Search results for "angle"
showing 10 items of 1921 documents
Through-bond versus through-space T1 energy transfers in organometallic compound-metalloporphyrin pigments
2009
The preparation and characterization of two d9−d9 M2-bonded Pt2(dppm)2(C≡CC6H4-M(P))2 complexes (where M = Zn or Pd, and P = diethylhexamethylporphyrin) were achieved. The central [Pt2(dppm)2(C≡CC6H4)2] organometallic unit appears to be an independent chromophore and is suspected to be luminescent at 77 K (in 2MeTHF) in the porphyrin-containing complexes, as this is the case for the unfunctionalized Pt2(dppm)2(C≡CPh)2 parent compound. However, when this spacer is connected (by a single C−C bond) to either M(P) (M = Zn, Pd), even in the absence of conjugation (as the computed dihedral angle between the C6H4 and porphyrin planes is ∼84.5°), total quenching of the luminescence of the [Pt2(dppm…
CONSIDERAZIONI TEORICHE E PRATICHE SUL METODO DEL MASSIMO RETTANGOLO CIRCOSCRITTO PER LA VALUTAZIONE DELL’AMPIEZZA DELLA TENSIONE TANGENZIALE NEI CRI…
2012
The multiaxial fatigue criteria based on the approach of the critical plane require the determination of the amplitude of the alternating shear stress τ aacting on different planes passing through the point of the material analyzed. In the case of non-proportional stresses the shear stress vector varies both in modulus and direction and its tip describes a curvedefined loading path. In these cases τ ais identified and evaluated by means of special procedures the most recent, and apparently more effective, of which is that of the Maximum Circumscribed Rectangle (MCR) to the loading path itself. In particular τ ais equal to the length of the diagonal of the MCR. In this paper, the MCR method …
R/C columns strengthened by means of steel angles and battens: testing, modeling and design
2010
Linear ViscoElastic (LVE) Behaviour of Pure Bitumen via Fractional Model
2012
AbstractBy fitting experimental data from static creep/recovery carried out on pure bitumen, it is shown that the fractional model proposed enables the description of both creep and recovery behaviour with fewer parameters than those needed by other models in the literature. In particular, the model is fitted to experimental data of complex modulus |G*| and phase angle δ° obtained from Dynamic Mechanical Analysis. Lastly, it is demonstrated that when the fractional model is used, complex modulus isotherms for a range of frequencies can be created simply starting from isochronals at f = 1Hz.
Crystal structure of (E)-4-methyl-N-{2-[2-(4-nitrobenzylidene)hydrazin-1-yl]-2-oxoethyl}benzenesulfonamideN,N-dimethylformamide monosolvate
2017
The molecule of the title Schiff base compound, C16H16N4O5S·C3H7NO, displays atransconformation with respect to the C=N double bond. The C—N and N—N bonds are relatively short compared to their normal bond lengths, indicating some degree of delocalization in the molecule. The molecule is bent at the S atom, with an S—N—C—C torsion angle of 164.48 (11)°. The dihedral angle between the two aromatic rings is 84.594 (7)°. Intermolecular N—H...O and C —H...O hydrogen bonds connect centrosymmetrically related molecules into dimers forming rings ofR33(11) andR22(10) graph-set motif stacked along theaaxis into a columnar arrangement. The molecular columns are further linked into a three-dimensional…
Naphthalene-2,6-diyl bis(4-methylbenzenesulfonate)
2018
The complete molecule of the title compound, C24H20O6S2, is generated by a crystallographic inversion centre at the middle of the naphthalene ring system. The dihedral angle between the naphthalene ring system and the pendant benzene ring is 10.23 (6)° and the C—S—O—C torsion angle is −172.05 (10)°. In the crystal, weak C—H...O interactions link the molecules into (10-1) sheets.
3,5-Dimethoxyphenyl 4-methylbenzenesulfonate
2017
Molecules of the title compound, C15H16O5S, are composed of a 3,5-dimethoxyphenyl moiety substituted with a toluene-4-sulfonate group. The dihedral angle between two aromatic rings is 57.23 (4)°. In the crystal, molecules are connected by weak C—H...O hydrogen bonds and S...O van der Waals interactions.
3,5-Bis(trifluoromethyl)phenyl 4-methylbenzenesulfonate
2017
Molecules of the title compound, C15H10F6O3S, are composed of 3,5-bis(trifluoromethyl)phenyl substituted with a toluene-4-sulfonate group. The dihedral angle between two aromatic moieties is 45.10 (5)°. In the crystal, molecules are connected by weak C—H...O and C—H...F contacts. One of the trifluoromethyl groups is disordered.
Crystal structure of 2-{[1-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-yloxy]carbonyl}benzoic acid
2014
In the title compound, C15H15N3O6, the dihedral angle between the planes of the benzene and imidazole rings is 34.93 (10)°. An intramolecular C—H...O hydrogen bond is observed. In the crystal, O—H...N hydrogen bonds link the molecules into chains parallel to thecaxis.
Crystal structure of 1-(2-fluorobenzoyl)-2,7-dimethoxynaphthalene
2014
The asymmetric unit of the compound contains two independent conformers. Each conformer is stacked along the a axis to form columns through van der Waals interactions only.