Search results for "anodic"

showing 10 items of 163 documents

Abatement of AO7 in a divided microbial fuel cells by sequential cathodic and anodic treatment powered by different microorganisms

2017

Abstract Microbial fuel cells (MFCs) can allow the treatment of organic pollutants resistant to conventional biological processes by electro-Fenton (EF) process performed in the cathodic compartment. However, EF usually results in a partial mineralization of pollutants. Here, we have studied the possible treatment of such organics in a MFC by a sequential cathodic and anodic treatment. In particular, the treatment of an aqueous solution of Acid Orange (AO7), a largely used azoic dye resistant to conventional biological processes, was performed in the cathodic compartment of a divided MFC by EF. The process allowed the total removal of the color and the partial removal of the TOC, due mainly…

Microbial fuel cellAO7MFCGeneral Chemical EngineeringMicroorganism02 engineering and technology010501 environmental sciencesShewanella putrefaciensSettore BIO/19 - Microbiologia Generale01 natural sciencesAnalytical ChemistryCathodic protectionElectrochemistryChemical Engineering (all)Shewanella putrefacienSequential cathodic and anodic treatmentEffluentGeobacter sulfurreducens0105 earth and related environmental sciencesPollutantAqueous solutionbiologyChemistrySettore ING-IND/27 - Chimica Industriale E Tecnologica021001 nanoscience & nanotechnologybiology.organism_classificationEnvironmental chemistryGeobacter sulfurreducenInsect gut microbiota0210 nano-technologyJournal of Electroanalytical Chemistry
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Photo-electrochemical investigation of anodic oxide films on cast Ti–Mo alloys. I. Anodic behaviour and effect of alloy composition

2009

Abstract The anodic behaviour of cast Ti–Mo alloys, having different Mo contents (6–20 wt.%), was investigated in acidic and neutral aerated aqueous solutions. All sample showed a valve-metal behaviour, owing to formation and thickening of barrier-type anodic oxides displaying interference colours. Growth kinetics of passive films is influenced by both anodizing electrolyte and composition of the starting alloy. This last parameter was found to change also the solid-state properties of the films, explored by photoelectrochemical and impedance spectroscopy experiments. Thicker films ( U f  = 8 V/MSE) grown on alloys richer in Mo showed more resistive character and a photocurrent sign inversi…

MolybdenumMaterials sciencePassivationAnodizingGeneral Chemical EngineeringAlloyPhotoelectrochemistryInorganic chemistryOxideTitanium alloychemistry.chemical_elementengineering.materialDielectric spectroscopychemistry.chemical_compoundSettore ING-IND/23 - Chimica Fisica ApplicatachemistryChemical engineeringMolybdenumAnodic filmPhotocurrent spectroscopyElectrochemistryengineeringTitanium alloyElectrochimica Acta
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Evaluation of adsorption ability of Cyclodextrin-Calixarene Nanosponges towards Pb2+ ion in aqueous solution

2021

Abstract Different cyclodextrin-calixarene nanosponges (CyCaNSs) have been characterized by means of FFC-NMR relaxometry, and used as sorbents to remove Pb2+ ions from aqueous solutions. Considering that the removal treatments may involve polluted waters with different characteristics, the adsorption experiments were performed on solutions without and with the addition of background salts, under different operational conditions. The adsorption abilities and affinities of the nanosponges towards Pb2+ ions were investigated by measuring the metal ion concentration by means of Inductively Coupled Plasma Emission Spectroscopy (ICP-OES) and Differential Pulse Anodic Stripping Voltammetry (DP-ASV…

NanospongesPolymers and PlasticsEnvironmental remediationSpeciationInorganic chemistryRemediation02 engineering and technology010402 general chemistry01 natural sciencesIonMetalAdsorptionCalixareneMaterials ChemistrySettore CHIM/01 - Chimica Analiticachemistry.chemical_classificationAqueous solutionCyclodextrinOrganic ChemistrySettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnologyAdsorption; FFC-NMR relaxometry; Lead; Nanosponges; Remediation; Speciation0104 chemical sciencesAnodic stripping voltammetrychemistryFFC-NMR relaxometryLeadvisual_artvisual_art.visual_art_mediumAdsorption0210 nano-technology
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Metodi elettrochimici per la preparazione di nanostrutture in membrane di allumina anodica

2008

Nanostructures Template Electrosynthesis Anodic Alumina MembraneSettore ING-IND/23 - Chimica Fisica Applicata
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Influence of electrodeposition techniques on Ni nanostructures

2008

Abstract Different Ni nanostructure arrays were fabricated by pulsed electrodeposition from a Watts bath inside the pores of anodic alumina membrane (AAM) templates. Under a trapezoidal waveform of potential, consisting of fast linear sweeps between 0 and −3 V (SCE) interleaved by delay times at 0 (10 s) and −3 V (0.1 s), Ni nanowires were grown. The rate of nanowires growth was constant up to 60 min of deposition. For longer times, the growth of nanowires was not uniform, and after about 180 min some nanowires reached the template surface exposed to the electrolyte. Under square potential pulses between the same potentials (pulse length 1 s), nanotubes of Ni are obtained. Morphological ana…

NanotubeNanostructureMaterials scienceScanning electron microscopeGeneral Chemical EngineeringNanowireNanotechnologyElectrolyteElectrochemistryAnodeAnodic alumina membranesSettore ING-IND/23 - Chimica Fisica ApplicataNanostructures electrosynthesiChemical engineeringElectrochemistryDeposition (law)Electrochimica Acta
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Anodic alumina membranes: from electrochemical growth to use as template for nanostructure fabrication

2009

NanowireNanotubeAnodic Alumina MembraneSettore ING-IND/23 - Chimica Fisica ApplicataElectrodepositionElectroless depositionAnodizationGalvanic Deposition
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Electrochemical synthesis and characterization of self-standing metal oxide nanostructures

2009

NanowireNanotubeMetal oxideSettore ING-IND/23 - Chimica Fisica ApplicataElectrodepositionAnodic Alumina MembranesTemplate Electrosynthesi
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Nanostructures Fabrication by Template Deposition in Anodic Alumina Membranes

2009

NanowireNanotubeNanostructureSettore ING-IND/23 - Chimica Fisica ApplicataElectrodepositionAnodic Alumina Membranes
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Raman spectroscopy of lead dioxide nanowires

2009

Nanowires Raman SpectroscpopySettore ING-IND/23 - Chimica Fisica ApplicataElectrodepositionLead dioxdeAnodic Alumina Membranes
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Simultaneous Anodic Dissolution and Passivation of Nickel in Moderate Acid Medium

2006

The EQCM results show that nickel electrodissolution and nickel passivation occur simultaneously in a sulphate acid media of pH = 3.5. Mass balances have been done from the instantaneous F(dm/dQ) function. The fitting of the experimental i = f(E) and -dm/dt = g(E) curves to the theoretical equations allow to obtain information about the kinetic parameters and the molecular mass of the species involved in the electrochemical processes.

NickelPassivationMolecular massChemistryInorganic chemistrychemistry.chemical_elementAnodic dissolutionElectrochemistryKinetic energyDeposition (law)
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