Search results for "bound"

showing 10 items of 2948 documents

On-Surface Synthesis of Unsaturated Carbon Nanostructures with Regularly Fused Pentagon–Heptagon Pairs

2020

Multiple fused pentagon-heptagon pairs are frequently found as defects at the grain boundaries of the hexagonal graphene lattice and are suggested to have a fundamental influence on graphene-related materials. However, the construction of sp2-carbon skeletons with multiple regularly fused pentagon-heptagon pairs is challenging. In this work, we found that the pentagon-heptagon skeleton of azulene was rearranged during the thermal reaction of an azulene-incorporated organometallic polymer on Au(111). The resulting sp2-carbon frameworks were characterized by high-resolution scanning probe microscopy techniques and feature novel polycyclic architectures composed of multiple regularly fused pen…

ChemistryGraphene530 PhysicsCommunicationAromaticityGeneral ChemistryElectronic structureAzulene010402 general chemistry01 natural sciencesBiochemistryCatalysis0104 chemical scienceslaw.inventionchemistry.chemical_compoundScanning probe microscopyCrystallographyColloid and Surface ChemistrylawLattice (order)540 ChemistryGrain boundaryHeptagonPhysics::Chemical PhysicsJournal of the American Chemical Society
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Improved embedded molecular cluster model

2002

We demonstrate that boundary effects (i.e., displacements of the cluster boundary atoms from their lattice sites and the difference between effective charges of the perfect crystal atoms and those of the cluster atoms in the case of a cluster with no point defect in it) in an embedded molecular cluster (EMC) model can be radically reduced. A new embedding scheme is proposed. It includes search for the structural elements (SE) of which perfect crystal is composed, use of corresponding to these SE expression for the total energy, and application of the degree of localization of equations consistent with the wave functions of the cluster. To get equations for the cluster wave functions, the pr…

ChemistryMathematical analysisCondensed Matter PhysicsAtomic and Molecular Physics and OpticsCoupled clusterPerfect crystalLattice (order)Quantum mechanicsCluster (physics)EmbeddingBoundary value problemPhysical and Theoretical ChemistryWave functionEigenvalues and eigenvectorsInternational Journal of Quantum Chemistry
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Chiral symmetry and pi-pi scattering in the Covariant Spectator Theory

2014

The pi-pi scattering amplitude calculated with a model for the quark-antiquark interaction in the framework of the Covariant Spectator Theory (CST) is shown to satisfy the Adler zero constraint imposed by chiral symmetry. The CST formalism is established in Minkowski space and our calculations are performed in momentum space. We prove that the axial-vector Ward-Takahashi identity is satisfied by our model. Then we show that, similar to what happens within the Bethe-Salpeter formalism, application of the axial-vector Ward-Takahashi identity to the CST pi-pi scattering amplitude allows us to sum the intermediate quark-quark interactions to all orders. The Adler self-consistency zero for pi-pi…

Chiral symmetryNuclear Theory (nucl-th)High Energy Physics - PhenomenologyCovariant spectator theoryHigh Energy Physics - Phenomenology (hep-ph)Nuclear TheoryHigh Energy Physics::LatticeNuclear TheoryHigh Energy Physics::PhenomenologyQuark-antiquark bound statesFOS: Physical sciences
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P-T path development derived from shearband boudin microstructure

2016

This work focuses on the development of a regional P-T-path from the Malpica-Lamego Ductile Shear Zone, NW Portugal, based on the microstructures of shearband boudins evolved during progressive simple shear. The combination of microstructural analysis, fluid inclusion studies, crystallographic pre- ffered orientation and fractal geometry analyses, allows to link several stages in the internal evolution of the boudin to regional P-T conditions. The boudinage process is initiated under differential stress after the original layer achieved sufficient viscosity contrast relative to the surrounding matrix. Two main transformations occur simultaneously: i) change in the external shape with contin…

Ciências Naturais::Ciências da Terra e do Ambiente010504 meteorology & atmospheric sciencesMineralogyQuartz CPO e Fabric AnalyserGeometry010502 geochemistry & geophysics01 natural sciencesBoudinageQuartz microstructure:Ciências da Terra e do Ambiente [Ciências Naturais]0105 earth and related environmental sciencesScience & Technology4. EducationQuartz CPO - Fabric AnalyserGeologyP-T-pathShearband boudinSimple shearStrain partitioningFractal geometryPTVX fluid inclusionShear (geology)Dynamic recrystallizationGrain boundaryShear zoneDifferential stressGeology
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Use of Ultrasound in Reconditioning by Welding of Tools Used in the Process of Regenerating Rubber

2018

Addressing the problem of reconditioning large parts is of particular importance, due to their value and to the fact that the technologies for their reconditioning are very complex. The tools used to refine regenerated rubber which measure 660 mm in diameter and 2130 mm in length suffer from a rather fast dimensional wear. Within this research, the authors looked for a welding reconditioning procedure that would allow a very good adhesion between the deposited material layer and the base material. In this regard, the MAG (Metal Active Gas) welding process was used, but the ultrasonic activation of the welding process was also considered. Thus, the wire used for welding was activated conside…

Cladding (metalworking)0209 industrial biotechnologyMaterials science02 engineering and technologyWeldingultrasoundsprocess; reconditioning; welding; ultrasounds; tools; regenerated rubberArticleCorrosionlaw.invention020901 industrial engineering & automationNatural rubberlawDeposition (phase transition)processGeneral Materials ScienceComposite materialwelding021001 nanoscience & nanotechnologyvisual_arttoolsvisual_art.visual_art_mediumregenerated rubberUltrasonic sensorGrain boundaryreconditioning0210 nano-technologyLayer (electronics)Materials; Volume 11; Issue 2; Pages: 276
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Upper Bound for the Approximation Error for the Kirchhoff-Love Arch Problem

2013

In this paper, a guaranteed and computable upper bound of approximation errors for the Kirchhoff-Love arch problem is derived. In general, it belongs to the class of functional a posteriori error estimates. The derivation method uses purely functional arguments and, therefore, the estimates are valid for any conforming approximation within the energy space. The computational implementation of the upper bound is discussed and demonstrated by a numerical example.

Class (set theory)Approximation errorA priori and a posterioriApplied mathematicsDerivation methodArchSpace (mathematics)Upper and lower boundsEnergy (signal processing)Mathematics
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Radial symmetry of minimizers to the weighted Dirichlet energy

2020

AbstractWe consider the problem of minimizing the weighted Dirichlet energy between homeomorphisms of planar annuli. A known challenge lies in the case when the weight λ depends on the independent variable z. We prove that for an increasing radial weight λ(z) the infimal energy within the class of all Sobolev homeomorphisms is the same as in the class of radially symmetric maps. For a general radial weight λ(z) we establish the same result in the case when the target is conformally thin compared to the domain. Fixing the admissible homeomorphisms on the outer boundary we establish the radial symmetry for every such weight.

Class (set theory)Computer Science::Information RetrievalGeneral Mathematics010102 general mathematicsMathematical analysisSymmetry in biologyBoundary (topology)Dirichlet's energy01 natural sciencesDomain (mathematical analysis)010101 applied mathematicsSobolev spacePlanar0101 mathematicsEnergy (signal processing)MathematicsProceedings of the Royal Society of Edinburgh: Section A Mathematics
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Systematisation of Systems Solving Physics Boundary Value Problems

2020

A general conservation law that defines a class of physical field theories is constructed. First, the notion of a general field is introduced as a formal sum of differential forms on a Minkowski manifold. By the action principle the conservation law is defined for such a general field. By construction, particular field notions of physics, e.g., magnetic flux, electric field strength, stress, strain etc. become instances of the general field. Hence, the differential equations that constitute physical field theories become also instances of the general conservation law. The general field and the general conservation law together correspond to a large class of relativistic hyperbolic physical …

Class (set theory)Conservation lawField (physics)numeeriset menetelmätDifferential equationDifferential formAction (physics)AlgebraMinkowski spacelaskennallinen tiedeBoundary value problemfysiikkadifferentiaaliyhtälötnumerical mathematics
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Duality theory for multi-marginal optimal transport with repulsive costs in metric spaces

2018

In this paper we extend the duality theory of the multi-marginal optimal transport problem for cost functions depending on a decreasing function of the distance (not necessarily bounded). This class of cost functions appears in the context of SCE Density Functional Theory introduced in "Strong-interaction limit of density-functional theory" by M. Seidl.

Class (set theory)Control and OptimizationComputer Science::Information Retrieval010102 general mathematicsFOS: Physical sciencesContext (language use)Function (mathematics)Mathematical Physics (math-ph)01 natural sciences010101 applied mathematicsComputational MathematicsMetric spaceMathematics - Analysis of PDEsControl and Systems EngineeringOptimization and Control (math.OC)Bounded functionFOS: MathematicsApplied mathematicsDensity functional theoryLimit (mathematics)0101 mathematicsMathematics - Optimization and ControlMathematical PhysicsMathematicsAnalysis of PDEs (math.AP)
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Bounding Techniques and Their Application to Simplified Plastic Analysis of Structures

1990

In the framework of the simplified analysis methods for elastoplastic analysis problems, the bounding techniques possess an important role. A class of these techniques, based on the so-called perturbation method, are here presented with reference to finite element discretized structures. A general bounding principle is presented and its applications are illustrated by means of numerical examples.

Class (set theory)DiscretizationBounding overwatchComputer scienceApplied mathematicsPerturbation methodFinite element methodAnalysis method
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