Search results for "amine"
showing 10 items of 7299 documents
Live free or die motionless : Walking the migrant path from Italy to France
2018
This essay and the photographs examine visual traces of irregular mobility in the border landscape between Italy and France. The ruined buildings and objects witness decades of movement of undocumented people on this old migrant path across the mountains. By taking the theoretical concept of multidirectional memory (Rothberg 2009) the essay argues that the Path of Hope can be thought of as a memory site through which the issues of migration in contemporary Europe can be seen in a more sustainable light. The ruins and discarded objects link memories of different places – including different border zones – in ways that allow us to critically examine borders as a practice – rather than as exis…
Leadership in Finnish comprehensive school core curricula since the 1970s
2014
Tiivistelmä – Abstract Suomen peruskoulujärjestelmä sai alkunsa vuonna 1970 ja samana vuonna julkaistiin ensimmäinen peruskoulun opetussuunnitelma. Seuraavat opetussuunnitelmauudistukset toteutettiin vuosina 1985, 1994 ja 2004. Parhaillaan Suomessa kehitetään uutta peruskoulun opetussuunnitelmaa, joka on tarkoitus ottaa käyttöön vuonna 2016. Tässä tutkimuksessa tarkasteltiin johtajuuden ja opetussuunnitelman välistä suhdetta. Tutkimus toteutettiin laadullisena sisällönanalyysina, jossa aineiston muodostivat viralliset opetussuunnitelmat ja kaksi asiantuntijahaastattelua. Tutkimustulokset analysoitiin summatiivisen sisällönanalyysin menetelmin ja tulokset kuvattiin tulkinnallisella menetelmä…
Drivers and outcomes of consumer engagement : Insights from mobile money usage in Ghana
2019
Purpose The purpose of this paper is to examine the drivers of consumer engagement and its consequences via the experiences of mobile money services’ users in Ghana and to discuss its implications for the society, financial service innovation, delivery and operations. Design/methodology/approach A pre-tested survey instrument was used with a sample of 595 mobile money services users in Ghana. SmartPLS application was used to analyze the data and report findings. Findings The study shows that perceived risk, consumer empowerment, subjective norm, performance expectancy and effort expectancy influence the affect component of consumer engagement and explain around half of its variance. The ef…
Extending customer relationship management. From empowering firms to empowering customers
2013
Purpose – The focus of customer relationship management (CRM) literature has been predominantly on the firm perspective and on IT, not on customer or service orientation and value co-creation. This paper seeks to explore and analyse contemporary CRM frameworks and suggests future research directions. To achieve this, a thorough literature review on CRM is conducted focusing on recent advances within CRM. This provides a good basis for critically analysing the current status of both CRM theory and practice. Design/methodology/approach – The paper reviews CRM literature published 2003-2011. Based on the literature review, it introduces a conceptual framework of the changing role of customer d…
Synthesis, crystal structure and magnetic properties of a new cyanide-bridged mixed-valence copper(I)/copper(II) clathrate
2013
A unique cyanide-bridge mixed-valence CuI/CuII clathrate of formula [CuI2(CN)3][{CuII(tren)}2(μ-CN)](CF3SO3)2 [tren = tris(2-aminoethyl)amine] containing cyanide-bridged [{CuII(tren)}2(μ-CN)]3 + binuclear cations stacked between anionic honeycomb layered copper(I) cyanide networks, was synthesized and structurally characterized by single crystal X-ray diffraction. Variable-temperature magnetic susceptibility studies showed that the cyanide bridge mediates a strong antiferromagnetic interaction between the copper(II) centers (J = − 160 cm− 1, the spin Hamiltonian being defined as H = − JSA⋅SB).
Synthesis, characterization and crystal structure of the bimetallic cyano-bridged [(η5-C5H5)(PPh3)2Ru(μ-CN)Ru(PPh3)2(η5-C5H5)][PF6]
2005
Abstract The bimetallic cyano-bridged [(η 5 -C 5 H 5 )(PPh 3 ) 2 Ru(μ-CN)Ru(PPh 3 ) 2 (η 5 -C 5 H 5 )][PF 6 ] ( 1 ) was prepared by reaction of [(η 5 -C 5 H 5 )(PPh 3 ) 2 RuCl] with N , N ′-bis(cyanomethyl)ethylenediamine. The single crystal structure determined by X-ray diffraction showed crystallization on the triclinic P1 space group with a perfect alignment of the cyanide bridges. This accentric crystallization was explored having in view the NLO properties at the macroscopic level, determined by the Kurtz Powder technique. Besides the very low efficiency values for the second harmonic generation, the value obtained for the bimetallic complex 1 showed to be higher than one of the parent…
Iron(II) metallomesogens based on symmetrical tripod ligands
2012
Abstract Novel mononuclear tripodand-based iron(II) complexes showing liquid crystal properties have been synthesized and characterized. These are based on ligands tris[3-aza-4-((5-Cn)(6-R-2-pyridyl))but-3-enyl]amine, where R = hydrogen or methyl, 1,3,5-cis,cis-tris[1-aza-2-((5-alkyloxy)(2-pyridyl))vinyl]cyclohexane and 2,2,2-tris(2-aza-3-((5-alkyloxy)(2-pyridyl))prop-2-enyl)ethane. The physical characterization has been carried out by means of single-crystal X-ray diffraction measurements, magnetic susceptibility, differential scanning calorimetry, X-ray powder diffraction and Mossbauer spectroscopy.
Ombitasvir, paritaprevir, and ritonavir, with or without dasabuvir, plus ribavirin for patients with hepatitis C virus genotype 1 or 4 infection with…
2017
Summary Background We ran a compassionate use nationwide programme (ABACUS) to provide access to ombitasvir, paritaprevir, and ritonavir, with dasabuvir, plus ribavirin for hepatitis C virus (HCV) genotype 1 infection and ombitasvir, paritaprevir, and ritonavir, plus ribavirin for HCV genotype 4 infection in patients with cirrhosis at high risk of decompensation while approval of these regimens was pending in Italy. Methods In this prospective observational study, we collected data from a compassionate use nationwide programme from March 17, 2014, to May 28, 2015. Patients with HCV genotype 1 infection and cirrhosis at high risk of decompensation were given coformulated ombitasvir (25 mg), …
Safety and efficacy of ombitasvir/paritaprevir/ritonavir/dasabuvir plus ribavirin in patients over 65 years with HCV genotype 1 cirrhosis
2018
Purpose: To analyse safety and efficacy of treatment based on ombitasvir/paritaprevir/ritonavir/dasabuvir plus ribavirin in the sub-group of GT1 patients older than 65 years. Methods: We collected data extracted from the ABACUS compassionate-use nationwide Italian programme, in patients with cirrhosis due to hepatitis C virus (HCV) Genotype-1 (GT1) or 4 and at high risk of decompensation. GT1-HCV-infected patients received once-daily ombitasvir/paritaprevir, with the pharmacokinetic enhancer ritonavir (25/150/100 mg) and twice-daily dasabuvir (250 mg) plus Ribavirin (RBV) (OBV/PTV/r + DSV + RBV) for 12 (GT1b) or 24 (GT1a) weeks. Endpoints were to evaluate safety and efficacy, the latter def…
Real-world experience with the all-oral, interferon-free regimen of ombitasvir/paritaprevir/ritonavir and dasabuvir for the treatment of chronic hepa…
2017
Summary Real-world studies are relevant to complement clinical trials on novel antiviral therapies against chronic hepatitis C; however, clinical practice data are currently limited. This study investigated effectiveness and safety of ombitasvir/paritaprevir/ritonavir (OBV/PTV/r)±dasabuvir (DSV)±ribavirin (RBV) for treatment of HCV genotype (GT) 1 and GT4 infection in a large real-world cohort. The German Hepatitis C Registry is an observational cohort study prospectively collecting clinical practice data on direct-acting antiviral therapies. Patients with GT1/4 infection treated with OBV/PTV/r±DSV±RBV were analysed. Effectiveness was assessed by sustained virologic response in 558 patients…