Search results for "chalcogenide"
showing 10 items of 141 documents
High third and second order non linearities of chalcogenide glasses and fibers for compact infrared non linear devices.
2008
Due to their intrinsic nature, chalcogenide glasses present attractive nonlinearities from third and second order, with values reaching between 10 and 1000 times those of silica. We present a study of their properties and their shaping with the purpose to reach efficient devices in the near-mid infrared.
Mid-infrared supercontinuum generation in suspended-core chalcogenide and tellurite optical fibers
2013
Summary form only given. The generation of optical supercontinua in the mid-infrared region and especially their expansion beyond the intrinsic limit dictated by fused silica is currently a subject of high interest. Tellurite and chalcogenide glasses have serious advantages because of their wide transmittance window which can reach more than 10 μm while the Kerr nonlinearity can be 500 times stronger than fused silica. These different features make them serious candidates for broad mid-infrared supercontinuum generation. For example, supercontinuum as broad as 4000-nm bandwidth has been generated in a sub-cm long Tellurite microstructured fiber by Domachuk et al. in ref. [1] by means of a f…
High bit rate optical pulses sources generation and microstructured chalcogenide fibers characterizations
2011
This memory of thesis s' registered voter in the context of the FUTUR project financed by l' ANR and concerning the development of optical functions for the high bit-rate transmissions in the Network heart and carries on very high rates optical fibers sources generation and the optical chalcogenide microstructured fiber characterization. For this purpose, we study the linear and non-linear characteristics of microstructured chalcogenide fibers conceived and realized in various collaborations within the framework of the ANR FUTUR project. For that a great number of characterizations methods were developed giving a comparison between a standard single mode fiber and these microstructured chal…
High bit rate optical pulses sources generation and microstructured chalcogenide fibers characterizations
2011
This memory of thesis s' registered voter in the context of the FUTUR project financed by l'ANR and concerning the development of optical finctions fot the high bit-rate transmissions in the Network heart and carries on very high rates optical fibers sources generation and the optical chalcogenide microstructured fiber charaterization. For this purpose, we study the linear and non-linear characteristics of microstructured chalcogenide fibers conceived and realized in various collaborations within the framework of the ANR FUTUR project. For that a great number of characterizations methods were developed giving a comparison between a standard single mode fiber and there microstructured chalco…
Reversible self-assembly of metal chalcogenide/metal oxide nanostructures based on Pearson hardness.
2010
Nanotechnology has reached a stage of development where not individual nanoparticles but rather systems of greater complexity are the focus of concern. These complex structures incorporate two or more types of materials, an example of which is the formation of metal–semiconductor hybrids, which effectively combine the properties of both materials. The assembly of multicomponent nanoparticles from constituents with different optical, electrical, magnetic, and chemical properties can lead to novel functionalities that are independent of the individual components and may be tailored to fit a specific application. These applications include such far-reaching challenges as solar energy conversio…
Supercontinuum generation in chalcogenide: application to gas spectroscopy in atmospheric band III
2023
This thesis work aims to contribute to the development of new fiber sources emitting over a wide range of wavelengths in the IR, in particular to detect greenhouse gases in the mid-infrared range. Our spectroscopy results with nitrous oxide N2O and methane CH4 are obtained in band III. To achieve this, the generation of supercontinuum (SC) covering band III was made possible by using chalcogenide optical fibers, purified and free of highly toxic elements according to REACH regulations, in particular arsenic and antimony. The fibrable vitreous composition belonging to the Ge-Se-Te ternary system fits perfectly into the context of sustainable development, it is the one that has been identifie…
Enzyme-Mediated Deposition of a TiO2Coating onto Biofunctionalized WS2 Chalcogenide Nanotubes
2009
A chemically specific and facile method for the biofunctionalization of WS2 nanotubes (NT-WS2) is reported. The covalent modification strategy is based on the affinity of the nitrilotriacetic acid (NTA) side chain, which serves as a ligand for the surface binding to NT-WS2 and simultaneously as an anchor group for the binding of His-tagged proteins to the polymer backbone. The polymer functionalized WS2 nanotubes can be solubilized either in water or organic solvents; they are stable for at least one week. The probes were characterized by FT-IR and UV-vis spectroscopy. The immobilization of silicatein, a hydrolytic protein encountered in marine sponges, was visualized by scanning force micr…
Disorder Classification of the Vibrational Spectra of Modern Glasses
2021
Using the coherent-potential approximation in heterogeneous-elasticity theory with a log-normal distribution of elastic constants for the description of the Raman spectrum and the temperature dependence of the specifi?c heat, we are able to reconstruct the vibrational density of states and characteristic descriptors of the elastic heterogeneity of a wide range of glassy materials. These descriptors are the non-affi?ne contribution to the shear modulus, the mean-square fluctuation of the local elasticity, and its correlation length. They enable a physical classification scheme for disorder in modern, industrially relevant glass materials. We apply our procedure to a broad range of real-world…
Optical Field-Induced Mass Transport in Soft Materials
2013
Abstract The dependence of the surface relief formation in amorphous chalcogenide (As 2 S 3 and As-S-Se) and Disperse Red 1 dye grafted polyurethane polymer films on the polarization state of holographic recording light beams was studied. It is shown that the direction of lateral mass transport on the film surface is determined by the direction of light electric vector and photoinduced anisotropy in the film. We propose a photoinduced dielectropfhoretic model to explain the photoinduced mass transport in amorphous films. Model is based on the photoinduced softening of the matrix, formation of defects with enhanced or decreased polarizability, and their drift under the electrical field gradi…
<title>Holographic recording in polymer composites of organic photochromes and chalcogenides</title>
2008
Recently a number of organic and inorganic materials have been studied for direct surface-relief formation during the exposure process by a light or e-beam. It is very promising for practical application enabling the possibility to simplify the surface-relief formation technology. In this report the method of preparation of thin polymer-chalcogenide and polymer-azobenzene composite films is described, and some features of photoinduced changes of optical properties and holographic recording of these materials are studied. Films of composites were obtained from solution of arsenic sulphide, Disperse red 1 and polymers in organic solvents. The solution was spread on glass substrate and dried. …