Search results for "blend"
showing 10 items of 421 documents
Use of PP-g-OXA in the Compatibilization of PP/LCP Blends
1999
Abstract Adding small amounts of liquid crystalline polymers (LCP) to flexible thermoplastic matrices (FTP) allows to enhance the mechanical and thermomechanical properties. Therefore it is possible to obtain materials with new properties only by simple mixing. A strong shortcoming is the incompatibility between LCP and FTP that leads to materials with very poor properties unusable for commercial pourposes. The presence of a compatibilizer is therefore required. Oxazoline functionality is known to be highly reactive toward many other functional groups and then oxazoline functionalized polymers can be efficiently used as compatibilizer precursors. In this work the compatibilizazion of polypr…
Effectiveness of organoclays as compatibilizers for multiphase polymer blends - A sustainable route for the mechanical recycling of co-mingled plasti…
2014
We prepare and characterize multiphase systems in which small amounts of recycled polymer, namely polyethylene terephtalate (PET) ground from waste bottles, are dispersed in a co-continuous blend of high-density polyethylene (HDPE) and polypropylene (PP). Some of such ternary systems are also filled with plate-like clay nanoparticles with different polarities, in order to assess their influence on the morphology and mechanical behaviour of the blends. On the basis of preliminary wettability considerations and inspections by means of scanning electron microscopy (SEM), the PET is found to preferentially locate within the PP phase. Such a positioning is desirable in order to minimize the pres…
On the mechanism of compatibilization of polyolefin/liquid crystalline polymer blends with graft copolymers
2000
The compatibilization mechanism of some compatibilizers for blends of polyolefins with a liquid crystalline polymer (LCP) was studied. Polyethylene (PE) and polypropylene (PP) were blended with a semirigid LCP (SBH) in a batch mixer, either with and without compatibilizers. The latter were two commercially available samples of functionalized polyolefins, that is, a PE-g-MA (HDM) and a PP-g-AA (Polybond 1001) copolymer and some purposely synthesized PE-g-LCP and PP-g-LCP copolymers. Microtomed films of the binary and the ternary blends were annealed at 240°C on the hot stage of a polarizing microscope and the changes undergone by their morphology were recorded as a function of time. The resu…
Chapter 5.2 The Ancient Gneiss Complex of Swaziland and Environs: Record of Early Archean Crustal Evolution in Southern Africa
2007
Publisher Summary This chapter discusses the record of early Archean crustal evolution in Southern Africa. Southern Africa preserves one of the most complete and detailed records of early Precambrian crustal evolution, and the Ancient Gneiss Complex (AGC) of Swaziland and the related rocks along the southern margin of the 3.5–3.2 Ga Barberton Greenstone Belt (BGB) have played a prominent role in models for the early evolution of continental crust. The AGC is separated from the BGB by a large granitoid sheet-like pluton some 3 Ga in age and known as the Mpuluzi Batholith. In northwest Swaziland, however, small inliers of AGC gneisses occur in faulted and sheared contact with BGB rocks, and t…
Geochronology and palaeomagnetism of a late Proterozoic island arc terrane from the Red Sea Hills, northeast Sudan
1992
Abstract Size fractions and single grains of zircon, hornblende and biotite have been dated to define the formation age and thermal history of the northern Haya Terrane (NHT), a late Proterozoic island arc terrane of the Red Sea Hills (RSH), northeast Sudan. U Pb and 207 Pb/ 206 Pb zircon data for acidic volcanics and granitoid rocks bracket the time of formation of the NHT between 887 ± 20 and 854 ± 9 Ma. 40 Ar/ 39 Ar hornblende and biotite ages of a gabbro near Suakin suggest passage through the argon closing temperature for hornblende at about 841 ± 4 Ma and 782 ± 6 Ma for biotite. The hornblende age is considered to be representative of the age of magnetic blocking and, hence, the age o…
Periodic measures and partially hyperbolic homoclinic classes
2019
In this paper, we give a precise meaning to the following fact, and we prove it: $C^1$-open and densely, all the non-hyperbolic ergodic measures generated by a robust cycle are approximated by periodic measures. We apply our technique to the global setting of partially hyperbolic diffeomorphisms with one dimensional center. When both strong stable and unstable foliations are minimal, we get that the closure of the set of ergodic measures is the union of two convex sets corresponding to the two possible $s$-indices; these two convex sets intersect along the closure of the set of non-hyperbolic ergodic measures. That is the case for robustly transitive perturbation of the time one map of a tr…
Poly(vinyl alcohol)/κ-Carrageenan-based hydrogels enriched with the adhesive mussel protein Pvfp5β as 3D cell culture scaffold for tissue engineering…
2021
Many marine organisms such as sandcastle worms, barnacles and mussels, produce natural adhesives to attach to wet surfaces in aqueous tidal environments. In mussels, the adhesion is possible through the secretion of a protein-based water-resistant glue, composed of a mixture of proteins called mussel adhesive proteins (MAPs) or mussel foot proteins (mfps), that allow anchoring to almost any kind of surface in wet conditions [1]. The proteins confined to adhesive plaques are mfp-2, -3, -4, -5, and -6. All these proteins contain an atypically high concentration of the catecholic amino acid 3,4- dihydroxy-l-phenylalanine (DOPA), obtained by the post-translational enzymatic hydroxylation of tyr…
Photooxidative behaviour of polyethylene/polyamide-6 blends
2010
International audience; The photochemical behaviour of several polyethylene/polyamide-6 blends was studied under conditions of artificial accelerated weathering. Particular attention was paid to five different compositions ranging from pure polyethylene to pure polyamide with blends of PE/PA-6 of various compositions: 75/25, 50/50 and 25/75 wt/wt%. Analysis by infrared spectroscopy of the chemical modifications caused by photooxidation showed that exposing the polyethylene/polyamide-6 blends to UV-light irradiation led to the formation of oxidation photoproducts in both polymer phases. In agreement with both the mechanical and spectroscopic analyses, the photooxidation rate of the blends wa…
Tissue engineered vascular grafts based on poly-lactic acid blends
2013
A great deal of research has been pursued in the last decade with the goal of developing blood vessel substitutes. Tissue engineering has emerged as a promising approach to address the shortcomings of current options. One of the major tasks in this research field is the possibility to tune the biodegradability of the implantable devices (scaffolds). After implantation, the scaffold has to be replaced by extra cellular matrix; with this respect, it is crucial that this replacement takes place with appropriate dynamics and a well-defined timescale. In this work tissue-engineered vascular graft were produced, utilizing several PLLA/PLA blends (100/0, 90/10, 75/25 wt/wt) in order to tune their …
Seamless Learning Environments in Higher Education with Mobile Devices and Examples
2016
The use of seamless learning environments that have the potential to support lifelong learning anytime and anywhere has become a reality. In this sense, many educational institutions have started to consider introducing seamless learning environments into their programs. The aim of this study is to analyze how various educational university programs implement the design elements for seamless learning environments with mobile devices. For that purpose, three cases involved in a Finnish teaching development project are explored by conducting semi-structured interviews with key participants. The themes of the interviews were related to the theoretical background for (mobile) seamless learning …