Search results for "bioimaging."

showing 10 items of 16 documents

A gas ionisation Direct-STIM detector for MeV ion microscopy

2015

Abstract Direct-Scanning Transmission Ion Microscopy (Direct-STIM) is a powerful technique that yields structural information in sub-cellular whole cell imaging. Usually, a Si p-i-n diode is used in Direct-STIM measurements as a detector. In order to overcome the detrimental effects of radiation damage which appears as a broadening in the energy resolution, we have developed a gas ionisation detector for use with a focused ion beam. The design is based on the ETH Frisch grid-less off-axis Geiger–Muller geometry. It is developed for use in a MeV ion microscope with a standard Oxford Microbeams triplet lens and scanning system. The design has a large available solid angle for other detectors …

Nuclear and High Energy Physicsta114Physics::Instrumentation and Detectorsbusiness.industryChemistryResolution (electron density)DetectorTriplet lensMeV ion microscopeFocused ion beamionisation detectorOpticsIonizationRadiation damagedirect-STIMAtomic physicsbioimagingbusinessInstrumentationField ion microscopeReNcells VMDiodeNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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Naphthalimide imidazolium-based supramolecular hydrogels as bioimaging and theranostic soft materials

2020

1,8-Naphthalimide-based imidazolium salts differing for the alkyl chain length and the nature of the anion were synthesized and characterized to obtain fluorescent probes for bioimaging applications. First, their self-assembly behavior and gelling ability were investigated in water and water/dimethyl sulfoxide binary mixtures. Only salts having longer alkyl chains were able to give supramolecular hydrogels, whose properties were investigated by using a combined approach of fluorescence, resonance light scattering, and rheology measurements. Morphological information was obtained by scanning electron microscopy. In addition, conductive properties of organic salts in solution and gel state we…

Materials scienceCell SurvivalMacromolecular SubstancesSurface PropertiesScanning electron microscopeimidazolium salts010402 general chemistry01 natural sciencesTheranostic Nanomedicinechemistry.chemical_compoundbioimaging; fluorescence; imidazolium salts; naphthalimide; supramolecular hydrogelsCell Line TumorPhase (matter)HumansGeneral Materials ScienceParticle SizeSettore BIO/06 - Anatomia Comparata E CitologiabioimagingAlkylFluorescent Dyeschemistry.chemical_classificationMolecular Structure010405 organic chemistryDimethyl sulfoxideOptical ImagingImidazolesHydrogelsBiological activitySettore CHIM/06 - Chimica OrganicaResonance (chemistry)Combinatorial chemistryFluorescencenaphthalimide0104 chemical sciencesNaphthalimideschemistrySelf-healing hydrogelssupramolecular hydrogelsfluorescence
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Fluorescent supramolecular hydrogels for biomedical applications

2019

hydrogels imidazolium salts supramolecular gels bioimaging anticancer activity
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New supramolecular fluorescent NDI-gels as bioimaging materials

supramolecular gelfluorescenceSettore CHIM/06 - Chimica OrganicabioimagingSettore BIO/06 - Anatomia Comparata E Citologia
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Single Heteroatom Fine-Tuning of the Emissive Properties in Organoboron Complexes with 7-(Azaheteroaryl)indole Systems

2016

The application of organoboron compounds as light-absorbing or light-emitting species in areas as relevant as organic electronics or biomedicine has motivated the search for new materials which contribute to the progress of those applications. This article reports the synthesis of four-coordinate boron complexes based on the unexplored 7-(azaheteroaryl)indole ligands. An easy synthetic approach has enabled the fine-tuning of the electronic structure of the organoboron species by modifying a heteroaromatic component in the conjugated system. Furthermore, a comprehensive characterization by X-ray diffraction, absorption and emission spectroscopy, both in solution and in the solid state, cycli…

Organic electronicsIndole test010405 organic chemistryOrganic ChemistryHeteroatomchemistry.chemical_elementElectronic structureFour-coordinate boron complexFluorophoreConjugated system010402 general chemistryBioimaging01 natural sciencesCombinatorial chemistry0104 chemical scienceschemistryOrganic chemistryEmission spectrumCyclic voltammetryBoronThe Journal of Organic Chemistry
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Upconversion Nanoparticles for Bioimaging and Regenerative Medicine.

2016

Nanomaterials are proving useful for regenerative medicine in combination with stem cell therapy. Nanoparticles can be administrated and targeted to desired tissues or organs and subsequently, be used in non-invasive real-time visualization and tracking of cells by means of different imaging techniques, they can act as therapeutic agent nanocarriers, and can also serve as scaffolds to guide the growth of new tissue. Nanoparticles can be of different chemical nature, such as gold, iron oxide, cadmium selenide, and carbon, and have the potential to be used in regenerative medicine. However, there are still many issues to be solved, such as toxicity, stability, and resident time. Upconversion …

Materials scienceHistologyMini ReviewBiomedical EngineeringNanoparticleNanotechnologyBioengineering02 engineering and technology010402 general chemistry01 natural sciencesRegenerative medicineNanomaterialschemistry.chemical_compoundUpconversion nanoparticlestransparencyCadmium selenideLow toxicityNIR excitationnon-toxic nanoparticlescell behavior regulationfungifood and beveragesBioengineering and Biotechnology021001 nanoscience & nanotechnologymulti-wavelength/multimodal bioimagingPhoton upconversion0104 chemical scienceschemistryupconverted (UV–VIS–NIR) emissionNanocarriers0210 nano-technologyBiotechnologyFrontiers in bioengineering and biotechnology
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Idrogel fluorescenti per applicazioni biomediche

2019

Lo studio di idrogel supramolecolari da utilizzare in ambito biomedico è in continua espansione. Questo è dovuto al fatto che, così come gli idrogel polimerici, mostrano eccellenti proprietà meccaniche, ma possono anche essere sottoposti reversibilmente a rigonfiamento o a transizioni gel-sol in risposta a stimoli esterni (temperatura, pH, enzimi, agenti redox).1Ad esempio, la buona risposta degli idrogel supramolecolari agli stimoli fisiologici, insieme alla loro elevata biodegradabilità e biocompatibilità, ne ha permesso l’utilizzo per la diagnosi tumorale. Solitamente, questi materiali sono facilmente assimilati dalle cellule e hanno la funzione di carrier per le molecole attive nel bioi…

Idrogel bioimaging chimica supramolecolareSettore CHIM/06 - Chimica Organica
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Rapid and eco-friendly synthesis of graphene oxide-silica nanohybrids

2014

The increasing interest in Graphene oxide (GO) is due to many issues: the presence of both sp2-conjugated atoms and oxygen-containing functional groups provides a strong hydrophilicity and the possibility to further functionalize it with other molecules (i.e. π-π interactions covalent attachment etc.) [1]. Furthermore since the GO is biocompatible and noncytotoxic many studies have been recently focused on the development of GO-based nanodevices for bioimaging DNA detection drug delivery. Due to their low cytotoxicity and large internal surface area silica nanoparticles have been taken into account as promising material for biolabeling and drug loading/delivery. Particular consideration has recently been demonstrated for GO-silica composites because of the potentialities for electrical applications their chemical inertia and stability toward ions exposure. The possibility to combine the extraordinary properties of GO and silica offers several advantages for the realization of nanoprobes for biological applications and of biosensor [12]. The strategy for the fabrication of GO-nanosilica nanohybrids can be schematized as follows: (i) synthesis of GO by oxidizing graphite powder with the method described by Marcano et al. [3] (ii) Preparation of oxygen-loaded silica nanoparticles by thermal treatments in controlled atmosphere in order to induce high NIR emission at 1272 nm from high purity silica nanoparticles. (iii) preparation of GrO-silica nanohybrid films via rapid solvent casting in water. The nanohybrids were tested by XPS FTIR Raman analysis UV photoluminescence analysis TGA Zeta potential measurements electrical tests AFM and SEM. Several nanohybrids were prepared by combining two different typologies of GO and two different samples of silica.
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Inorganic Janus particles for biomedical applications.

2014

Based on recent developments regarding the synthesis and design of Janus nanoparticles, they have attracted increased scientific interest due to their outstanding properties. There are several combinations of multicomponent hetero-nanostructures including either purely organic or inorganic, as well as composite organic–inorganic compounds. Janus particles are interconnected by solid state interfaces and, therefore, are distinguished by two physically or chemically distinct surfaces. They may be, for instance, hydrophilic on one side and hydrophobic on the other, thus, creating giant amphiphiles revealing the endeavor of self-assembly. Novel optical, electronic, magnetic, and superficial pro…

Materials scienceBiocompatibilitysynthesisJanus particlesGeneral Physics and AstronomyNanoparticleNanotechnologyJanus particlesProtein CoronaReviewlcsh:Chemical technologylcsh:TechnologyNanomaterialshetero-nanoparticlesprotein coronaMulti-photon)AmphiphileNanotechnologylcsh:TP1-1185General Materials ScienceElectrical and Electronic Engineeringlcsh:ScienceNanoscopic scalePlasmonlcsh:Tbioimaging (CTlcsh:QC1-999Nanosciencelcsh:Qlcsh:PhysicsMRIBeilstein journal of nanotechnology
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E-Beam Crosslinked Polymeric and Bio-Hybrid Nanocarriers for Drug Delivery and Bioimaging

2014

PVPnanogeldrug deliverybioimaging.Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie
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