Search results for "carbonatite"

Geochemical characteristics of Cretaceous carbonatites from Angola

1999

Abstract The Early Cretaceous (138–130 Ma) carbonatites and associated alkaline rocks of Angola belong to the Parana-Angola-Etendeka Province and occur as ring complexes and other central-type intrusions along northeast trending tectonic lineaments, parallel to the trend of coeval Namibian alkaline complexes. Most of the Angolan carbonatite-alkaline bodies are located along the apical part of the Mocamedes Arch, a structure representing the African counterpart of the Ponta Grossa Arch in southern Brazil, where several alkaline-carbonatite complexes were also emplaced in the Early Cretaceous. Geochemical and isotopic (C, 0, Sr and Nd) characteristics determined for five carbonatitic occurren…

Between carbonatite and lamproite - Diamondiferous Torngat ultramafic lamprophyres formed by carbonate-fluxed melting of cratonic MARID-type metasomes

2008

Abstract New U–Pb perovskite ages reveal that diamondiferous ultramafic lamprophyre magmas erupted through the Archean crust of northern Labrador and Quebec (eastern Canada) between ca. 610 and 565 Ma, a period of strong rifting activity throughout contiguous Laurentia and Baltica. The observed Torngat carbonate-rich aillikite/carbonatite and carbonate-poor mela-aillikite dyke varieties show a large spread in Sr–Nd–Hf–Pb isotope ratios with pronounced correlations between isotope systems. An isotopically depleted component is identified solely within aillikites (87Sr/86Sri = 0.70323–0.70377; eNdi = +1.2–+1.8; eHfi = +1.4–+3.5; 206Pb/204Pbi = 18.2–18.5), whereas some aillikites and all mela-…

Carbonatites from the southern Brazilian Platform: A review. II: Isotopic evidences

2020

Early and Late Cretaceous alkaline and alkaline–carbonatitic complexes from southern Brazil are located along the main tectonic lineaments of the South America Platform. Calcium-, magnesium-, and ferrocarbonatites are well represented and frequently associated even in the same complex. Primary carbonates present significant variations in C–O isotopic compositions, which are mainly due to isotope exchange with H2O–CO2-rich hydrothermal fluids, whereas fractional crystallization or liquid immiscibility probably affects the δ18O and δ13C values by no more than 2δ‰. Our isotope exchange model implies that the most significant isotopic variations took place in a hydrothermal environment, e.g., i…

Carbonatites from the Southern Brazilian platform: I

2020

We present a comprehensive overview of the geochemical characteristics and evolution of the carbonatites from the southern Brazilian Platform (Paraná Basin). The carbonatites from different complexes display large compositional variability in terms of abundances of incompatible and rare earth elements. This is in agreement with an origin from heterogeneous lithospheric sources, as confirmed by isotopic data (see Speziale et al., this issue). The characteristic major and trace element abundances of these carbonatites present compelling evidence for invoking liquid unmixing as the main mechanism of their formation and evolution albeit few exceptions. We propose an evolutionary trend for the B…

Procesos hidrotermales con enriquecimiento en REE en las carbonatitas de Fuerteventura: evidencias en minerales accesorios

2021

Carbonatitic dykes that crop out in the central western part of Fuerteventura Basal Complex (Ajuy, Punta de la Nao), were affected by the Miocene intrusive event responsible for contact metamorphism and partial melting of part of the alkaline-carbonatitic complex. Textural characteristics, monazite enriched in LREE (La, Ce, Nd) formation processes in microfractures that affect zircon crystals, show carbonatite interactions with hydrothermal fluids and partial REE remobilization. Pyrochlore is the main mineral carrier of rare earth elements (sum REE=216694 ppm), with high LREE (LaN=185816 and CeN=165209) with respect to HREE (YbN=2589 and LuN=1814) with a rather steep pattern (La/Yb)N=72 in …

Hydrothermal processes with REE enrichment in Fuerteventura carbonatites: evidences in accessory minerals

2021

Los diques carbonatíticos que afloran en la parte centro-occidental del Complejo Basal de Fuerteventura (Ajuy, Punta de la Nao), fueron afectados por el evento intrusivo mioceno responsable del metamorfismo de contacto y fusión parcial de parte del complejo alcalino-carbonatítico. Las características texturales, los procesos de formación de monacita enriquecida en LREE (La, Ce, Nd) en microfracturas que afectan a los cristales de zircón, evidencian interacciones de las carbonatitas con fluidos hidrotermales y removilización parcial de REE. El pirocloro es el principal mineral reservorio de tierras raras (suma REE=216694 ppm), con valores elevados de LREE (LaN=185816 y CeN=165209) respecto a…

Seeking the mantle source and storage system of carbonatite magmas: case studies from Fuerteventura (Canary Islands) and Mt. Vulture volcano (souther…

Carbonatite magmatism is mainly associated with intraplate continental tectonic settings, with a temporal distribution from Archean to the present. The growing number of carbonatite occurrences from unconventional tectonic settings, such as oceanic contexts (e.g., Carnevale et al., 2021) or subduction zones (e.g., D’Orazio et al., 2007), received considerable attention during last two decades, given their importance as source of rare elements, and, most importantly, because they provide meaningful information about the geochemical cycle of carbon and mantle metasomatism as well. This work shows how the study of fluids trapped within minerals from carbonatites and carbonatite magmas can prov…

Ca-rich carbonates associated with ultrabasic-ultramafic melts. Carbonatite or limestone xenoliths? A case study from the late Miocene Morron de Vill…

2016

The volcanic products of the late Miocene Morron de Villamayor volcano (Calatrava Volcanic Field, central Spain) are known for being one of the few outcrops of leucitites in the entire circum-Mediterranean area. These rocks are important because aragonite of mantle origin has been reported as inclusion in olivine macrocrysts. We use petrographic observations, mineral compositions, as well as oxygen and carbon isotope ratios coupled with experimental petrology to understand the origin of carbonate phase in these olivine-phyric rocks. Groundmass and macrocryst olivines range from δ18OVSMOW of +4.8‰, typical of mantle olivine values, to +7.4‰, indicating contamination by sedimentary carbonate.…

Microthermometry of fluid inclusions in calcite from Fuerteventura carbonatites: composition and formation conditions

2022

The petrographic analysis in calcite minerals in carbonatitic dykes from Fuerteventura Basal Complex (Ajuy, Punta de la Nao) shows the presence of isolated primary fluid inclusions, corroborating their magmatic origin instead of a late-stage origin. Micro-thermometric studies in calcite show a restricted range of apparent eutectic temperature (Te*= -21.7 – -21.0 °C) and final ice melting temperatures (Tim= -3.2 – -2.1. °C). Homogenization temperatures and pressures are in the range of 140-210 °C and 4-16 bars respectively. Our results suggest the binary NaCl-H2O system as a characterizing chemical system in studied fluid inclusions, with the presence of low salinity fluids (≈ 5 wt. % NaCleq…

Petrology and geochemistry of peri-Mediterranean carbonatite magmatism: case studies from Fuerteventura (Canary Islands) and Mt. Vulture volcano (sou…

2023

Carbonatites are rare magmatic rocks of great scientific and economic importance, and carbonatite magmatism is mainly associated with intraplate continental tectonic settings, with some rare occurrences in oceanic contexts. Despite their importance, many aspects of carbonatite petrogenesis and evolution processes remain still poorly constrained. In order to further constrain the mantle source and the storage system of carbonatite magmas, Fuerteventura (Canary Islands) was taken as a representative case study of oceanic carbonatites, while Mt. Vulture (southern Italy) was taken as a representative case study of intra-continental carbonatites, with a two-fold aim: to understand (i) the role o…