral ChemistryLimitingethene/norbornene copolymerization010402 general chemistry01 natural sciencescatalysts0104 chemical sciencesCatalysis[ CHIM.POLY ] Chemical Sciences/Polymerschemistry.chemical_compound[CHIM.POLY]Chemical Sciences/PolymersPolymer chemistryCopolymeraluminoxanesComputingMilieux_MISCELLANEOUSTitaniumNorbornene

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