Search results for "astatiini"

The electron affinity of astatine

2020

One of the most important properties influencing the chemical behavior of an element is the electron affinity (EA). Among the remaining elements with unknown EA is astatine, where one of its isotopes, 211At, is remarkably well suited for targeted radionuclide therapy of cancer. With the At− anion being involved in many aspects of current astatine labeling protocols, the knowledge of the electron affinity of this element is of prime importance. Here we report the measured value of the EA of astatine to be 2.41578(7) eV. This result is compared to state-of-the-art relativistic quantum mechanical calculations that incorporate both the Breit and the quantum electrodynamics (QED) corrections and…

Experimental study of isomeric intruder ½+ states 197,203At

2017

A newly observed isomeric intruder ½ + state [ T ½ = 3.5 ( 6 ) ms ] is identified in 203 At using a gas-filled recoil separator and fusion-evaporation reactions. The isomer is depopulated through a cascade of E 3 and mixed M 1 / E 2 transitions to the 9 / 2 − ground state, and it is suggested to originate from the π ( s ½ ) − 1 configuration. In addition, the structures above the ½ + state in 203 At and 197 At are studied using in-beam γ -ray spectroscopy, recoil-decay tagging, and recoil-isomer decay tagging methods. The ½ + state is fed from 3 / 2 + and 5 / 2 + states, and the origin of these states are discussed. peerReviewed

A spectroscopic study of low-lying states in neutron-deficient astatine and francium nuclei

2013

Spectroscopy of [sub 199,201]At

2015

The excited states of 199At and 201At were studied using fusion evaporation reactions, a gas-filled recoil separator and various tagging methods. The level scheme of 201At was extended a lot including a cascade of magnetic dipole transitions, that is suggested to form a shears band. In addition, a 29/2+ [T1/2 = 3.39(9) s] isomeric state was observed. The 29/2+ state is suggested to originate from the p(h9/2) j200Po; 11􀀀i configuration, and it depopulates through 269-keV E2 and 339-keV E3 transitions. In both nuclei 199,201At we have observed also the isomeric 1/2+ [T1/2 = 273(9), 45(3) ms, respectively] intruder state, that is suggested to originate from the p(s1/2)􀀀1 configuration. The 1…