Search results for "analytical"
showing 10 items of 9586 documents
Attenuated total reflectance infrared determination of sodium nitrilotriacetate in alkaline liquid detergents
2005
Abstract An attenuated total reflectance infrared (ATR–FTIR) method has been developed for the direct determination of the chelating agent sodium nitrilotriacetate (NTA) in high pH cleaning formulations. Aqueous samples and standards were placed directly on the diamond ATR cell without any pre-treatment and FTIR spectra were recorded between 4000 and 600 cm−1. Measurement conditions were evaluated. Results obtained for five different commercial formulations containing from 6.22 to 9.25% (w/w) of NTA were in good agreement with the manufacturer's declared content (differences between 3.2 and −3.7%). Recovery studies evidenced the accuracy of the developed method, having found values between …
Water-Soluble Polysaccharides from Ephedra alata Stems: Structural Characterization, Functional Properties, and Antioxidant Activity
2020
In this study, the physicochemical characterization, functional properties, and antioxidant activity of polysaccharides extracted from Ephedra alata (EAP) were investigated. EAP were extracted in water during 3 h with a liquid/solid ratio of 5 in a water bath at 90 °
Reaction pathways of glucose oxidation by ozone under acidic conditions.
2009
The ozonation of d-glucose-1-(13)C, 2-(13)C, and 6-(13)C was carried out at pH 2.5 in a semi-batch reactor at room temperature. The products present in the liquid phase were analyzed by GC-MS, HPAEC-PAD, and (13)C NMR spectroscopy. Common oxidation products of glucose have also been submitted to identical ozonation conditions. For the first time, a pentaric acid was identified and its formation quantitatively correlated to the loss of C-6 of glucose in the form of carbon dioxide. Potential mechanisms for the formation of this pentaric acid are discussed. The well-accepted pathway involving the anomeric position in glucose, gluconic acid, arabinose, and carbon dioxide is reinvestigated. The …
Application of Modified Tafel Analysis to the Identification of Corrosion Products on Archaeological Metals Using Voltammetry of Microparticles
2011
Voltammetry of microparticles is applied to the identification of lead corrosion products by means of an essentially non-invasive 'one-touch' technique based on the use of graphite pencil. This methodology permits the mechanical attachment of few nanograms of sample from the surface of lead archaeological artefacts to a paraffin-impregnated graphite electrode, which, upon immersion in aqueous electrolytes, provides distinctive voltammetric responses for litharge and cotunnite- anglesite-, cerusite-based corrosion products. The reported method is applied to the identification of corrosion products in archaeological lead pieces from different Iberian sites in Valencia (Spain). © 2011 WILEY-VC…
Early Bronze Age painted wares from Tell el-'Abd, Syria: A compositional and technological study
2018
Abstract The ‘Euphrates Monochrome Painted Ware’ (henceforth EMPW) is a ceramic style attested in the Middle Euphrates region in northern Syria at the beginning of the Early Bronze Age, ca. 2900–2700 BCE. This style is not an isolated phenomenon; rather, it must be understood in the context of a general, albeit short-lived, re-introduction of painted ceramics into local assemblages of Greater Mesopotamia. In the present study, we investigate the technology and provenance of the painted pottery from Tell el-'Abd (North Syria) and its relation to contemporary ceramics retrieved at this site. We apply a combination of macroscopic observations, ceramic petrography, and micro X-ray diffraction (…
Design and implementation of an augmented reality application for rock art visualization in Cova dels Cavalls (Spain)
2019
[EN] Prehistoric rock art paintings, specifically rock-shelters exposed to environmental and anthropogenic factors, are usually faint and severely damaged, being them difficult to identify and understand by visitors. Augmented Reality (AR) supplements reality with virtual information superimposed onto the real world. This sensor-based technology in smartphones/tablets can improve the paintings experience displaying the 2D digital tracings overlapped onto the real scene (rock with faint paintings). This paper presents an AR application (app) developed in Cova dels Cavalls that shows a recreation of a possible original composition full of motifs with descriptive information to improve current…
Reconstrucción virtual y visualización 3d del yacimiento arqueológico Castellet de Bernabé (Lliria, España)
2017
3D virtual reconstruction of cultural heritage is a useful tool to reach many goals: the accurate documentation of our tangible cultural legacy, the determination of mechanical alteration on the assets, or the mere shape acquisition prior to restoration and/or reconstruction works, etc. Among these goals, when planning and managing tourism enhancement of heritage sites, it demands setting up specific instruments and tools to guarantee both, the site conservation and the visitors’ satisfaction. Archaeological sites are physical witnesses of the past and an open window to research works and scientific discoveries, but usually, the major structures do no exist nowadays, and the general public …
Color degradation mapping of rock art paintings using microfading spectrometry
2021
[EN] Rock art documentation is a complex task that should be carried out in a complete, rigorous and exhaustive way, in order to take particular actions that allow stakeholders to preserve the archaeological sites under constant deterioration. The pigments used in prehistoric paintings present high light sensitivity and rigorous scientific color degradation mapping is not usually undertaken in overall archaeological sites. Microfading spectrometry is a suitable technique for determining the light-stability of pigments found in rock art paintings in a non-destructive way. Spectral data can be transformed into colorimetric information following the recommendations published by the Commission …
Documenting carved stones by 3D modelling – Example of Mongolian deer stones
2018
Rock art studies are facing major technical challenges for extensive documentation. Nowadays, recording is essentially obtained from time-consuming tracing and rubbing, techniques that also require a high level of expertise. Recent advances in 3D modelling of natural objects and computational treatment of the modelled surfaces may provide an alternative, and reduce the current documentation bottleneck. The aim of this study is to examine the extent to which such treatments can be applied. The case study presented here concerns the famous deer stones erected by ancient Mongolian nomad populations. The 3D acquisition workflow is based on structure-from-motion, a versatile photogrammetric tech…
Levantamiento 3D para el estudio arqueológico y la reconstrucción virtual del Santuario de Isis en la antigua Lilybaeum (Italia)
2020
[EN] In recent years, the use of three-dimensional (3D) models in cultural and archaeological heritage for documentation and dissemination purposes has increased. New geomatics technologies have significantly reduced the time spent on fieldwork surveys and data processing. The archaeological remains can be documented and reconstructed in a digital 3D environment thanks to the new 3D survey technologies. Furthermore, the products generated by modern surveying technologies can be reconstructed in a virtual environment on effective archaeological bases and hypotheses coming from a detailed 3D data analysis. However, the choice of technologies that should be used to get the best results for dif…