Search results for "character"
showing 10 items of 2956 documents
Local porosity theory for electrical and hydrodynamical transport through porous media
1993
The current status of local porosity theory for transport in porous media is briefly reviewed. Local porosity theory provides a simple and general method for the geometric characterization of stochastic geometries with correlated disorder. Combining this geometric characterization with effective medium theory allows for the first time to understand a large variety of electrical and hydrodynamical flow experiments on porous rocks from a single unified theoretical framework. Rather than reproducing or rephrasing the original results the present review attempts instead to place local porosity theory within the context of other current developments in theory and experiment.
Block–Savits Characterization and Star Ordering of Exponential Mixtures
2008
Block and Savits (1980) established a characterization of life distributions using the Laplace transform. In this article, we remark that one of the necessary conditions to be IFRA distribution is equivalent to the star ordering of exponential mixtures. It leads to the definition of two new classes of life distributions, called LIFR and LIFRA, and their dual classes: LDFR and LDFRA. It occurs that these classes have many useful aging properties and preserve known reliability operations. Properties of the classes are studied and relations with known classes are established.
Infinite rate mutually catalytic branching in infinitely many colonies: The longtime behavior
2012
Consider the infinite rate mutually catalytic branching process (IMUB) constructed in [Infinite rate mutually catalytic branching in infinitely many colonies. Construction, characterization and convergence (2008) Preprint] and [Ann. Probab. 38 (2010) 479-497]. For finite initial conditions, we show that only one type survives in the long run if the interaction kernel is recurrent. On the other hand, under a slightly stronger condition than transience, we show that both types can coexist.
Structural and dynamical characterization of melt PEO–salt mixtures
2002
Abstract Salt doped poly ethylene oxide (PEO) mixtures were investigated by means of both small angle neutron scattering and QENS techniques aiming to characterize morphological and dynamical features in the melt state. These experimental evidences provide support to the proposed heterogeneous scenario for polymer electrolytes. In particular, the existence of PEO–cation complexes is proposed to play a major role in intramolecular cooperation and intermolecular transient crosslinks, which affects the mixture properties.
Extremal polynomials in stratified groups
2018
We introduce a family of extremal polynomials associated with the prolongation of a stratified nilpotent Lie algebra. These polynomials are related to a new algebraic characterization of abnormal subriemannian geodesics in stratified nilpotent Lie groups. They satisfy a set of remarkable structure relations that are used to integrate the adjoint equations.
Assessing local differences between the spatio-temporal second-order structure of two point patterns occurring on the same linear network
2021
Abstract We introduce Local Indicators of Spatio-Temporal Association (LISTA) functions on linear networks and use them to build a statistical test for local second-order structure. This allows to identify differences in the spatio-temporal clustering behaviour of two point patterns, a point pattern of interest and a background one, both occurring on the same linear network. We assess the performance of the testing procedure for local second-order structure through simulation studies under a variety of scenarios that also account for different generating point processes. We show that the proposed local test is able to correctly identify the spatio-temporal difference in the local second-ord…
Recent applications of point process methods in forestry statistics
2000
Forestry statistics is an important field of applied statistics with a long tradition. Many forestry problems can be solved by means of point processes or marked point processes. There, the "points" are tree locations and the "marks" are tree characteristics such as diameter at breast height or degree of damage by environmental factors. Point pro- cess characteristics are valuable tools for exploratory data analysis in forestry, for describing the variability of forest stands and for under- standing and quantifying ecological relationships. Models of point pro- cesses are also an important basis of modern single-tree modeling, that gives simulation tools for the investigation of forest stru…
Precursors of aza-macrocycles: Characterization of substituted phenanthrolines and related bases. Crystal and molecular structure of dichloro-d i-n-b…
1993
The synthesis, characterization and 1~ NMR spectra of some substituted 1,lO-phenantrolines are described. These are precursors of azacyclophanes which are, along with their metal complexes, insoluble in polar solvents. It is suggested that the use of substituted 2,2’, 6,6’ -bipyrimidines as precursors would lead to soluble macrocycles. The crystal and molecular structure of dichloro-di-n-butyl(2,2’,6,6’-bipyr
Impact of the use of sterically congested Ir(III) complexes on the performance of light-emitting electrochemical cells
2018
International audience; The synthesis, structural and optoelectronic characterization of a family of sterically congested cyclometalated cationic Ir(iii) complexes of the form [Ir(C^N)2(dtBubpy)]PF6 (with dtBubpy = 4,4′-di-tert-butyl-2,2′-bipyridine and C^N = a cyclometalating ligand decorated at the 4-position of the pyridine ring and/or the 3-position of the phenyl ring with a range of sterically bulky substituents) are reported. This family of complexes is compared to the unsubstituted analogue complex R1 bearing 2-phenylpyridinato as cyclometalating ligand. The impact of sterically bulky substituents on the C^N ligands on both the solid state photophysics and light-emitting electrochemi…