Search results for "block"
showing 10 items of 1177 documents
Synthesis and characterization of a new layered organic-inorganic hybrid nickel(II) 1,4 : 5,8-naphthalenediimide bis-phosphonate, exhibiting canted a…
2008
A new Ni(II) layered hybrid organic-inorganic compound of formula Ni{sub 2}[(NDI-BP)(H{sub 2}O){sub 2}].2H{sub 2}O has been prepared in very mild conditions from N,N'-bis(2-phosphonoethyl)napthalene-1,4:5,8-tetracarboximide (NDI-BP ligand) and NiCl{sub 2}. The X-ray powder structure characterization of the title compound suggests a pillared layered organic-inorganic hybrid structure. The distance between the organic and inorganic layers has been found to be 17.8 A. The inorganic layers consist of corner sharing [NiO{sub 5}(H{sub 2}O)] octahedra and they are pillared by the diphosphonate groups. DC and AC magnetic measurements as a function of temperature and field indicate the presence of 2…
The solubilisation behaviour of some dichloroalkanes in aqueous solutions of PEO-PPO-PEO triblock copolymers: a dynamic light scattering, fluorescenc…
2006
The aggregation behaviour of PEO-PPO-PEO triblock copolymers in water and in water + chlorinated additive mixtures was studied by means of fluorescence spectroscopy, dynamic light scattering (DLS), and small-angle neutron scattering (SANS). The copolymers were chosen such as to investigate the effects of molecular architecture (L35 and 10R5) and molecular weight by keeping constant the hydrophilic/hydrophobic balance (F88 and F108). 1,2-Dichloroethane was used as a prototype of water basins contaminants. The hydrodynamic radius of the block copolymer aggregates (R(h,M)) and the intensity ratio of pyrene of the first and the third vibrational band (I(1)/I(3)) were determined as a function of…
Neutron-Induced Effects on a Self-Refresh DRAM
2022
International audience; The field of radiation effects in electronics research includes unknowns for every new device, node size, and technical development. In this study, static and dynamic test methods were used to define the response of a self-refresh DRAM under neutron irradiation. The neutron-induced effects were investigated and characterised by event cross sections, soft-error rate, and bitmaps evaluations, leading to an identification of permanent and temporary stuck cells, single-bit upsets, and block errors. Block errors were identified in different patterns with dependency in the addressing order, leading to up to two thousand faulty words per event, representing a real threat fr…
Rapid Access to Polyfunctional Lipids with Complex Architecture via Oxyanionic Ring-Opening Polymerization
2011
Polymer-coated liposomes, particularly poly(ethylene glycol) (PEG)-substituted liposomes, have emerged as long-circulating carrier systems for drug delivery and diagnostic purposes. A rapid synthesis of three different types of multifunctional lipids with structurally diverse hydrophilic, polyether-based architectures via one- or two-pot approaches is described. Architectural variation is achieved by the combination of different oxyanionic polymerization strategies and various glycidyl ether building units. Branched polyglycerol lipids have been prepared via cholesterol- or 1,2-bis-n-alkyl glyceryl ether-initiated, oxyanionic ring-opening polymerization (ROP) of protected glycidyl ethers an…
Optimal MAC PDU Size in IEEE 802.16
2008
In the IEEE 802.16 the number of errors and the MAC PDU size have an impact on the performance of the network. We present a way to estimate the optimal PDU size and we run a number of simulation scenarios to study these parameters and how they impact on the performance of application protocols. The simulation results reveal that the channel bit error rate has a major impact on the optimal PDU size in the IEEE 802.16 networks. Also, the ARQ block rearrangement influences the performance.
Performance Evaluation of the IEEE 802.16 ARQ Mechanism
2007
The IEEE 802.16 technology defines the ARQ mechanism that enables a connection to resend data at the MAC level if an error is detected. In this paper, we analyze the key features and parameters of the ARQ mechanism. In particular, we consider a choice for the ARQ feedback type, a scheduling of the ARQ feedbacks and retransmissions, the ARQ block rearrangement, ARQ transmission window and ARQ block size. We run a number of simulation scenarios to study these parameters and how they impact a performance of application protocols. The simulation results reveal that the ARQ mechanism plays an important role in transmitting data over wireless channels in the IEEE 802.16 networks.
A performance analysis of block ACK scheme for IEEE 802.11e networks
2010
The demand for the IEEE 802.11 wireless local-area networks (WLANs) has been drastically increasing along with many emerging applications and services over WLAN. However, the IEEE 802.11 medium access control (MAC) is known to be limited in terms of its throughput performance due to the high MAC overhead, such as interframe spaces (IFS) or per-frame based acknowledgement (ACK) frame transmissions. The IEEE 802.11e MAC introduces the block ACK scheme for improving the system efficiency of the WLAN. Using the block ACK scheme can reduce the ACK transmission overhead by integrating multiple ACKs for a number of data frames into a bitmap that is contained in a block ACK frame, thus increasing t…
Interleukin 9 neutralisation reduces collagen-induced arthritis severity in mouse models.
2021
Objective Interleukin 9 (IL-9) is a mediator of tissue damage in several inflammatory diseases. In this study we aimed to evaluate the effects of in vivo IL-9 neutralisation in mice developing collagen induced arthritis (CIA). Methods DBA/1 were immunised with collagen in Freund’s complete adjuvant (CFA) to induce arthritis. Anti-IL-9 mAb was injected in mice after the onset of arthritis (Group A) or on the same day as sensitisation and again on the day of the challenge (Group B). Histological analysis was performed in joints of mice and spleen cells were also analysed by flow cytometry. A geneset analysis was carried out on whole tarsal joint tissue transcriptomes. Results IL-9 was over-ex…
Structure and function of the vacuolar Ccc1/VIT1 family of iron transporters and its regulation in fungi
2020
Iron is an essential micronutrient for most living beings since it participates as a redox active cofactor in many biological processes including cellular respiration, lipid biosynthesis, DNA replication and repair, and ribosome biogenesis and recycling. However, when present in excess, iron can participate in Fenton reactions and generate reactive oxygen species that damage cells at the level of proteins, lipids and nucleic acids. Organisms have developed different molecular strategies to protect themselves against the harmful effects of high concentrations of iron. In the case of fungi and plants, detoxification mainly occurs by importing cytosolic iron into the vacuole through the Ccc1/V…
Challenges and Opportunities using MultiChain for Real Estate
2019
The real estate market involves multiple untrusted actors with contrasting objectives. We propose REchain, a blockchain-based platform for real estate, which provides benefits to all actors in terms of transparency, trust, immutability, and traceability. REchain architecture handles real estate data through well-defined workflows that leverage the MultiChain platform. REchain changes the real estate market enabling direct transactions without intermediaries, and providing new mechanisms for negotiating the purchase conditions. This paper refutes the misleading idea of using blockchains for solving generic problems as blockchain platforms have peculiar features that make them suitable for sp…