Search results for "bond"

Determination of the Stability Constants of the Acetate Complexes of the Actinides Am(III), Th(IV), Np(V), and U(VI) Using Capillary Electrophoresis-…

2019

Capillary electrophoresis-inductively coupled plasma mass spectrometry (CE-ICP-MS) was used to determine the stability constants of the actinides Am(III), Th(IV), Np(V), and U(VI) at an ionic strength of I = 0.3 M. The obtained stability constants were extrapolated to zero ionic strength by means of the Davies equation. For both U(VI) and Am(III), three consecutive acetate complexes with log(β

Molecular organization via ionic interactions at interfaces. 1. Monolayers and LB films of cyclic bisbipyridinium tetracations and dimyristoylphospha…

1993

Study of the effect of the membrane composition on ion transfer across a supported liquid membrane

2003

Abstract The rate of ion transfer across the supported liquid membrane (SLM) is studied in the rotating diffusion cell (RDC), varying the chemical composition of the SLM from net-cloth supported gel membranes to radiation-grafted polymer membranes. Steady-state current–voltage curves are measured as a function of the rotation rate, and values for the standard rate constant, k 0 , are determined for a series of tetraalkylammonium cations from the analysis of the initial slopes and the diffusion limiting currents. The analysis gives values for k 0 of the order of 10 −2 –10 −4 cm s −1 , which is in rather good agreement with the values found in the literature for this type of the system. As co…

Comparison of the performance of non-ionic and anionic surfactants as mobile phase additives in the RPLC analysis of basic drugs

2011

Surfactants added to the mobile phases in reversed-phase liquid chromatography (RPLC) give rise to a modified stationary phase, due to the adsorption of surfactant monomers. Depending on the surfactant nature (ionic or non-ionic), the coated stationary phase can exhibit a positive net charge, or just change its polarity remaining neutral. Also, micelles in the mobile phase introduce new sites for solute interaction. This affects the chromatographic behavior, especially in the case of basic compounds. Two surfactants of different nature, the non-ionic Brij-35 and the anionic sodium dodecyl sulfate (SDS) added to water or aqueous-organic mixtures, are here compared in the separation of basic …

Quantitative Retention−Structure and Retention−Activity Relationship Studies of Local Anesthetics by Micellar Liquid Chromatography

2011

The retention of compounds in micellar liquid chromatography (MLC) is governed by hydrophobic and electrostatic forces. For ionic compounds, both interactions should be considered. The present report offers a novel retention model that includes the hydrophobicity of compounds and the molar fraction of the charged form of compounds and compares it with other previously reported models. High correlations between the logarithm of capacity factors and these structural parameters were obtained for local anesthetics with different degrees of ionization using a nonionic surfactant solution as mobile phase. Modeling the retention of compounds as a function of physicochemical parameters and experime…

Quantitative retention—structure and retention—activity relationship studies of ionic and non-ionic catecholamines by micellar liquid chromatography

1997

When ionic surfactants are used as mobile phases in micellar liquid chromatography, MLC, the retention of compounds is governed by hydrophobic and electrostatic forces. In the absence of electrostatic effects, the hydrophobicity of a compound is the predominant factor affecting its retention and its interaction with micelles. Because both interactions should be considered for ionic compounds, a novel retention model is proposed which includes the hydrophobicity of a compound and the molar fraction of its charged form. High correlations between the logarithm of the capacity factors and structural parameters were obtained for ionic compounds with different degrees of ionization. The effect of…

Micellar versus hydro-organic reversed-phase liquid chromatography: a solvation parameter-based perspective.

2007

The performance of the solvation parameter model is examined for micellar liquid chromatography. The results are compared with those offered with hydro-organic eluents, intending to reveal the properties that influence the retention and distinguish the particular behaviour of micellar systems. The retention data of several series of non-ionisable and ionisable compounds (mainly steroids, polyaromatic hydrocarbons, phenols, sulfonamides, beta-blockers, phenethylamines, antihistamines, and diuretics) were used as probe compounds. The micellar mobile phases contained an anionic (sodium dodecyl sulphate), non-ionic (Brij-35), or cationic (cetyltrimethylamonium bromide) surfactant, with or witho…

Retention mechanisms in micellar liquid chromatography.

2008

Micellar liquid chromatography (MLC) is a reversed-phase liquid chromatographic (RPLC) mode with mobile phases containing a surfactant (ionic or non-ionic) above its critical micellar concentration (CMC). In these conditions, the stationary phase is modified with an approximately constant amount of surfactant monomers, and the solubilising capability of the mobile phase is altered by the presence of micelles, giving rise to diverse interactions (hydrophobic, ionic and steric) with major implications in retention and selectivity. From its beginnings in 1980, the technique has evolved up to becoming a real alternative in some instances (and a complement in others) to classical RPLC with hydro…

Performance of a series of novel N-substituted acrylamides in capillary electrophoresis of DNA fragments

1996

DNA separations by capillary electrophoresis in viscous solutions of novel polymers, made with Ω-hydroxyl, N-substituted acrylamides (notably N-acryloyl amino propanol, AAP and N-acryloyl amino butanol, AAB) are evaluated. Whereas in standard poly(acrylamide), at 6% concentration, the theoretical plate number (N) does not exceed 500 000, in 6% poly(AAP) N reaches 922 000 and in 6% poly(AAB) N values as high as 1 200 000 are obtained. Also, copolymers of AAP and AAB give N values in excess of 1 million plates. The two novel monomers (AAP and AAB) remain extremely stable during alkaline hydrolysis and display very good hydrophilicity, while being devoid of the noxious habit of auto-polymeriza…

Ionomers in solution: 1. Viscometric and chromatographic studies in cononsolvent and cosolvent mixtures

1997

Abstract The viscosity and elution behaviour of polystyrene sulfonate ionomers with varying ionic content has been studied in the pure solvents chloroform (CHL), tetrahydrofuran (THF), dioxan (DIO), ethyl acetate (EA) and dimethylformamide (DMF) as well as in their cononsolvent mixtures CHL/THF (50:50), DIO/CHL (75:25) and in the cosolvent mixture EA/DMF (50:50). In the pure solvents with low dielectric constant the reduced viscosities of ionomers are lower at low concentrations and higher at moderate ones than the respective viscosities of the polystyrene precursor. These results can be explained by formation of intramolecular and intermolecular associations. Moreover, differences in visco…