Search results for "carbonate"
showing 10 items of 920 documents
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Impact of basin burial and exhumation on Jurassic carbonates diagenesis on both sides of a thick clay barrier (Paris Basin, NE France).
2014
27 pages; International audience; Several diagenetic models have been proposed for Middle and Upper Jurassic carbonates of the eastern Paris Basin. The paragenetic sequences are compared in both aquifers to propose a diagenetic model for the Middle and Late Jurassic deposits as a whole. Petrographic (optical and cathodoluminescence microscopy), structural (fracture orientations) and geochemical (δ18O, δ13C, REE) studies were conducted to characterize diagenetic cements, with a focus on blocky calcite cements, and their connection with fracturation events. Four generations of blocky calcite (Cal1-Cal4) are identified. Cal1 and Cal2 are widespread in the dominantly grain-supported facies of t…
Oligo-Miocene lacustrine microbial and metazoan buildups from the Limagne Basin (French Massif Central)
2018
The Limagne Basin (French Massif Central) is an extensive continental lacustrine system accommodating microbial and metazoan buildups from Chattian to Aquitanian age. A description of these buildups and their associated biotic components in Grand Gandaillat and Crechy quarries provides insights into their spatio-temporal distribution patterns. Flats, cauliflowers, domes, cones and coalescent columnar morphologies have been identified with a main laminated mesofabric and laminated, columnar, filamentous and caddisfly-coated microfabrics. Two low-gradient margin models emerged based on the changes in the distribution, morphology and size of the microbial and metazoan-rich deposits through tim…
Some sedimentological and geochemical characters of the late Triassic Noto formation, source rock in the Ragusa basin (Sicily)
1990
URA 724 du CNRS a intégré UMR 6113 - ISTO CNRS Université d'Orléans; In the Ragusa basin (southeastern Sicily), the late Triassic Noto formation is considered as the main oil source rock. We provide a detailed description of the sedimentary facies determined from core samples, and discuss geochemical results, obtained for both kerogens and chloroform extractable hydrocarbons from samples where sedimentary organic matter is immature. Two main sedimentary sequences were encountered: (i) layers of limestones and of marls (or shales) alternating at a metric scale, and (ii) laminites having various types and carbonate contents. The high petroleum potentials (S2 up to 100 kg HC/t rock) are relate…
Reactive transport modelling of carbonate cementation in a deep saline aquifer, the Middle Jurassic Oolithe Blanche Formation, Paris Basin, France.
2016
10 pages; International audience; The Oolithe Blanche Formation (Bathonian, Middle Jurassic) is one of the deep saline aquifers of the Paris Basin in France. The spatial distribution of its reservoir properties (porosity, permeability, tortuosity, etc.) is now better known with relatively homogeneous properties, except for some levels in the central part of the basin, where permeability exhibits higher values. This spatial distribution has been correlated with diagenetic events (variability of cementation) and palaeo-fluid flow circulation phases leading to variable cementation. In this paper, numerical simulations of reactive transport are performed. They provide a preliminary quantitative…
Petrographic and geochemical characterization of the Middle‒Upper Jurassic Fe–Mn crusts and mineralizations from Monte Inici (north-western Sicily): …
2021
AbstractFe–Mn concretions and mineralizations, associated with condensed horizons and hardground, are significant archives in ancient carbonate rocks. Their petro-chemical study allows an assessment of the palaeoenvironmental context in which they were formed also connected to their biotic or abiotic origin. At the western side of the Monte Inici (Fornazzo section, north-western Sicily) a well exposed outcrop of condensed pelagic limestones (Rosso Ammonitico facies: Middle‒Upper Jurassic) is well-known and thoroughly studied. In this section, the base of the Rosso Ammonitico facies consists of a very condensed level rich in fossils with a variable thickness deposited from the early Bathonia…
ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …
2019
Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …
Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.
2012
Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…
Is there a global carbonate layer in the oceanic mantle?
2021
co-auteur étranger; International audience; Previous modeling of carbonate subduction by high‐pressure experimentation has allowed to propose scenarios for bulk carbon return to the mantle, but the detailed transfer mechanisms have seldom been studied. We monitored carbonate – silicate reactions by combining high‐pressure experiments and synchrotron‐based x‐ray diffraction. Carbonates break down at moderate pressure and high temperature and CO2 is trapped at grain boundaries. Further isothermal compression yields melting, which may control continuous carbon introduction, first in the mantle wedge, and next, away from the wedge. Carbon presence has been discussed in a variety of magmatic con…
Trace elements in the thermal groundwaters of Vulcano Island (Sicily)
2000
The chemical concentrations of many trace elements that have never before been examined in Vulcano Island groundwaters are reported. Chemical data indicate that rock composition is not the only factor determining the metal content in the aqueous system. The observed concentrations depend mainly on: (1) the chemical composition of the host rocks; (2) the chemical–physical conditions of the weathering solution (temperature, acidity, redox conditions); (3) input of magmatic gases; (4) adsorption of metal ions on oxide particles, formation of soluble complexes and/or precipitation of solid phases. Chloride complexes in solution are of minimal significance for all elements with the exception of …