Search results for "angle"
showing 10 items of 1921 documents
Modification of carboxyl groups of poly(ethylene-co-acrylic acid) via facile wet chemistry method: A kinetic study
2010
Abstract In this work, we present the results of a kinetic study of the surface modification of the carboxyl group of poly(ethylene-co-acrylic acid) into acyl chloride. Reaction temperature and time, concentration of the reactants, kind of agitation have been changed in order to understand their effect on the conversion. A study on the penetration of the reaction inside the sample bulk was also performed. The results indicate that, when short reaction times are adopted, the reaction limits to the outer layers of the samples and, in this case, on increasing the temperature, the concentration of the reactants and the stirring allows having a faster kinetic. At longer reaction times, the react…
Spherulite formation in a ?noncrystalline? two-dimensional hydrogen-bond assembly
1996
4-Urazoyl benzoic acid groups 1 are attached as terminal end group to an oligoisobutene. According to wide-angle X-ray scattering the material is amorphous. Differential scanning calorimetry, small-angle X-ray scattering, transmission electron microscopy, and polarizing microscopy show that the polar head groups form ordered two-dimensional assemblies which organize into spherulites. Temperature-dependent SAXS measurements and the d.s.c. analysis give a close insight into the order-disorder (“melting”) process of the two-dimensional clusters which form macroscopic spherulites. The order-disorder transition of the clusters is closely related to the dynamics and order of the polyisobutene cha…
Physicochemical investigation of cobalt?iron cyanide nanoparticles synthesized by a novel solid?solid reaction in confined space
2004
Cobalt–iron cyanide (Cox[Fe(CN)6]) nanoparticles have been synthesized by a novel solid–solid reaction in the confined space of dry sodium bis(2-ethylhexyl)sulfosuccinate (AOT) reversed micelles dispersed in n-heptane. The reaction has been carried out by mixing two dry AOT/n-heptane solutions containing CoCl2 and K4Fe(CN)6 or K3Fe(CN)6 nanoparticles in the micellar core, respectively. By UV-Vis spectroscopy it was ascertained that, after the mixing process, the formation of stable nanoparticles is fast and complete. Microcalorimetric measurements of the thermal effect due to the Cox[Fe(CN)6] nanoparticle formation allowed the determination of the stoichiometric ratio (x) and of the molar e…
Controlled loading and release of beta-lactoglobulin in calcium-polygalacturonate hydrogels
2020
International audience; We show here how the structure of polygalacturonate (polyGalA) hydrogels cross-linked by Ca2+ cations via external gelation controls the loading and the release rate of betalactoglobulin (BLG), a globular protein. Hydrogels prepared from a polyGalA/BLG solution are found similar to those obtained from a polyGalA solution in our previous study (Maire du Poset, et al. Biomacromolecules 2019, 20(7), 2864-2872): they exhibit similar transparencies and gradients of mechanical properties and polyGalA concentration. The nominal BLG/polyGalA ratio of the mixtures is almost recovered within the whole mixed hydrogel despite such strong concentration gradients, except in the pa…
Highly water repellent aerogels based on cellulose stearoyl esters
2011
Herein we combine in a novel way the physical effect of porous structure of a cellulosic aerogel with the chemical effect of long alkyl tails by a well known homogeneous green esterification method, to achieve purely bio-based and highly water repellent cellulosic materials. As an alternative for a traditional fluoro derivatized hydrophobization, here long fatty acid tails are utilized to lower the surface energy. To minimize the process emission, ionic liquid (IL) 1-allyl-3-methylimidazolium chloride is used for the esterification, due to its non-volatility and recyclability. We have shown here that low degree of substitution (DS) of the fatty acid cellulose material enables the spontaneou…
An Approximating-Interpolatory Subdivision Scheme.
2011
International audience; In the last decade, study and construction of quad/triangle subdivision schemes have attracted attention. The quad/triangle subdivision starts with a control mesh consisting of both quads and triangles and produces ner and ner meshes with quads and triangles (Fig. 1). Design- ers often want to model certain regions with quad meshes and others with triangle meshes to get better visual qual- ity of subdivision surfaces. Smoothness analysis tools exist for regular quad/triangle vertices. Moreover C1 and C2 quad/triangle schemes (for regular vertices) have been con- structed. But to our knowledge, there are no quad/triangle schemes that uni es approximating and interpola…
Study and construction of the quasi-linear subdivision schemes over bi-regular meshs
2012
Subdivision schemes are commonly used to generate a smooth shape from a much more coarseone. The reverse subdivision is designed to describe a high resolution mesh from a coarse one. Bothof these tools are used in numerous graphical modelisation domains. In this thesis, we focused ontwo distinct aspects: on one hand the construction of quasi-linear subdivision schemes and on theother hand the construction of reverse quad/triangle subdivision schemes. The work, presented inthe context of the subdivision, describes the construction of a new type of subdivision schemes, andtheirs applications to solve some problems coming from the application of linear subdivision schemes.The work presented in…
Relationship between UVB and broadband solar radiation in Spain
2014
The daily values of UVB irradiation (290–315 nm), IUVB, and the broadband total irradiation (300–2800 nm), IT, measured on a horizontal plane have been correlated for the period 2000–2008 at 16 measurement sites in Spain. The results have been compared with the daily experimental values registered at the same sites during the period 2009–2011. The coefficients of determination R2 obtained by applying a linear regression are higher than 0.88 for all sites and increase to 0.94 when using a quadratic regression. When all data are considered together, the values of R2 are 0.91 and 0.97 for the linear and quadratic regressions, respectively. Three different clearness indices, which are dimension…
Exact Voronoi diagram of smooth convex pseudo-circles: General predicates, and implementation for ellipses
2013
International audience; We examine the problem of computing exactly the Voronoi diagram (via the dual Delaunay graph) of a set of, possibly intersecting, smooth convex \pc in the Euclidean plane, given in parametric form. Pseudo-circles are (convex) sites, every pair of which has at most two intersecting points. The Voronoi diagram is constructed incrementally. Our first contribution is to propose robust and efficient algorithms, under the exact computation paradigm, for all required predicates, thus generalizing earlier algorithms for non-intersecting ellipses. Second, we focus on \kcn, which is the hardest predicate, and express it by a simple sparse $5\times 5$ polynomial system, which a…
Structure of isotactic polypropylene/ hydrogenated oligo(cyclopentadiene) blends: 1. Polypropylene-rich blends
1998
Blends of isotactic polypropylene (iPP) and hydrogenated oligo(cyclopentadiene) (HOCP) containing 30% or less HOCP have been studied by small-angle X-ray scattering in the temperature range 25 to 160°C. The structure of blends has been analysed in terms of a pseudo two-phase model consisting of stacks of lamellae whose thickness is a function of temperature and composition. Structural parameters of the model have been derived and their temperature and composition dependences have been interpreted in the light of existing theories.