Search results for "biothiols"

showing 2 items of 2 documents

2,4,5-Triaryl imidazole probes for the selective chromo-fluorogenic detection of Cu(II). Prospective use of the Cu(II) complexes for the optical reco…

2019

The sensing behaviour toward metal cations and biothiols of two 2,4,5-triarylimidazole probes (3a and 3b) is tested in acetonitrile and in acetonitrile-water. In acetonitrile the two probes present charge-transfer absorption bands in the 320-350 nm interval. Among all cations tested only Cu(11) is able to induce bathochromic shifts of the absorption band in the two probes, which is reflected in marked colour changes. Colour modulations are ascribed to the formation of 1:1 Cu(II)-probe complexes in which the cation interacts with the imidazole acceptor heterocycle. Besides, the two probes present intense emission bands (at 404 and 437 nm for 3a and 3b respectively) in acetonitrile that are q…

010402 general chemistryPhotochemistryCu(II) detection01 natural sciencesCu(II) imagingInorganic ChemistryMetalchemistry.chemical_compoundBathochromic shiftMaterials ChemistryImidazolePhysical and Theoretical ChemistryAcetonitrileImidazole-based probesAqueous solutionScience & Technology010405 organic chemistryGSH imagingAcceptor0104 chemical sciences3. Good healthchemistryAbsorption bandvisual_artvisual_art.visual_art_mediumHypsochromic shiftBiothiols recognition
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Biothiols, taurine, and lipid-soluble antioxidants in the edible pulp of Sicilian cactus pear (Opuntia ficus-indica) fruits and changes of bioactive …

2005

Biothiols, taurine, and flavonols, as well as tocopherols and carotenoids have been assessed in the edible pulp of Sicilian red (Sanguigna), yellow (Surfarina), and white (Muscaredda) cultivars of cactus pear. The yellow cultivar has the highest level of reduced glutathione (GSH, 8.1 +/- 0.78 mg/100 g pulp), whereas the white cultivar showed the highest amount of cysteine (1.21 +/- 0.12 mg/100 g pulp). Taurine accounted for 11.7 +/- 1.0 mg/100 g in the yellow pulp, while lower levels were measured in the others. With the exception of kaempferol in the yellow cultivar (2.7 +/- 0.2 microg/100 g pulp), the edible pulp of cactus pear was not a source of flavonols. Very low amounts of lipid-solu…

AntioxidantbiothiolflavonolFood HandlingTaurinemedicine.medical_treatmentTocopherolsindustrial juice.engineering.materialAntioxidantsBeverageschemistry.chemical_compoundFlavonolsstomatognathic systemSpecies SpecificityBotanymedicinebiothiols; taurine; flavonols; tocopherols; carotenoids; cactus pear fruit; industrial juice.TocopherolFood scienceCysteineSulfhydryl CompoundsCarotenoidchemistry.chemical_classificationPEARVitamin EPulp (paper)food and beveragesOpuntiaGeneral ChemistrytocopherolCarotenoidsGlutathioneLipidscarotenoidcactus pear fruitstomatognathic diseaseschemistrySolubilityFruitengineeringGeneral Agricultural and Biological SciencesKaempferolOxidation-ReductionJournal of agricultural and food chemistry
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