Search results for "atmosphere"

Ceria-based electrolytes prepared by solution combustion synthesis: The role of fuel on the materials properties

2016

Ce0.8Sm0.2O2 − xpowders were synthesized by solution combustion synthesis using citric acid, cellulose and sucrose as single, or intimately mixed, fuels. The powders were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N2sorption at −196 °C, H2-temperature programmed reduction and thermogravimetric analyses. Textural properties of the powders were shaped by the peculiar employed fuel. The study of reducibility revealed that oxygen vacancies formation is mainly influenced by both parameters, specific surface area and total pore volume. The different tendency toward reduction played a key role in sintering under reducing atmosphe…

Shipborne measurements of Antarctic submicron organic aerosols: an NMR perspective linking multiple sources and bioregions

2020

Special issue Marine organic matter: from biological production in the ocean toorganic aerosol particles and marine clouds (ACP/OS inter-journalSI).-- 15 pages, 8 figures, 1 table, supplement https://doi.org/10.5194/acp-20-4193-2020

Column-integrated aerosol optical properties in the free troposphere: case study-Sierra Nevada, Spain

2004

From spectral solar irradiance extinction measurements in the visible range carried out at Sierra Nevada (2950 m a.s.l.) during July 1998, the characteristics of the aerosol column in the free troposphere have been measured. The results show that in stable atmospheric conditions, the column-integrated aerosol takes an optical depth (AOD) at 500 nm of 0.02 /spl plusmn/ 0.02, and an average radius in the accumulation mode of 0.15 /spl mu/m, with a likely Atlantic origin. In unstable situations, the AOD at 500 nm can increase by more than an order of magnitude, and the aerosols' origin is uncertain, since air masses can arrive from different sources at different altitudes.

Global sensitivity of aviation NO<sub>x</sub> effects to the HNO<sub>3</sub>-forming channel …

2013

Abstract. The impact of a recently proposed HNO3-forming channel of the HO2 + NO reaction on atmospheric ozone, methane and their precursors is assessed with the aim to investigate its effects on aviation NOx induced radiative forcing. The first part of the study addresses the differences in stratospheric and tropospheric HOx-NOx chemistry in general, by comparing a global climate simulation without the above reaction to two simulations with different rate coefficient parameterizations for HO2 + NO → HNO3. A possible enhancement of the reaction by humidity, as found by a laboratory study, particularly reduces the oxidation capacity of the atmosphere, increasing methane lifetime significantl…

The pattern of radiative heating and cooling in the troposphere and lower stratosphere

1956

For any meteorological effects of radiation, only those constituents of the air which have a very strong absorption in the infra-red are involved; these are water vapour and carbon dioxide. Several methods have been developed (Mügge & Möller 1932 a, b ; Elsasser 1942; Yamamoto 1952) for computing the radiation flux, and numerous calculations of these fluxes and of the cooling rates have been performed in the last 25 years (Ludwig 1935; Kortiim 1939; Thompson & Neiburger 1955). The results are summarized in figure 1, which shows the distribution of the tem­perature and of the cooling rate by water vapour in some characteristic atmospheres. The lower levels of the tropical atmosphere…

Contribution of the gas-phase reaction between hydroxyl radical and sulfur dioxide to the sulfate aerosol over West Pacific

2021

Sulfate is among the major components of atmospheric aerosols or fine particulate matters. Aerosols loaded with sulfate result in low air quality, damage to ecosystems, and influences on climate change. Sulfate aerosols could originate from that directly emitted to the atmosphere and that produced by atmospheric physicochemical processes. The latter is generated from sulfur dioxide (SO2) via oxidation either in the gas phase reactions or in the aqueous phase. Several mechanisms of SO2 oxidation have been proposed, but the differentiation of the various mechanisms and identification of the sources remain challenging. To meet this need, a new method to estimate the contribution of the gas-pha…

2013

Abstract. It has become possible to retrieve the global, long-term trends of trace gases that are important to atmospheric chemistry, climate, and air quality from satellite data records that span more than a decade. However, many of the satellite remote sensing techniques produce measurements that have variable sensitivity to the vertical profiles of atmospheric gases. In the case of constrained retrievals like optimal estimation, this leads to a varying amount of a priori information in the retrieval and is represented by an averaging kernel (AK). In this study, we investigate to what extent the estimation of trends from retrieved data can be biased by temporal changes of averaging kernel…

The Influence of Trace Substances on the Atmospheric Energy Budget

1979

ABSTRACT The most effective absorbers of solar radiation in the system earth-atmosphere are the earth's surface layer, the atmospheric water vapor, ozone and oxygen. In the troposphere water vapor is dominant, in the lower stratosphere ozone. The absorption contribution due to carbon dioxide may be neglected in both regions of the atmosphere. The contribution of aerosol particles is significant only close to the earth's surface. Here the absorption by aerosol particles equals the effect by water vapor. This fact and the following properties of aerosol particles motivate a special treatment. Particles absorb; particles scatter and elongate the optical path of solar radiation through the abso…

Regional variations in the chemical and helium–carbon isotope composition of geothermal fluids across Tunisia

2011

Abstract Tunisia has numerous thermo-mineral springs. Previous studies have shown that their chemical composition and occurrence are strongly influenced by the regional geology. However little work has been done so far to study the isotopic composition of volatiles associated with these geothermal manifestations. Here, we report on the results of an extensive survey of both natural hot springs and production wells across Tunisia, aimed at investigating the spatial distribution of thermal fluids' geochemical characteristics and He–C isotopic composition. The chemistry of the analyzed samples highlights the heterogeneity of the water mineralization processes in Tunisia, as a consequence of th…

Dynamics of outgassing and plume transport revealed by proximal Unmanned Aerial System (UAS) measurements at Volcán Villarrica, Chile

2019

Volcanic gas emissions are intimately linked to the dynamics of magma ascent and outgassing, and, on geological timescales, constitute an important source of volatiles to the Earth's atmosphere. Measurements of gas composition and flux are therefore critical to both volcano monitoring and to determining the contribution of volcanoes to global geochemical cycles. However, significant gaps remain in our global inventories of volcanic emissions, (particularly for CO2, which requires proximal sampling of a concentrated plume) for those volcanoes where the near‐vent region is hazardous or inaccessible. Unmanned Aerial Systems (UAS) provide a robust and effective solution to proximal sampling of …