Search results for "bath"

The sedimentary series of upper Bajocian-lower Bathonian age and their organization in the Burgundy threshold and its surroundings. Stratigraphy, sed…

1981

Three fundamental features concerning the organization of the bio-sedimentary series of the upper Bajocian-lower Bathonian of the Burgundy threshold environment are retained:- the formations are organized in a bio-sedimentary platform, composed of three sets: a deep SW platform with clay sedimentation, a superficial NE platform, a transition zone- the geochemical characteristics are consistent with the reconstitution of the NE-NW polarized platform- this device has changed over time: a migration and extension of the surface platform to the SW, development of the transition zone, a slight displacement of the deep platform correlated with a more and more opening towards the SW.

Submarine canyons of north-western Sicily (Southern Tyrrhenian Sea): Variability in morphology, sedimentary processes and evolution on a tectonically…

2014

Special issue Submarine Canyons: Complex Deep-Sea Environments Unravelled by Multidisciplinary Research.-- 13 pages, 11 figures, 2 tables

Potential Cyclic Steps in a Gully System of the Gulf of Palermo (Southern Tyrrhenian Sea)

2016

Multibeam bathymetric data revealed the occurrence of atrain of bedforms along a gully system in the Gulf of Palermo, Southern Tyrrhenian Sea. The observed gullies, located in the westernmost sector of the Gulf of Palermo, incise the outer shelf at a depth of 120 m and converge at the Zafferano Canyon, connecting to the Palermo Basin at a the depth of 1300 m. Bedforms develop along these gullies and along the thalweg of the canyon, displaying an average wavelength of 200 m, with maximum values of 340 m. Their gully floor location combined with their wave length, upslope asymmetry and crescent shape point to a possible cyclic steporigin of these bedforms. Preliminary numerical modeling sugge…

Effects of sauna bath on heart failure : A systematic review and meta-analysis

2018

Background: Sauna bath has potential as a lifestyle treatment modality for heart failure (HF). It is important to analyze the current evidence to help suggest paths of future study and potential for clinical application. Hypothesis: Sauna bath has a positive effect on HF patients. Methods: PubMed, Cochrane Library, and CINAHL databases were searched to identify randomized and nonrandomized controlled studies to compare effects of sauna bath with no sauna bath. Studies were searched for both infrared sauna bath and Finnish sauna bath. The strength of evidence was rated using a modified GRADE approach. Out of 1444 studies, nine met the inclusion criteria and were included in this review. Seve…

A Colorimetric Probe for the Selective Detection of Norepinephrine Based on a Double Molecular Recognition with Functionalized Gold Nanoparticles

2019

[EN] A simple colorimetric probe for the selective and sensitive detection of neurotransmitter norepinephrine (NE), an important biomarker in the detection of tumors such as pheochromocytoma and paraganglioma, is described. The sensing strategy is based on the use of spherical gold nanoparticles functionalized with benzaldehyde and boronic acid-terminated moieties. A double molecular recognition involving on one hand the aromatic aldehyde and the aminoalcohol group of NE, and on the other hand the boronic acid and the catechol moiety of the neurotransmitter, results in analyte triggered aggregation of the gold nanoparticles, leading to a bathochromic shift of the SPR band in the UV-vis spec…

ChemInform Abstract: Methylium Ions with OPV Chains - New NIR Dyes.

2010

Carbinols, which contain three OPV chains, were generated in convergent syntheses. The extension of the conjugation leads to a bathochromic effect that shifts the absorption from the UV into the visible region. The carbinol series has a convergence limit of the absorption at λmax = 415 nm. The corresponding carbenium ions exhibit a stronger bathochromic shift with the increasing number of repeating units in each chain. Thus, NIR dyes were obtained which show a convergence limit at λmax = 879 nm. The charge distribution in the ground state of the carbocations is discussed on the basis of 13C NMR spectroscopic data.

ChemInform Abstract: Bathochromic or Hypsochromic Effects via the Extension of Conjugation: A Study Stilbenoid Squaraines.

2010

Methylium Ions with OPV Chains − New NIR Dyes

2001

Carbinols, which contain three OPV chains, were generated in convergent syntheses. The extension of the conjugation leads to a bathochromic effect that shifts the absorption from the UV into the visible region. The carbinol series has a convergence limit of the absorption at λmax = 415 nm. The corresponding carbenium ions exhibit a stronger bathochromic shift with the increasing number of repeating units in each chain. Thus, NIR dyes were obtained which show a convergence limit at λmax = 879 nm. The charge distribution in the ground state of the carbocations is discussed on the basis of 13C NMR spectroscopic data.

Extension of Conjugation Leading to Bathochromic or Hypsochromic Effects in OPV Series

2004

Four OPV series 1-4 (a-d) with a terminal dialkylamino group as electron donor were prepared by Wittig-Horner reactions. To study the influence of the push-pull effect on the long-wavelength absorption, three of the four series contained terminal acceptor groups (CN, CHO, NO(2)). The length of the chromophores strongly affects the intramolecular charge transfer (ICT)-an effect which superimposes upon the extension of the conjugation. Increasing numbers n of repeat units cause an overall bathochromic shift for the purely donor-substituted series 1 a-4 a and the series 1 b-4 b with CN as weak acceptor. The two effects annihilate each other in the series 1 c-4 c with terminal CHO groups, so th…

Metallophilic interactions in stacked dinuclear rhodium 2,2'-biimidazole carbonyl complexes

2012

Non-covalent metallophilic interactions were studied by investigating the stacking of two neutral rhodium complexes [Rh2I(R2bim)Cl2(CO)4] (R = Et, ethyl or Pr, propyl) in the solid state. Both dinuclear complexes formed infinite arrays of square planar d8 rhodium centres with intramolecular Rh⋯Rh distances of 3.1781(5) A (R = Et) and 3.1469(3) A (R = Pr) and the intermolecular Rh⋯Rh distances of 3.4345(6) A (R = Et) and 3.4403(3) A (R = Pr) between the adjacent molecules. The crystalline solids were stable and did not contain any solvent of crystallization. The effect of the metallophilic interactions on the absorption properties were studied using TD-DFT methods. The computational results …