Search results for "aurinkokennot"
showing 5 items of 5 documents
Boron–nitrogen substituted dihydroindeno[1,2-b]fluorene derivatives as acceptors in organic solar cells
2019
The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron–nitrogen doped dihydroindeno[1,2-b]fluorene which can be synthesized using standard Schlenk techniques and worked up and handled readily under atmospheric conditions. Through transmetallation via diarylzinc reagents a series of derivatives were synthesized which show broad visible to near-IR light absorption profiles that highlight the versatility of this BN substituted core for use in optoelectronic devices. The synthesis is efficient, scalable and allows for tuning through changes in substituents on the planar heterocyclic core and at boron. Exploratory evaluation in organic solar cell devices as non-ful…
Tetrahedral chalcopyrite quantum dots in solar-cell applications
2010
We have considered two different chalcopyrite material combinations suggested for intermediate-band solar cell (IBSC) sample fabrication in Helmholtz Zentrum, Berlin. We have obtained the maximum theoretical efficiency values of these two chalcopyrite IBSCs. The optimal sizes of the chalcopyrite quantum dots (QDs) in the corresponding QD-IBSC implementations have been calculated. Optical absorption spectrum of a single chalcopyrite QD has been obtained for both systems. The effect of the QD geometry, especially the effect of the roundness of the QD, was examined. We hope that these results will help in the quest towards more efficient and more affordable solar cells.