Search results for "carbon"

Chronospeciation of uranium released in soil during a long-term DU shell weathering experiment.

2021

Corrosion process was investigated of depleted uranium (DU) ammunition fragments buried for three years in aerobic soils continuously irrigated with water. The continuing corrosion process was triggered through formation of soluble uranyl oxyhydrate phases such as metaschoepite and becquerelite, which were identified by micro-Raman and X-ray diffraction spectroscopy. The soil was not amended by phosphates and, therefore, no uranyl phosphates were found as corrosion products on the DU surfaces by X-ray photoelectron spectroscopy. A speciation modelling at high temporal sequence (chronospeciation approach) indicated that the abundant Fe oxyhydroxides in the soil immobilized the U(IV) released…

ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …

2019

Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …

Asynchronous changes of CO2, H2, and He concentrations in soil gases: A theoretical model and experimental results

2016

Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.

2012

Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…

High-resolution spectroscopy and analysis of the nu3/2nu4 dyad of CF4

2011

International audience; CF4 is a strong greenhouse gas of both anthropogenic and natural origin [D.R. Worton et al., Environ. Sci. Technol. 41, 2184 (2007)]. However, high-resolution infrared spectroscopy of this molecule has received only a limited interest up to now. Until very recently, the public databases only contained cross-sections for this species, but no detailed line list. We reinvestigate here the strongly absorbing ν3 region around 7.8 μm. New Fourier transform infrared (FTIR) spectra up to a maximal resolution of 0.0025 cm−1 have been recorded: (i) room-temperature spectra in a static cell and (ii) a supersonic expansion jet spectrum at a 23 K estimated temperature. Following …

High time resolution fluctuations in volcanic carbon dioxide degassing from Mount Etna

2014

Abstract We report here on the first record of carbon dioxide gas emission rates from a volcano, captured at ≈ 1 Hz. These data were acquired with a novel technique, based on the integration of UV camera observations (to measure SO2 emission rates) and field portable gas analyser readings of plume CO2/SO2 ratios. Our measurements were performedat the North East crater of Mount Etna, southern Italy, and the data reveal strong variability in CO2 emissions over timescales of tens to hundreds of seconds, spanning two orders of magnitude. This carries importantimplications for attempts to constrain global volcanic CO2 release to the atmosphere, and will lead to an increased insight into short te…

Is there a global carbonate layer in the oceanic mantle?

2021

co-auteur étranger; International audience; Previous modeling of carbonate subduction by high‐pressure experimentation has allowed to propose scenarios for bulk carbon return to the mantle, but the detailed transfer mechanisms have seldom been studied. We monitored carbonate – silicate reactions by combining high‐pressure experiments and synchrotron‐based x‐ray diffraction. Carbonates break down at moderate pressure and high temperature and CO2 is trapped at grain boundaries. Further isothermal compression yields melting, which may control continuous carbon introduction, first in the mantle wedge, and next, away from the wedge. Carbon presence has been discussed in a variety of magmatic con…

Humusica 2, article 19: Techno humus systems and global change - Conservation agriculture and 4/1000 proposal

2018

International audience; Philosophy can overlap pedology. It is not casual that life begins and finishes in the soil. We separated the concepts of Humipedon, Copedon and Lithopedon. Some sections were dedicated to the founders of the movement for a new type of agriculture (agroecology). They simply proclaim to accompany the process of natural evolution instead of spending a lot of energy in hunting competitor organisms with pesticides or boosting the soil with mineral fertilisation and tillage. The core of the article is built on a biological concept of the soil and shows researches supporting this view. After pointing to the soil structure and illustrating its natural genesis, explaining wh…

Bioconcentration, biotransformation and elimination of pyrene in the arctic crustacean Gammarus setosus (Amphipoda) at two temperatures

2015

The influence of temperature on the bioaccumulation, toxicokinetics, biotransformation and depuration of pyrene was studied in the arctic marine amphipod Gammarus setosus. A two-compartment model was used to fit experimental values of total body burden, total metabolites and parent pyrene concentrations and to calculate toxicokinetic variables derived for two experimental treatments (2 and 8 °C). No statistically significant differences were observed with temperature for these toxicokinetic variables or bioconcentration factors. Contrarily, the Q10 values suggested that the toxicokinetic variables ke and km were temperature-dependent. This may be explained by the high standard deviation of …

Trace elements in the thermal groundwaters of Vulcano Island (Sicily)

2000

The chemical concentrations of many trace elements that have never before been examined in Vulcano Island groundwaters are reported. Chemical data indicate that rock composition is not the only factor determining the metal content in the aqueous system. The observed concentrations depend mainly on: (1) the chemical composition of the host rocks; (2) the chemical–physical conditions of the weathering solution (temperature, acidity, redox conditions); (3) input of magmatic gases; (4) adsorption of metal ions on oxide particles, formation of soluble complexes and/or precipitation of solid phases. Chloride complexes in solution are of minimal significance for all elements with the exception of …