Search results for "cascade"
showing 10 items of 271 documents
Counting statistics for electron capture in a dynamic quantum dot
2012
We report non-invasive single-charge detection of the full probability distribution $P_n$ of the initialization of a quantum dot with $n$ electrons for rapid decoupling from an electron reservoir. We analyze the data in the context of a model for sequential tunneling pinch-off, which has generic solutions corresponding to two opposing mechanisms. One limit considers sequential "freeze out" of an adiabatically evolving grand canonical distribution, the other one is an athermal limit equivalent to the solution of a generalized decay cascade model. We identify the athermal capturing mechanism in our sample, testifying to the high precision of our combined theoretical and experimental methods. …
Rethinking the sGLOH Descriptor
2018
sGLOH (shifting GLOH) is a histogram-based keypoint descriptor that can be associated to multiple quantized rotations of the keypoint patch without any recomputation. This property can be exploited to define the best distance between two descriptor vectors, thus avoiding computing the dominant orientation. In addition, sGLOH can reject incongruous correspondences by adding a global constraint on the rotations either as an a priori knowledge or based on the data. This paper thoroughly reconsiders sGLOH and improves it in terms of robustness, speed and descriptor dimension. The revised sGLOH embeds more quantized rotations, thus yielding more correct matches. A novel fast matching scheme is a…
ChemInform Abstract: Gold Catalyzed Stereoselective Tandem Hydroamination-Formal Aza-Diels-Alder Reaction of Propargylic Amino Esters.
2013
The overall sequence of the tandem reaction presented here leads to nitrogen-containing tetracycles under formation of 4 bonds and five stereocenters, in most cases as single diastereoisomers.
Gold-Catalyzed Tandem Hydroamination/Formal Aza-Diels-Alder Reaction of Homopropargyl Amino Esters: A Combined Computational and Experimental Mechani…
2015
A tandem gold-catalyzed hydroamination/formal aza-Diels-Alder reaction is described. This process, which employs quaternary homopropargyl amino ester substrates, leads to the formation of an intrincate tetracyclic framework and involves the generation of four bonds and five stereocenters in a highly diastereoselective manner. Theoretical calculations have allowed us to propose a suitable mechanistic rationalization for the tandem protocol. Additionally, by studying the influence of the ligands on the rate of the gold-catalyzed reactions, it was possible to establish optimum conditions in which to perform the process with a variety of substituents on the amino ester substrates. Notably, the …
Friedel-Crafts Alkylation of Arenes in Total Synthesis
2015
ChemInform Abstract: A Light-Induced Vinylogous Nazarov-Type Cyclization.
2016
The title reaction is incorporated in a three-step cascade transformation providing novel tetracyclic ring structures containing a seven-membered ring.
Cascaded H-Bridges Multielvel Inverters: grid connected advanced applications
Power electronics is going to increase in the modern electrical systems. It is well known that the use of power electronics allows the management and the control of the energy flow, obtaining voltage and current waveforms suitable for electrical loads. In this scenario, multilevel power converters are finding increased attention in industry and academia as one of the promising choices of electronic conversion thanks to their features and many different application fields with high power and medium voltage. Moreover, they are fundamental in interfacing electric grid to high power renewable energy systems (i.e. PV, Wind farm, Biomass, Fuel Cell etc.). Nowadays, the research is focused on the …
A novel method for harmonic mitigation for single-phase five-level cascaded H-Bridge inverter
2018
The efficiency of a system is a very important parameter for high power electrical drives applications. Moreover, the efficiency of power converters plays a fundamental role. Aim of this work, is to propose a novel selective harmonic mitigation method without solving non-linear equations. Through a very simple approach, the polynomial equations which drive the control angles have been detected for a single-phase five-level cascaded H-Bridge inverter. The obtained polynomial equations can be easily implemented in a digital system to real-time operation. The paper also presents the simulation analysis and experimental validation.
Enhanced Modelling for Extended Performance Analysis of Interior Permanent Magnet Synchronous Machine Drive fed with Cascaded H-Bridges Multilevel In…
2021
This paper presents a comparative simulation analysis of an Interior Permanent Magnet Synchronous Machine (IPMSM) performance once fed by a traditional three-phase two-level inverter and then using a three-phase five-level Cascaded H-Bridges Multilevel Inverter (CHBMI). For this purpose, an enhanced mathematical model of the IPMSM, that take into account simultaneously saturation, cross-coupling, spatial harmonics and iron loss effects, has been employed. Furthermore, two different PWM modulation strategies have been considered. The study was conducted for several working conditions, evaluating the impact of CHBMI adoption on the IPMSM performance in terms of improved efficiency and torque …
Conversion of levulinic acid to γ-valerolactone over Zr-containing metal-organic frameworks: Evidencing the role of Lewis and Brønsted acid sites
2021
Zr-containing UiO-66 and MOF-808 are evaluated for converting levulinic acid (LA) into γ-valerolactone (GVL) through various routes: (i) Step-wise esterification of LA to n-butyl levulinate (nBuL) and Meerwein-Ponndorf-Verley (MPV) reduction to GVL; (ii) One-pot two-steps esterification with n-butanol followed by MPV reduction with sec-butanol; and (iii) direct conversion of LA into GVL through a tandem reaction. Selection of this multistep complex reaction evidences the participation of the different acid sites (Lewis or Brønsted) of the material in each individual step: Brønsted-induced acid sites catalyze esterification reaction efficiently, while Lewis acid sites are the preferred sites…